Fundamentals Of Carbanion Chemistry PDF Download
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Author | : Donald J. Cram |
Publisher | : Elsevier |
Total Pages | : 299 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 0323162444 |
Download Fundamentals of Carbanion Chemistry Book in PDF, ePub and Kindle
Organic Chemistry, Volume 4: Fundamentals of Carbanion Chemistry provides information pertinent to carbanion chemistry. This book explores several topics, including carbonium ions, carbanions, carbenes, and carbon radicals. Comprised of six chapters, this volume starts with an overview of the variation of the kinetic and thermodynamic acidities of carbon acids with substituents and environments. This text then explores the methods of carbanion stabilization by substituents and discusses the various types of stabilization. Other chapters explain the stereochemistry of hydrogen–deuterium exchange and examine the stereochemistry of substitution reactions of organometallic compounds. This book discusses as well the structure and immediate environment of reaction intermediates through the use of stereochemical techniques. The final chapter considers the unsaturated anionic rearrangements of carbanions, carbonium ions, as well as carbon radicals and other rearrangements. Chemists, organic chemists, researchers, and graduate students interested in the field of carbanion chemistry will find this book extremely useful.
Author | : Donald James Cram |
Publisher | : |
Total Pages | : 289 |
Release | : 1965 |
Genre | : Carbanions |
ISBN | : |
Download Fundamentals of Carbanion Chemistry Book in PDF, ePub and Kindle
Author | : Donald J. Cram |
Publisher | : |
Total Pages | : 0 |
Release | : 1965 |
Genre | : |
ISBN | : |
Download Organic chemistry Book in PDF, ePub and Kindle
Author | : Victor Snieckus |
Publisher | : Greenwich, Conn. : JAI Press |
Total Pages | : 306 |
Release | : 1992 |
Genre | : Science |
ISBN | : 9780892328598 |
Download Advances in Carbanion Chemistry Book in PDF, ePub and Kindle
This series deals with the continuously evolving area of carbanion chemistry. Fundamentals are stressed, as are synthetic applications. The overall aim is to provide a series which lends itself to pedagogic and resource use by novice and experienced investigators, graduates and professionals.
Author | : Cram DJ. |
Publisher | : |
Total Pages | : |
Release | : 1965 |
Genre | : |
ISBN | : |
Download Fundamentals of Carbanion Chemistry (Volume 4). Book in PDF, ePub and Kindle
Author | : R. Bates |
Publisher | : Springer |
Total Pages | : 0 |
Release | : 2012-01-19 |
Genre | : Science |
ISBN | : 9783642690396 |
Download Carbanion Chemistry Book in PDF, ePub and Kindle
This book was prepared with the idea of collecting some of the multitudinous new literature on carbanions and pre- senting it along with the fundamentals of carbanion chemi- stry. Some 400 papers from the period 1976 to 1982 have been assimilated into the book along with about an equal number of references (many to reviews) from the earlier literature. The material is organized under the headings Structures (with emphasis on the results of X-ray studies since they unambiguously show the molecular geometry), Preparations, and Reactions. Reactions, the largest topic, is divided into reactions with electrophiles, eliminations, oxidations, and rearrangements. Under these headings, carbanions without resonance stabilization (0' carbanions) are generally discus- sed first, and are further subdivided into Sp3 (alkyl) followed by Sp2 (vinyl and aryl) followed by sp (acetylenic); resonance- stabilized (n) hydrocarbon anions such as allyl and benzyl follow; lastly, heteroatom-containing n carbanions such as enolates are considered. Some references to carbanion equivalents are included at the end. Tucson, Arizona U.S.A. Robert B. Bates May 1983 Craig A. Ogle Table of Contents I. Introduction 1 II. Structures . 3 1. Non-delocalized (0") 3 a. Sp3 ..... . 3 b. Sp2 and sp . . . 7 2. Delocalized (n) . . 8 a. Hydrocarbon Anions 8 b. Heteroatom-containing Carbanions 10 III. Preparations. . . . . 13 13 1. From Alkyl Halides 13 a. With Metals . . 15 b. With Organometallics . 17 2. From Alkanes by Proton Abstraction 17 a. Acidities of CH Protons. . 21 b. Base-solvent Systems . . . 25 3. From Unsaturated Compounds 25 a. By Reduction . . . . . .
Author | : Laren M. Tolbert |
Publisher | : |
Total Pages | : |
Release | : 1989 |
Genre | : Carbanions |
ISBN | : |
Download Fundamentals of Carbanion Photochemistry Book in PDF, ePub and Kindle
Author | : Narain R. P. |
Publisher | : PHI Learning Pvt. Ltd. |
Total Pages | : 279 |
Release | : 2011-03 |
Genre | : Science |
ISBN | : 8120341791 |
Download Fundamentals of Reaction Mechanisms in Organic Chemistry Book in PDF, ePub and Kindle
Written for the undergraduate and postgraduate students of chemistry, this textbook presents comprehensive coverage of different types of reactions and their mechanisms. The need for such a book has been felt for a very long time both by students and teachers. The book discusses chemical kinetics, structure and reactivity, and reactive intermediates such as carbenes, nitrenes and benzynes. It also describes the mechanism of tautomerism and the concepts of aromaticity. In addition, the book elaborates the various reactions such as substitution, free radical, addition, elimination and alkylation reactions. Finally, the text presents a detailed discussion on molecular rearrangements, oximes and diazo compounds, as well as the concepts of photochemistry. KEY FEATURES: Presents a number of examples to explain the mechanistic concepts. Offers graphs and tables at various places to illustrate the key points. Includes latest information on the subject.
Author | : Victor Snieckus |
Publisher | : Greenwich, Conn. : JAI Press |
Total Pages | : 272 |
Release | : 1996 |
Genre | : Science |
ISBN | : 9781559385480 |
Download Advances in Carbanion Chemistry Book in PDF, ePub and Kindle
This series deals with all facets of the continuously evolving area of carbanion chemistry. It will not slight structural and physical organic aspects at the expense of reactivity and synthetic topics; fundamentals will be stressed, as will synthetic applications. The overall aim is to provide a series which lends itself to pedagogic and resource use by novice and experienced investigators, graduates and professionals.
Author | : Carl David Gutsche |
Publisher | : Prentice Hall |
Total Pages | : 300 |
Release | : 1975 |
Genre | : Science |
ISBN | : |
Download Fundamentals of Organic Chemistry Book in PDF, ePub and Kindle
- - Supplement: Solutions manual/ C. David Gutsche, Daniel J. Pasto. - 1975. - 284p.; 23cm.