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Functionalization of Polyolefins

Functionalization of Polyolefins
Author: T. C. Chung
Publisher: Academic Press
Total Pages: 296
Release: 2002-02-28
Genre: Science
ISBN: 9780121746513

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Summarizes the significant experimental results on the functionalization of polyolefins and classifies them into several chemical methods. This book also provides information on the functional polyolefin materials. It covers: chemical approaches in the functionalization of polyolefins, and polyolefin materials and their potential applications.


Functionalization of Polyolefins

Functionalization of Polyolefins
Author: T. C. Mike Chung
Publisher: Elsevier
Total Pages: 290
Release: 2002-02-04
Genre: Technology & Engineering
ISBN: 0080477933

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Polyolefins are the most widely used commercial polymers and their functionalization has been a long standing scientific challenge and an industrially important area. In recent decades significant progress has been made in the area, with exciting results reported in many journals. Functionalization of Polyolefins is the first book to summarize the significant experimental results on the functionalization of polyolefins and classify them into several chemical methods (shown in each chapter of this book). The book also provides an update on the functional polyolefin materials available today. The two key subject categories covered are: Chemical approaches in the functionalization of polyolefins New available polyolefin materials and their potential applications The book includes: The historic development and future prospects for polyolefins Functionalization chemistry, classified into four general approaches Chemical approaches with experimental results Functionalization approaches The book provides an invaluable reference for researchers in industry and academia interested in functionalization chemistry and polymers. It has been developed through Professor Chung's own teaching experience, both at Pennsylvania State University and on short courses. It is therefore ideally suited as a core text for advanced polymer chemistry and courses on polyolefins and polymers, as well as being a useful supplementary reference for introductory courses on polyolefin chemistry and materials. T.C. Mike Chung is Professor of Polymer Science in the Materials Science and Engineering Department, Pennsylvania State University, USA. He is one of the most experienced people in the field of polyolefin functionalization, with a wide-ranging knowledge gained through many years of experience both in academia and industry. Shows the available functionalisation approaches with a discussion of their scope and limitations Written by one of the most experienced people in this field


Polyolefin Blends

Polyolefin Blends
Author: Domasius Nwabunma
Publisher: John Wiley & Sons
Total Pages: 689
Release: 2008-01-02
Genre: Technology & Engineering
ISBN: 0470198974

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The definitive reference on the properties and applications of polyolefin blends Polyolefins account for more than half of total plastics consumption in the world. In recent years, usage of and research on polyolefin blends have increased significantly due to new applications in medicine, packaging, and other fields and the development of novel polyolefins. With a special emphasis on nano- and micro-structures of crystals and phase morphology, Polyolefin Blends condenses and consolidates current information on polyolefins so that the reader can compare, select, and integrate a material solution. Focusing exclusively on the fundamental aspects as well as applications of polyolefin blends, this authoritative reference: * Features an introductory chapter that serves as a guide to polyolefin blends * Includes chapters covering formulation design, processing, characterization, modeling and simulation, engineering performance properties, and applications * Covers polyolefin/polyolefin blends and polyolefin/non-polyolefin blends * Discusses miscibility, phase behavior, functionalization, compatibilization, microstructure, crystallization, hierarchical morphology, and physical and mechanical properties * Covers new research trends including in-situ reactor blending and reactive processing, such as compatibilization/functionalization in the melt * Contains practical examples from open literature sources and commercial products With chapters contributed by leading experts from several countries, this is a must-have reference for scientists and engineers conducting research on polyolefin blends and for professionals in medical, packaging, and other commodity fields. It is also an excellent text for graduate students studying polymer science and polymer processing.


Reactive Modifiers for Polymers

Reactive Modifiers for Polymers
Author: S. Al-Malaika
Publisher: Springer Science & Business Media
Total Pages: 416
Release: 2012-12-06
Genre: Science
ISBN: 9400914490

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Chemical modification of polymers by reactive modifiers is no longer an academic curiosity but a commercial reality that has delivered a diverse range of speciality materials for niche markets: reactively grafted styrenic alloys, maleated polyolefins, super-tough nylons, silane modified and moisture-cured polyolefins, and thermoplastic elastomers, are but few exam ples of commercial successes. Although the approach of reactive modification of polymers has been largely achieved either in solution or in the solid state (through in situ reactions in polymer melts), it is the latter route that has attracted most attention in the last two decades owing to its flexibility and cost-effective ness. This route, referred to as reactive processing, focuses on the use of suitable reactive modifier(s) and the adoption of conventional polymer processing machinery, an extruder or a mixer, as a chemical reactor, to perform in situ targeted reactions for chemical modification of preformed polymers. This relatively simple, though scientifically highly challenging, approach to reactive modification offers unique opportunities in exploiting various reactive modifiers for the purpose of altering and transforming in a controlled manner the properties of preformed commercial polymers into new/speciality materials with tailor-made properties and custom-designed performance for target applications. Such an economically attractive route constitutes a radical diversion away from the traditional practices of manufacturing new polymers from monomers which involves massive in vestments in sophisticated technologies and chemical plants.


