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Emulsion Polymerisation and Latex Applications

Emulsion Polymerisation and Latex Applications
Author: Christopher D. Anderson
Publisher: iSmithers Rapra Publishing
Total Pages: 160
Release: 2003
Genre: Science
ISBN: 9781859573815

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The term latex covers emulsion polymers, polymer dispersions and polymer colloids. This review report provides a general overview of the emulsion polymerisation processes and explains how the resulting latices are used in industrial applications. The classes of emulsion polymers are surveyed and the commercial technologies and potential future uses discussed. An additional indexed section containing several hundred abstracts from the Polymer Library gives useful references for further reading.


Chemistry and Technology of Emulsion Polymerisation

Chemistry and Technology of Emulsion Polymerisation
Author: A. M. van Herk
Publisher: John Wiley & Sons
Total Pages: 332
Release: 2013-05-13
Genre: Technology & Engineering
ISBN: 1118638360

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Chemistry and Technology of Emulsion Polymerisation 2e provides a practical and intuitive explanation of emulsion polymerization, in combination with both conventional and controlled radical polymerization. For those working in industry, coupling theory with everyday practice can be difficult. By carefully explaining the principles of the reaction, based on well-designed experimental investigation, the book explains how the principles relate to practical application. The second edition of this book includes a new chapter on morphology of latex particles, a rapidly progressing area where modelling the thermodynamic and kinetic aspects of phase separation and morphology has developed into a mature and powerful tool to predict and control morphology of latex particles. Another area that is rapidly progressing is the application of controlled radical polymerisation in emulsion polymerization. Controlled radical polymerisation is used in aiding encapsulation of inorganic particles like pigment particles and clay platelets. These latest developments are included in the second edition.


Principles and Applications of Emulsion Polymerization

Principles and Applications of Emulsion Polymerization
Author: Chorng-Shyan Chern
Publisher: John Wiley & Sons
Total Pages: 268
Release: 2008-10-06
Genre: Science
ISBN: 0470377933

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Up-to-date coverage of methods of emulsion polymerization This book provides a comprehensive reference on emulsion polymerization methods,focusing on the fundamental mechanisms and kinetics of each process, as well as howthey can be applied to the manufacture of environmentally friendly polymeric materials. Topics covered include: Conventional emulsion polymerization Miniemulsion polymerization Microemulsion polymerization Industrial emulsion polymerization processes (primarily the semibatch and continuous reactions systems) The role of various colloidal phenomena in emulsion polymerization Important end-use properties of emulsion polymer (latex) products Information on industrial applications in paints, coatings, adhesives, paper and board, and more This is a hands-on reference for graduate students and professionals in polymerchemistry, chemical engineering, and materials science who are involved in researchon coatings, adhesives, rubber, latex, paints, finishes, and other materials that can becreated using various methods of emulsion polymerization.


Chemistry and Technology of Emulsion Polymerisation

Chemistry and Technology of Emulsion Polymerisation
Author: A. M. van Herk
Publisher: John Wiley & Sons
Total Pages: 328
Release: 2008-04-15
Genre: Technology & Engineering
ISBN: 1405171782

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Emulsion polymerisation produces high value polymers in a low cost, environmentally friendly process. The drive to develop environmentally benign production methods for polymers has resulted in widespread development and implementation of the emulsion polymerisation technique. In addition, when combined with novel polymerisation mechanisms the process can give rise to a range of polymer products with particularly useful properties. Emulsion polymerisation is a complex process, governed by the interplay of both chemical and physical properties including polymerisation kinetics and dispersion stability. Successful industrial application relies on understanding and controlling those properties. By carefully explaining the principles of the reaction, based on well-designed experimental investigation, Chemistry and Technology of Emulsion Polymerisation provides a practical and intuitive explanation of emulsion polymerisation. In the development of industrial processes, coupling that understanding with everyday practice can be a further difficult step, so the book emphasises a clear, comprehensive and straightforward discussion to illustrate how the principles relate to practical application. Written for research chemists, technologists and engineers in the polymer, fine and specialty chemicals industries, and in university or government laboratories, this book will be particularly valuable to those early on in their careers. The comprehensive and straightforward coverage will also ensure it is an important resource for advanced courses in emulsion polymerisation.


Emulsion Polymerization and Emulsion Polymers

Emulsion Polymerization and Emulsion Polymers
Author: Peter A. Lovell
Publisher: John Wiley & Sons
Total Pages: 858
Release: 1997-04-03
Genre: Science
ISBN:

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Emulsion Polymerization and Emulsion Polymers Edited by Peter A. Lovell Manchester Materials Science Centre, UMIST, Manchester, UK and Mohamed S. El-Aasser Emulsion Polymers Institute and Department of Chemical Engineering, Lehigh University, Bethlehem, PA, USA Emulsion polymerization is a technologically and commercially important reaction used to produce synthetic polymers and latexes for a wide range of applications. It is the basis of a massive global industry that is expanding due to the versatility of the reaction and the greater realization of the ability to control properties of the polymer latexes produced. Emulsion Polymerization and Emulsion Polymers provides an up-to-date treatment of both academic and industrial aspects of the subject in a single self-contained volume. Established knowledge is integrated with latest developments and introductory chapters to give a state-of-the-art summary which is also suitable as a broad based introduction to the field. The individual chapters have been written by specialists from academia and industry and are presented in a way which ensures that the book will be of equal value to experienced researchers and students.


