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| Author | : Nicolay V. Tsarevsky |
| Publisher | : Royal Society of Chemistry |
| Total Pages | : 379 |
| Release | : 2013 |
| Genre | : Science |
| ISBN | : 1849734259 |
Provides an in-depth history, description, and mechanistic understanding of each of the controlled/living radical polymerization techniques and practical details necessary to carry out the reactions.
| Author | : Krzysztof Matyjaszewski |
| Publisher | : John Wiley & Sons |
| Total Pages | : 934 |
| Release | : 2003-04-14 |
| Genre | : Technology & Engineering |
| ISBN | : 0471461571 |
Klassische und moderne Verfahren der radikalischen Polymerisation: In diesem handlichen Band finden Sie Antworten auf theoretische und praktische Fragen. Neben grundlegenden Ausführungen zur Einteilung radikalischer Polymere sind Angaben über die wichtigsten experimentellen Verfahren zur Synthese, Reinigung und Charakterisierung von Polymeren enthalten. Interessante Zugabe: ein Abriß der Geschichte der Radikalkettenpolymerisation.
| Author | : Krzysztof Matyjaszewski |
| Publisher | : |
| Total Pages | : 506 |
| Release | : 2000 |
| Genre | : Language Arts & Disciplines |
| ISBN | : |
This book examines recent progress in controlled/living radical polymerization. The volume focuses on three synthetic methods: atom transfer radical polymerization, nitroxide mediated polymerization and degenerative transfer via addition fragmentation. In addition, the volume covers the preparation and characterization of many never before seen materials using ATRP, NMP and RAFT.
| Author | : |
| Publisher | : |
| Total Pages | : 17 |
| Release | : 1995 |
| Genre | : |
| ISBN | : |
Fundamentals and some practical synthetic aspects of controlled radical polymerization will be discussed in the lecture. Effect of slow initiation, termination, and transfer on kinetics, molecular weights and polydispersities will be described in the quantitative way. Conditions for typical radical polymerization and for controlled radical polymerization will be compared. The concept of reversible deactivation of growing radicals in order to control molecular weights, polydispersities and terminal functionalities will be presented. Four systems will be discussed in detail: (1) Reversible cleavage of covalent species (2) Reversible formation of persistent radicals (3) Reversible redox systems (4) Degenerative group and atom transfer. In all four systems the effect of dynamics of exchange between dormant and active species on kinetics as well as on the evolution of molecular weights and polydispersities with conversion will be presented. jg p.2.
| Author | : Krzysztof Matyjaszewski |
| Publisher | : Academic |
| Total Pages | : 444 |
| Release | : 2009 |
| Genre | : Language Arts & Disciplines |
| ISBN | : |
Recent progress in the field of controlled/living radical polymerization.
| Author | : Wayne F. Reed |
| Publisher | : John Wiley & Sons |
| Total Pages | : 493 |
| Release | : 2014-01-21 |
| Genre | : Technology & Engineering |
| ISBN | : 0470917385 |
Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.
| Author | : Krzysztof Matyjaszewski |
| Publisher | : OUP USA |
| Total Pages | : 0 |
| Release | : 2007-01-04 |
| Genre | : Science |
| ISBN | : 9780841239913 |
The preparation and characterization of new materials with precisely controlled macromolecular dimensions, functionalities, and decomposition, as well as with well-defined topologies, is perhaps the main focus of contemporary polymer synthesis. The best control of molecular functions can be achieved in a controlled/living polymerization -- a chain growth process without chain breaking reactions. Recently, controlled/living polymerizations have extended to radical systems which are not only commercially important, but also have the largest potential due to the availability of radically polymerizable monomers, facile copolymerization and undemanding experimental conditions. Controlled Radical Polymerization will examine recent advances in mechanistic and synthetic aspects of controlled/living radical (co)polymerization systems. Not only will this book be focused on recent progress in the dynamically developing field of controlled/living radical polymerization, but it will be a sequel to the very popular ACS Symposium Series 685, 768, and 854. The book will consist of >30 chapters separated into seven subsections: Fundamentals, Mechanism of ATRP, Mechanisms of SFRP and Degenerative Transfer Processes, Controlled Architecture by CRP, Organic-inorganic Hybrids by CRP, Biomaterials by CRP and Industrial Applications. This book targets chemists and polymer scientists in academia and in industry.
| Author | : Samir Chikkali |
| Publisher | : CRC Press |
| Total Pages | : 188 |
| Release | : 2017-08-03 |
| Genre | : Science |
| ISBN | : 1351649957 |
The proposed book focusses on metal mediated/catalyzed “controlled/living radical polymerization” (CRP/LRP) methods. It surveys a wide variety of catalyzed polymerization reactions, making it essentially a “one stop” review in the field. A significant contribution to polymer science is “metathesis polymerization” discovered by Grubbs and others. The book will cover various metathesis polymerization methods and implications in polymer industry.
| Author | : Vivek Mishra |
| Publisher | : LAP Lambert Academic Publishing |
| Total Pages | : 132 |
| Release | : 2013 |
| Genre | : |
| ISBN | : 9783659355776 |
This book gives a good understanding of the progress being made in controlled radical polymerization process. The basic principle of controlled/living radical polymerization is fundamental to the creation of new radical polymerization techniques including atom transfer radical, and reversible addition-fragmentation transfer polymerization. These discoveries bring new life to the field of free radical polymerization; indeed, an abundance of polymer materials with different topologies have been prepared. I hope that this Special Topic on "Functional Controlled/Living Radical Polymers: Synthesis, Kinetics and Physico-chemical Properties" will cultivate new ideas and catalyze discoveries in every reader's laboratory. This book is aimed to provide information related to the newest controlled radical polymerization methodology, ATRP and RAFT, their required components and their advantages and necessities. I demonstrates that how simple molecule selectively arrange as different topology like linear, star, multi arm polymers containing functional groups for various applications.
| Author | : Jean-François Lutz |
| Publisher | : John Wiley & Sons |
| Total Pages | : 532 |
| Release | : 2018-04-09 |
| Genre | : Technology & Engineering |
| ISBN | : 3527342370 |
Edited by a leading authority in the field, the first book on this important and emerging topic provides an overview of the latest trends in sequence-controlled polymers. Following a brief introduction, the book goes on to discuss various synthetic approaches to sequence-controlled polymers, including template polymerization, genetic engineering and solid-phase chemistry. Moreover, monomer sequence regulation in classical polymerization techniques such as step-growth polymerization, living ionic polymerizations and controlled radical polymerizations are explained, before concluding with a look at the future for sequence-controlled polymers. With its unique coverage of this interdisciplinary field, the text will prove invaluable to polymer and environmental chemists, as well as biochemists and bioengineers.