Introduction to Industrial Polypropylene

Introduction to Industrial Polypropylene
Author: Dennis B. Malpass
Publisher: John Wiley & Sons
Total Pages: 290
Release: 2012-07-02
Genre: Technology & Engineering
ISBN: 111846320X

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This introductory text is an important resource for new engineers, chemists, students, and chemical industry personnel to understand the technical aspects of polypropylene which is the 2nd largest synthetics polymer in manufactured output. The book considers the following topics: What are the principal types of polypropylene and how do they differ? What catalysts are used to produce polypropylene and how do they function? What is the role of cocatalysts and how have they evolved over the years? How are industrial polypropylene catalysts tested and the resultant polymer evaluated? What processes are used in the manufacture of polypropylene? What are the biopolymer alternatives to polypropylene? What companies are the major industrial manufacturers of polypropylene? What is the environmental fate of polypropylene?


Polymer Modification

Polymer Modification
Author: Graham G. Swift
Publisher: Springer Science & Business Media
Total Pages: 207
Release: 2013-06-29
Genre: Technology & Engineering
ISBN: 1489914773

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Proceedings of an ACS-PMSE Division Symposium held in Orlando, Florida, August 21-25, 1996


The Plasma Chemistry of Polymer Surfaces

The Plasma Chemistry of Polymer Surfaces
Author: Jörg Friedrich
Publisher: John Wiley & Sons
Total Pages: 479
Release: 2012-05-29
Genre: Technology & Engineering
ISBN: 3527318534

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More than 99% of all visible matter in the universe occurs as highly ionized gas plasma with high energy content. Electrical low- and atmospheric-pressure plasmas are characterized by continuous source of moderate quantities of energy or enthalpy transferred predominantly as kinetic energy of electrons. Therefore, such energetically unbalanced plasmas have low gas temperature but produce sufficient energy for inelastic collisions with atoms and molecules in the gas phase, thus producing reactive species and photons, which are able to initiate all types of polymerizations or activate any surface of low reactive polymers. However, the broadly distributed energies in the plasma exceed partially the binding energies in polymers, thus initiating very often unselective reactions and polymer degradation. The intention of this book is to present new plasma processes and new plasma reactions of high selectivity and high yield. This book aims to bridge classical and plasma chemistry, particularly focusing on polymer chemistry in the bulk and on the surface under plasma exposure. The stability of surface functionalization and the qualitative and quantitative measurement of functional groups at polymer surface are featured prominently, and chemical pathways for suppressing the undesirable side effects of plasma exposure are proposed and illustrated with numerous examples. Special attention is paid to the smooth transition from inanimate polymer surfaces to modified bioactive polymer surfaces. A wide range of techniques, plasma types and applications are demonstrated.


New Advances in Polyolefins

New Advances in Polyolefins
Author: T.C. Chung
Publisher: Springer Science & Business Media
Total Pages: 245
Release: 2012-12-06
Genre: Science
ISBN: 1461529921

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Polyolefin is one of the most important materials produced in the chemical industry. The research in this area is not only scientifically challenging but also potentially economically rewarding. Many research activities, such as developing new catalysts, understanding polymerization mechanisms, modifying the products and improving the physical properties of the material, have been proceeding at a very fast pace, especially in the industrial laboratories in many countries. It is very important and exciting to bring researchers active in this area, from both the academic and industrial sectors, to communicate their new findings. To the best of my knowledge, a symposium covering diverse aspects of polyolefin research has not been held in the USA for many years. With this in mind, a symposium entitled "Recent Advances in Polyolefins" was held at the National ACS Meeting in Washington D. C. , August 23-28, 1992. This symposium covered both scientific and technological aspects of polyolefin, which included four sections: CatalystIPolymerization, Functionalization of Polyolefins, Blends of Polyolefins with Other Polymers, and Applications. More than 50 papers, including 20 foreign contributions, were presented during three and a half days of meetings. It was truly exciting to see key researchers from both academic and industrial laboratories exchange their recent results and to share the important developments in polyolefins. This volume is based on the same spirit and is intended to capture some of the most recent and emerging technical achievements presented at the meeting.


Metal-Polymer Systems

Metal-Polymer Systems
Author: Jörg Florian Friedrich
Publisher: John Wiley & Sons
Total Pages: 444
Release: 2017-12-04
Genre: Technology & Engineering
ISBN: 352733677X

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The result of decades of research by a pioneer in the field, this is the first book to deal exclusively with achieving high-performance metal-polymer composites by chemical bonding. Covering both the academic and practical aspects, the author focuses on the chemistry of interfaces between metals and polymers with a particular emphasis on the chemical bonding between the different materials. He elucidates the various approaches to obtaining a stable interface, including, but not limited to, thermodynamically driven redox reactions, bond protection to prevent hydrolysis, the introduction of barrier layers, and stabilization by spacer molecules. Throughout, chemical bonding is promoted as a simple and economically viable alternative to adhesion based on reversible weak physical interaction. Consequently, the text equips readers with the practical tools necessary for designing high-strength metal-polymer composites with such desired properties as resilience, flexibility, rigidity or degradation resistance.