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| Author | : Konstantin P. Bryliakov |
| Publisher | : Springer Nature |
| Total Pages | : 295 |
| Release | : 2019-10-02 |
| Genre | : Science |
| ISBN | : 9813297514 |
Download Frontiers of Green Catalytic Selective Oxidations Book in PDF, ePub and Kindle
The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C–H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.
| Author | : Konstantin P. Bryliakov |
| Publisher | : |
| Total Pages | : 295 |
| Release | : 2019 |
| Genre | : Catalysis |
| ISBN | : 9789813297524 |
Download Frontiers of Green Catalytic Selective Oxidations Book in PDF, ePub and Kindle
The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C-H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.
| Author | : Hermenegildo Garcia |
| Publisher | : John Wiley & Sons |
| Total Pages | : 501 |
| Release | : 2023 |
| Genre | : |
| ISBN | : 3527350896 |
Download Catalysis in Confined Frameworks Book in PDF, ePub and Kindle
Understanding the synthesis and applications of porous solid catalysts Heterogeneous catalysis is a catalytic process in which catalysts and reactants exist in different phases. Heterogeneous catalysis with solid catalysts proceeds through the absorption of substrates and reagents which are liquid or gas, and this is largely dependent on the accessible surface area of the solid which can generate active reaction sites. The synthesis of porous solids is an increasingly productive approach to generating solid catalysts with larger accessible surface area, allowing more efficient catalysis. Catalysis in Confined Frameworks: Synthesis, Characterization, and Applications provides a comprehensive overview of synthesis and use of porous solids as heterogeneous catalysts. It provides detailed analysis of pore engineering, a thorough characterization of the advantages and disadvantages of porous solids as heterogeneous catalysts, and an extensive discussion of applications. The result is a foundational introduction to a cutting-edge field. Catalysis in Confined Frameworks: Synthesis, Characterization, and Applications readers will also find: An editorial team comprised of international experts with extensive experience Detailed discussion of catalyst classes including zeolites, mesoporous aluminosilicates, and more A special focus on size selective catalysis Catalysis in Confined Frameworks: Synthesis, Characterization, and Applications is an essential reference for catalytic chemists, organic chemists, materials scientists, physical chemists, and any researchers or industry professionals working with heterogeneous catalysis.
| Author | : Manas Sutradhar |
| Publisher | : Royal Society of Chemistry |
| Total Pages | : 526 |
| Release | : 2020-11-05 |
| Genre | : Science |
| ISBN | : 1839160896 |
Download Vanadium Catalysis Book in PDF, ePub and Kindle
Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast. Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.
| Author | : Ning Jiao |
| Publisher | : John Wiley & Sons |
| Total Pages | : 701 |
| Release | : 2019-07-13 |
| Genre | : Science |
| ISBN | : 1119304040 |
Download Green Oxidation in Organic Synthesis Book in PDF, ePub and Kindle
A valuable introduction to green oxidation for organic chemists interested in discovering new strategies and new reactions for oxidative synthesis Green Oxidation in Organic Synthesis provides a comprehensive introduction and overview of chemical preparation by green oxidative processes, an entry point to the growing journal literature on green oxidation in organic synthesis. It discusses both experimental and theoretical approaches for the study of new catalysts and methods for catalytic oxidation and selective oxidation. The book highlights the discovery of new reactions and catalysts in recent years, discussing mechanistic insights into the green oxidative processes, as well as applications in organic synthesis with significant potential to have a major impact in academia and industry. Chapters are organized according to the functional groups generated in the reactions, presenting interesting achievements for functional group formation by green oxidative processes with O2, H2O2, photocatalytic oxidation, electrochemical oxidation, and enzymatic oxidation. The mechanisms of these novel transformations clearly illustrated. Green Oxidation in Organic Synthesis will serve as an excellent reference for organic chemists interested in discovering new strategies for oxidative synthesis which address the priorities of green and sustainable chemistry.
| Author | : Jean-Baptiste Sortais |
| Publisher | : John Wiley & Sons |
| Total Pages | : 368 |
| Release | : 2021-08-31 |
| Genre | : Technology & Engineering |
| ISBN | : 3527826114 |
Download Manganese Catalysis in Organic Synthesis Book in PDF, ePub and Kindle
Manganese Catalysis in Organic Synthesis A must-read reference for anyone interested in catalyst design and sustainable organic synthesis In Manganese Catalysis in Organic Synthesis, distinguished researcher Jean-Baptiste Sortais delivers an insightful and robust overview of the use of manganese in homogenous catalysis. The editor includes papers from authoritative academics describing the organometallic precursors used to develop manganese catalysts and covers critical applications in organic synthesis, including reduction to oxidation reactions, C-C, C-N, C-X bond formation reactions, cross-coupling reactions, C-H bond activation to dihydroxylation and epoxidation reactions. Manganese Catalysis in Organic Synthesis is a practical resource for every organic chemist in academia and industry with an interest in non-noble metal catalysis, organic synthesis, and sustainable chemistry. It is intuitively and clearly organized, covering the most important synthetic procedures using homogenous manganese catalysts. It is also the ideal companion to works like Cobalt Catalysis in Organic Synthesis, Nickel Catalysis in Organic Synthesis, and Iron Complexes in Catalysis. Readers will also enjoy: Thorough introductions to organometallic manganese compounds in organic synthesis and manganese-catalyzed hydrogenation and hydrogen transfer reactions A comprehensive exploration of manganese-catalyzed hydrogen borrowing reactions and dehydrogenative coupling reactions Practical discussions of manganese-catalyzed hydrosilylation and hydroboration reactions and manganese-catalyzed electro- and photocatalysis transformations In-depth examinations of manganese-catalyzed C-H oxygenation reactions and manganese-catalyzed organometallic C-H activation Insightful treatments of manganese-catalyzed cross-coupling processes and manganese(III) acetate mediated cyclizations Perfect for catalytic, organic, and pharmaceutical chemists, Manganese Catalysis in Organic Synthesis deserves a place in the libraries of researchers and professionals interested in catalyst design and sustainable organic synthesis.
