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Equilibrium Between Phases of Matter

Equilibrium Between Phases of Matter
Author: H.A.J. Oonk
Publisher: Springer Science & Business Media
Total Pages: 411
Release: 2007-10-23
Genre: Science
ISBN: 140206408X

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The first volume of this work is organized in three levels, so that the portion and importance of thermodynamics and mathematics increase from level to level. The ground level shows that basics of phase equilibria can be understood without thermodynamics provided the concept of chemical potential is introduced early. The intermediate level introduces thermodynamics, culminating in the Gibbs energy as the arbiter for equilibrium. At the third level the accent is on binary systems, where one or more phases are solutions of the components. Priority is given throughout to the thermodynamic assessment of experimental data. 200 exercises are included with solutions.


Equilibrium Between Phases of Matter

Equilibrium Between Phases of Matter
Author: M.H.G. Jacobs
Publisher: Springer Science & Business Media
Total Pages: 305
Release: 2012-03-02
Genre: Science
ISBN: 9400719485

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The Second Volume of “Equilibrium between Phases of Matter”, when compared with the First Volume, by H.A.J. Oonk and M.T. Calvet, published in 2008, amounts to an extension of subjects, and a deepening of understanding. In the first three sections of the text an extension is given of the theory on isobaric binary systems. The fourth section gives an account of the thermodynamic analyses of four isobaric binary key systems, highlighting the power of empirical, (exo)thermodynamic correlations. The fifth section is devoted to the thermodynamic description of ternary systems. The last three sections concentrate on the properties of materials, and the phase behaviour of systems under the conditions of high temperature and high pressure – conditions that prevail in the interior of the Earth. A new equation of state is the subject of the sixth section. In the seventh section a move is made to statistical thermodynamics and vibrational models; the description of the systems has changed from mathematical to physical. The last section is on the system MgO – SiO2, looked upon from a geophysical point of view. Throughout the work high priority is given to the thermodynamic assessment of experimental data; numerous end-of-section exercises and their solutions are included. Along with the First Volume, the work is useful for materials scientists and geophysicists as a reference text. Audience Volume II is a lecture book for postgraduate students in chemistry, chemical engineering, geology and metallurgy. It is highly useful as a recommended text for teachers and researchers in all fields of materials science.


Equilibrium Statistical Physics

Equilibrium Statistical Physics
Author: M. Baus
Publisher: Springer Science & Business Media
Total Pages: 362
Release: 2007-11-15
Genre: Science
ISBN: 3540746323

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This is a textbook which gradually introduces the student to the statistical mechanical study of the different phases of matter and to the phase transitions between them. Throughout, only simple models of both ordinary and soft matter are used but these are studied in full detail. The subject is developed in a pedagogical manner, starting from the basics, going from the simple ideal systems to the interacting systems, and ending with the more modern topics. The textbook provides the student with a complete overview, intentionally at an introductory level, of the theory of phase transitions. All equations and deductions are included.


Phase Equilibrium in Mixtures

Phase Equilibrium in Mixtures
Author: M. B. King
Publisher: Elsevier
Total Pages: 604
Release: 2013-10-22
Genre: Technology & Engineering
ISBN: 1483152413

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Phase Equilibrium in Mixtures deals with phase equilibrium and the methods of correlating, checking, and predicting phase data. Topics covered range from latent heat and vapor pressure to dilute solutions, ideal and near-ideal solutions, and consistency tests. Molecular considerations and their use for the prediction and correlation of data are also discussed. Comprised of nine chapters, this volume begins with an introduction to the role of thermodynamics and the criteria for equilibrium between phases, along with fugacity and the thermodynamic functions of mixing. The discussion then turns to some of the phase phenomena which may be encountered in chemical engineering practice; methods of correlating and extending vapor pressure data and practical techniques for calculating latent heats from these data; the behavior of dilute solutions both at low and high pressures for reacting and non-reacting systems; and the behavior of ideal and near-ideal solutions. The remaining chapters explore non-ideal solutions at normal pressures; practical methods for testing the thermodynamic consistency of phase data; and the extent to which the broad aspects of phase behavior may be interpreted in the light of simple molecular considerations. This book is intended primarily for graduate chemical engineers but should also be of interest to those graduates in physics or chemistry who need to use phase equilibrium data.


