Fundamentals of Carbanion Chemistry (Volume 4).
| Author | : Cram DJ. |
| Publisher | : |
| Total Pages | : |
| Release | : 1965 |
| Genre | : |
| ISBN | : |
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Fundamentals Of Carbanion Chemistry Volume 4 PDF Download
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Fundamentals of Carbanion Chemistry
| Author | : Donald J. Cram |
| Publisher | : Elsevier |
| Total Pages | : 299 |
| Release | : 2012-12-02 |
| Genre | : Science |
| ISBN | : 0323162444 |
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Organic Chemistry, Volume 4: Fundamentals of Carbanion Chemistry provides information pertinent to carbanion chemistry. This book explores several topics, including carbonium ions, carbanions, carbenes, and carbon radicals. Comprised of six chapters, this volume starts with an overview of the variation of the kinetic and thermodynamic acidities of carbon acids with substituents and environments. This text then explores the methods of carbanion stabilization by substituents and discusses the various types of stabilization. Other chapters explain the stereochemistry of hydrogen–deuterium exchange and examine the stereochemistry of substitution reactions of organometallic compounds. This book discusses as well the structure and immediate environment of reaction intermediates through the use of stereochemical techniques. The final chapter considers the unsaturated anionic rearrangements of carbanions, carbonium ions, as well as carbon radicals and other rearrangements. Chemists, organic chemists, researchers, and graduate students interested in the field of carbanion chemistry will find this book extremely useful.
Survey of Progress in Chemistry
| Author | : Arthur F. Scott |
| Publisher | : Elsevier |
| Total Pages | : 303 |
| Release | : 2013-10-22 |
| Genre | : Science |
| ISBN | : 1483225097 |
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Survey of Progress in Chemistry, Volume 4 considers the principles common to all chemistry that undergo major developments and modifications, including aqueous solutions, carbanions, stable isotopes, nitrogen fixation, ionizing radiation, and organic compound luminescence. This volume is organized into six chapters. The first chapter surveys first the theories of water and aqueous solutions structure, followed by the evaluation of temperature, pressure, and electrolytes on water. This chapter emphasizes the role of water structure in biological systems. The second chapter covers the generation, capture, mechanism of stabilization, and isomerization of carbanions, while the separation and practical applications of isotopes are examined in the third chapter. The following chapter describes the mechanism of nitrogen fixation by those cells capable of fixing nitrogen. The concluding chapters explore some aspects of the energy transfer process and the formation of intermediate molecular species. These chapters also evaluate the luminescence of organic systems. This book is of value to college chemistry teachers and students.
Ylid Chemistry
| Author | : A.W. Johnson |
| Publisher | : Elsevier |
| Total Pages | : 399 |
| Release | : 2012-12-02 |
| Genre | : Science |
| ISBN | : 0323162797 |
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Organic Chemistry, Volume 7: Ylid Chemistry focuses on the physical and chemical properties of ylids. This book discusses the Wittig synthesis of olefins, which involves the reaction between carbonyl compounds and phosphonium ylids. Organized into two parts encompassing nine chapters, this book starts with an overview of the definition of ylids as a substance in which a carbanion is attached directly to a heteroatom transporting a high degree of positive charge. This text then examines the unique stabilization that afforded the carbanions by the presence of the adjacent 'onium atom group, which is the special characteristic of ylids. Other chapters consider the general structure of phosphonium ylids, which virtually has no limitation on the nature of the X groups on phosphorus. This book discusses as well the Wittig reaction involving a condensation-elimination between a phosphonium ylid and ketone. The final chapter deals with the various aspects of the chemistry of sulfur ylids. This book is a valuable resource for chemists.