| Author | : Bunsho Ohtani |
| Publisher | : Frontiers Media SA |
| Total Pages | : 163 |
| Release | : 2021-05-20 |
| Genre | : Science |
| ISBN | : 2889667863 |
Download Catalysis & Photocatalysis Editor’s Pick 2021 Book in PDF, ePub and Kindle
| Author | : Gabriele Centi |
| Publisher | : Springer |
| Total Pages | : 0 |
| Release | : 2012-11-02 |
| Genre | : Science |
| ISBN | : 9781461368724 |
Download Selective Oxidation by Heterogeneous Catalysis Book in PDF, ePub and Kindle
Selective Oxidation by Heterogeneous Catalysis covers one of the major areas of industrial petrochemical production, outlining open questions and new opportunities. It gives keys for the interpretation and analysis of data and design of new catalysts and reactions, and provides guidelines for future research. A distinctive feature of this book is the use of concept by example. Rather than reporting an overview of the literature results, the authors have selected some representative examples, the in-depth analysis of which makes it possible to clarify the fundamental, but new concepts necessary for a better understanding of the new opportunities in this field and the design of new catalysts or catalytic reactions. Attention is given not only to the catalyst itself, but also to the use of the catalyst inside the process, thus evidencing the relationship between catalyst design and engineering aspects of the process. This book provides suggestions for new innovative directions of research and indications on how to reconsider the field of selective oxidation from different perspectives, outlining that is not a mature field of research, but that new important breakthroughs can be derived from fundamental and applied research. Suggestions are offered on how to use less conventional approaches in terms of both catalyst design and analysis of the data.
| Author | : Istvan T Horvath |
| Publisher | : World Scientific |
| Total Pages | : 451 |
| Release | : 2020-03-06 |
| Genre | : Science |
| ISBN | : 9811210594 |
Download Advanced Green Chemistry - Part 2: From Catalysis To Chemistry Frontiers Book in PDF, ePub and Kindle
This book is indexed in Chemical Abstracts ServiceGreen Chemistry has evolved in response to several environmental issues in the second half of the last century, mostly due to the almost freely expanding chemical, petrochemical, and pharmaceutical industries. During the past two decades Green Chemistry grew rapidly and we can now consider this area as a mature and powerful field. Tremendous development has taken place in many important areas including renewable energy and resources, reaction environments, catalysis, synthesis, chemical biology, green polymers, and facile recycling. The combination of Green Chemistry with engineering, biology, toxicology, and physics will lead to novel interdisciplinary systems, which can now lift Green Chemistry to the next, advanced level.The editors have assembled authors among the best specialists of this growing area of research. This collection of reviews and perspectives provides an exciting vision of the more recent developments in Green Chemistry. The contents of this book illustrate the breath of the field and its role to address environmental issues. This volume will serve as a book of reference showing a panoramic view of the field and a preview of its future direction, as well as a book of inspiration for those aiming to further advance its frontiers. This volume emphasizes on the most recent developments in green catalysis, bio-sourced polymers and the study of continental organic matter for a better understanding of the carbon geochemical cycle.
| Author | : Sarah Elaine Specht |
| Publisher | : |
| Total Pages | : 133 |
| Release | : 2019 |
| Genre | : |
| ISBN | : |
Download Fundamental Studies of Selective Oxidations by Green Oxidants Over Heterogeneous Catalysts Book in PDF, ePub and Kindle
Heterogeneous catalysts are an integral part of the chemical value chain that affects our everyday standard of living. The understanding of known catalysts and development of new catalysts are crucial to improving the sustainability of the industry and society at large. This thesis explores such catalysts for three different reactions: aerobic propylene epoxidation, hydrogen peroxide mediated cyclohexene epoxidation, and oxidative dehydrogenation of propane. Epoxides and olefins are important building block chemicals that require better catalysts (or the use of a catalyst at all) to ensure long-term sustainability in their synthesis. This thesis begins by describing the catalyst characterization and reaction kinetics for aerobic propylene epoxidation over Ag/KNO[3]/CaCO[3]. We show that the reaction proceeds in a Langmuir-Hinshelwood fashion, in which propylene and oxygen interact at the catalyst surface to generate the products. We further describe the selectivity enhancement effect of carbon dioxide on the reaction, as well as the effects of water and carbon monoxide on the reaction. Following gas phase epoxidation, we then present new hexagonal tungsten oxide catalysts for the liquid phase epoxidation of cyclohexene using hydrogen peroxide as the oxidant. We demonstrate that the cation composition affects the rate of epoxide formation and pathway selectivity. Furthermore, substitution of silver into the hexagonal tungsten oxide structure shows improved pathway selectivity, albeit at slower reaction rates. Finally, we demonstrate the use of two important characterization techniques for understanding heterogeneous catalysts. We show the development of a shell-isolated nanoparticle-enhanced Raman spectroscopy method for the practical observation of heterogeneous catalysts. In the final chapter, we demonstrate the utility of electron microscopy for the understanding of heterogeneous catalysts.