Phase Diagrams and Heterogeneous Equilibria

Phase Diagrams and Heterogeneous Equilibria
Author: Bruno Predel
Publisher: Springer Science & Business Media
Total Pages: 357
Release: 2013-03-09
Genre: Science
ISBN: 366209276X

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This advanced comprehensive textbook introduces the practical application of phase diagrams to the thermodynamics of materials consisting of several phases. It describes the fundamental physics and thermodynamics as well as experimental methods, treating all material classes: metals, glasses, ceramics, polymers, organic materials, aqueous solutions. With many application examples and realistic cases from chemistry and materials science, it is intended for students and researchers in chemistry, metallurgy, mineralogy, and materials science as well as in engineering and physics. The authors treat the nucleation of phase transitions, the production and stability of technologically important metastable phases, and metallic glasses. Also concisely presented are the thermodynamics and composition of polymer systems. This innovative text puts this powerful analytical approach into a readily understandable and practical context, perhaps for the first time.


The Thermodynamics of Phase and Reaction Equilibria

The Thermodynamics of Phase and Reaction Equilibria
Author: Ismail Tosun
Publisher: Newnes
Total Pages: 736
Release: 2012-10-17
Genre: Science
ISBN: 0444594973

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This book provides you with a sound foundation for understanding abstract concepts (eg physical properties such as fugacity, etc or chemical processes, ie distillation, etc) of phase and reaction equilibria and shows you how to apply these concepts to solve practical problems using numerous and clear examples.


Phase Theory

Phase Theory
Author: H.A.J. Oonk
Publisher: Elsevier
Total Pages: 284
Release: 2012-12-02
Genre: Science
ISBN: 0444599339

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Studies in Modern Thermodynamics, 3: Phase Theory: The Thermodynamics of Heterogeneous Equilibria focuses on the processes, methodologies, principles, and approaches employed in the determination of the thermodynamics of heterogeneous equilibria. The publication first elaborates on thermodynamic background, phase rule, and general relations for binary equilibria. Discussions focus on linear contributions, G-curves and phase diagram, function changes, Clapeyron's equation, derivation of phase rule, pressure and temperature, heat capacity, enthalpy, and Gibbs energy. The manuscript then examines demixing, isothermal liquid-vapor equilibria, isobaric equilibria between two mixed states, and isobaric equilibria between unmixed solid and mixed liquid state. Topics include phase diagrams, pure solid component with liquid mixture, equilibrium between two ideal states, calculation of phase diagrams, and types of phase diagram. The text ponders on the interpretation of TX phase diagrams and retrograde equilibrium curves, including retrograde solubility, regions of demixing, excess parameters, and eutectic systems. The publication is a valuable reference for researchers wanting to dig deeper into the thermodynamics of heterogeneous equilibria.


Phase Equilibria, Phase Diagrams and Phase Transformations

Phase Equilibria, Phase Diagrams and Phase Transformations
Author: Mats Hillert
Publisher: Cambridge University Press
Total Pages: 525
Release: 2007-11-22
Genre: Technology & Engineering
ISBN: 1139465864

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Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.


Principles of Modern Chemistry

Principles of Modern Chemistry
Author: David W. Oxtoby
Publisher: Harcourt Brace College Publishers
Total Pages: 244
Release: 1998-07-01
Genre:
ISBN: 9780030247521

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PRINCIPLES OF MODERN CHEMISTRY has dominated the honors and high mainstream general chemistry courses and is considered the standard for the course. The fifth edition is a substantial revision that maintains the rigor of previous editions but reflects the exciting modern developments taking place in chemistry today. Authors David W. Oxtoby and H. P. Gillis provide a unique approach to learning chemical principles that emphasizes the total scientific process'from observation to application'placing general chemistry into a complete perspective for serious-minded science and engineering students. Chemical principles are illustrated by the use of modern materials, comparable to equipment found in the scientific industry. Students are therefore exposed to chemistry and its applications beyond the classroom. This text is perfect for those instructors who are looking for a more advanced general chemistry textbook.


Concept Development Studies in Chemistry

Concept Development Studies in Chemistry
Author: John S. Hutchinson
Publisher: Orange Grove Texts Plus
Total Pages: 0
Release: 2009-09-24
Genre: Chemistry
ISBN: 9781616100216

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This is an on-line textbook for an Introductory General Chemistry course. Each module develops a central concept in Chemistry from experimental observations and inductive reasoning. This approach complements an interactive or active learning teaching approach. Additional multimedia resources can be found at: http: //cnx.org/content/col10264/1.5