Catalog of Books and Reports in the Bureau of Mines Technical Library, Pittsburgh, Pa
| Author | : United States. Bureau of Mines. Technical Library, Pittsburgh |
| Publisher | : |
| Total Pages | : 778 |
| Release | : 1968 |
| Genre | : Library catalogs |
| ISBN | : |
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Carbene Chemistry
| Author | : Wolfgang Kirmse |
| Publisher | : Elsevier |
| Total Pages | : 311 |
| Release | : 2012-12-02 |
| Genre | : Science |
| ISBN | : 0323162487 |
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Organic Chemistry, Volume 1: Carbene Chemistry is a 12-chapter text that covers pertinent research studies on the carbene chemistry. The first ten chapters are devoted to comprehensive surveys of carbene chemistry. Each chapter tackles specific carbene compound, such as olefinic and acetylenic carbenes, aryl and diarylcarbenes, carboalkoxycarbenes, ketocarbenes, halocarbenes, heteroatom-containing carbenes, and dicarbenes. The formation, synthesis, and reactions of these compounds are discussed. The remaining two chapters the excess energy in reactions and spin states of carbenes. This book will be of value to organic chemists, organic chemistry researchers, teachers, and students.
1,4-Cycloaddition Reaction: The Diels-Alder Reaction in Heterocyclic Syntheses
| Author | : Jan Hamer |
| Publisher | : Elsevier |
| Total Pages | : 513 |
| Release | : 2013-07-19 |
| Genre | : Science |
| ISBN | : 0323163114 |
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Organic Chemistry, Volume 8: 1,4-Cycloaddition Reactions: The Diels-Alder Reaction in Heterocyclic Syntheses describes 1,4-cycloaddition reactions leading to the formation of five- or six-membered heterocyclic compounds. Divided into 13 chapters, this book starts with an overview of various 1,4-cycloaddition reaction equations in the presence of at least one atom other than carbon. The following chapters describe the reaction mechanisms of five- or six-membered ring formed upon reaction with a dienophile, which contains an atom other than carbon. Considerable chapters are devoted to compounds used as dienophiles, including trivalent phosphorus, cyanogens and cyanogens-like compounds, imino, azo, carbonyl, thiocarbonyl, and diene compounds, as well as oxygen. Other chapters highlight some 1,4-cycloaddition reactions taking place through free radical intermediates. This book is of value to organic and research chemists, as well as undergraduate and graduate organic chemistry students.
Organic Functional Group Preparations
| Author | : Stanley R. Sandler |
| Publisher | : Elsevier |
| Total Pages | : 513 |
| Release | : 2013-10-22 |
| Genre | : Science |
| ISBN | : 1483275558 |
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Organic Functional Group Preparations, Volume III describes 13 organic functional groups and presents a critical review of their available methods of synthesis with preparative examples of each. The book puts special attention to the presentation of specific laboratory directions for the many name reactions used in describing the synthesis of these functional groups. Each chapter deals with the preparation of a given functional group by various reaction types (condensation, elimination, oxidation, reduction) and a variety of starting materials. Acetals and ketals, anhydrides, and thiohydroxamic acids are some of the organic functional groups described in the text. Organic chemists will find the book invaluable.
Inorganic Reactions and Methods, The Formation of the Bond to Hydrogen (Part 2)
| Author | : J. J. Zuckerman |
| Publisher | : John Wiley & Sons |
| Total Pages | : 505 |
| Release | : 2009-09-17 |
| Genre | : Science |
| ISBN | : 0470145374 |
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For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifiying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.
Organometallic Syntheses
| Author | : John Eisch |
| Publisher | : Elsevier |
| Total Pages | : 209 |
| Release | : 2012-12-02 |
| Genre | : Science |
| ISBN | : 0323160174 |
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Nontransition-Metal Compounds is the second volume in the series Organometallic Syntheses and presents various procedures for the nontransition-metal compounds. Topics also covered in this volume include sensitive liquids, sample transfer, and inert atmosphere provision. The text is divided into two major parts. Part I is mostly procedural as it offers directions and suggestions in different processes such as (a) establishment of an inert atmosphere and solvent medium; (b) evaluation of purity, mode of mixing, and solvent type; and (c) isolation and purification of reaction products. Organometallic products, particularly its physical and chemical characteristics, are also tackled. In Part II, around 85 nontransition-metal organometallic compounds and the reliable procedures used for their synthesis are presented. This particular volume will be of help to students both in the fields of chemistry and biology.