Emulsion Polymerization and Its Applications in Industry

Emulsion Polymerization and Its Applications in Industry
Author: V. I. Eliseeva
Publisher: Springer Science & Business Media
Total Pages: 231
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 1468416413

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There is a large body of Soviet work on emulsion polymerization, spanning a period of over three decades, that has been published primarily in the Russian language. Most of this has remained untranslated into English and hence un available to most other scientists. The value of this book lies primarily in the fact that it brings together the most important of these Soviet contributions, along with comment and analysis by the authors, who may be considered among the foremost authorities in this field in the Soviet Union. But the hundreds of literature citations go far beyond the borders of the Soviet Union and serve as an excellent bibliography of the world literature on emulsion polymerization up to the time this book was written. The book covers both fundamental and applied aspects. In the former are included discussions of particle formation mechanisms, a comprehensive theory of emulsion polymerization, copolymerization of polar monomers, and particle morphology and its implications with regard to derived film properties. Among the applied aspects are discussions of continuous emulsion polymerization, both tubular reactors and continuous stirred tank cascades, and various aspects con cerning the manufacture of some of the most important monomers, such as styrene, butadiene, vinyl acetate, methyl methacrylate, acrylonitrile, and chloroprene. This book will be an indispensable reference source for scientists who are entering the field as well as those who are experienced and who have wanted a ready access to this large body of literature.


Polymeric Dispersions: Principles and Applications

Polymeric Dispersions: Principles and Applications
Author: J.M. Asua
Publisher: Springer Science & Business Media
Total Pages: 571
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9401155127

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A comprehensive and up to date survey of the science and technology of polymeric dispersions. The book discusses the kinetics and mechanisms of polymerization in dispersed media, examines the processes controlling particle morphology, presents both off-line and on-line methods for the characterization of polymer colloids, considers reactor engineering and control, and covers a wide variety of applications, such as latex paint formulations, encapsulation of inorganic particles, reactive latexes, adhesives, paper coating, and biomedical and pharmaceutical applications. Audience: A valuable resource for scientists and engineers, academic and industrial, who are involved in the manufacture or application of polymeric dispersions.


Polymer Particles

Polymer Particles
Author: Masayoshi Okubo
Publisher: Springer Science & Business Media
Total Pages: 388
Release: 2005-02-10
Genre: Technology & Engineering
ISBN: 9783540229230

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In this special volume on polymer particles, recent trends and developments in the synthesis of nano- to micron-sized polymer particles by radical polymerization (Emulsion, Miniemulsion, Microemulsion, and Dispersion Polymerizations) of vinyl monomers in environmentally friendly heterogeneous aqueous and supercritical carbon dioxide fluid media are reviewed by prominent worldwide researchers. In addition to the important challenges and possibilities with regards to design and preparation of functionalized polymer particles of controlled size, the topics described are of great current interest due to the increased awareness of environmental issues.


Emulsion Polymerization of Vinyl Acetate

Emulsion Polymerization of Vinyl Acetate
Author: Mohamed S. El-Aasser
Publisher: Springer Science & Business Media
Total Pages: 250
Release: 2012-12-06
Genre: Science
ISBN: 9400981147

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It is particularly appropriate that this symposium on the emulsion polymeriza tion of vinyl acetate was held in recognition of the industrial importance of poly(vinyl acetate) and vinyl acetate copolymers, and their rather unique properties among emulsion polymers in general. Poly( vinyl acetate) latexes were the first synthetic polymer latexes to be made on a commercial scale: their production using polyvinyl alcohol as emulsifier began in Germany during the mid-1930s and has continued to the present day, growing steadily with the years. Indeed, poly(vinyl acetate) latexes prepared with polyvinyl alcohol are still one of the mainstays of the adhesives industry. With the passing of time, however, vinyl acetate copolymers have been developed: copolymers with maleate esters such as dibutyl maleate, acrylate esters such as ethyl acrylate and butyl acrylate, versatic acid esters, and, more recently, ethylene. These versatile copolymers have found increasing use in more sophisticated adhesives with specialized properties, adhesives for clay coatings on paper, carpet backing, and interior and exterior paints. Thus more than 45 years after the first commercial production of vinyl acetate latexes, their use is still growing, both in actual quantities and different applications. The industrial importance of vinyl acetate latexes makes the mechanism and kinetics of their emulsion polymerization of practical as well as scientific interest.


Advances in Polymer Latex Technology

Advances in Polymer Latex Technology
Author: Vikas Mittal
Publisher:
Total Pages: 0
Release: 2009
Genre: Latex
ISBN: 9781607411703

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The polymer latex technology by emulsion polymerisation offers significant advantages as compared to bulk and solution polymerisation technologies owing to the better control of heat and viscosity of the medium along with the possibility of increasing the molecular weight of the polymer chains without affecting the rate of polymerisation. These emulsion polymerisation methods have undergone significant advances in the recent years and now a days, synthesis of structured latexes with well defined morphologies and properties has been possible. The development of miniemulsion polymerisation has helped to polymerise very hydrophobic and very hydrophilic monomers, which otherwise are difficult to be polymerised with the conventional emulsion polymerisation. The combination of controlled living polymerisation methods like nitroxide mediated polymerisation, atom transfer radical polymerisation as well as reversible addition fragmentation chain transfer with the emulsion and miniemulsion polymerisation methods has resulted into the synthesis of functional block copolymer chains, graft copolymer chains and star or multi arm copolymer chains in the polymer particles. Apart from that, specific surface modifications on the surface of the emulsion particles have been achieved which have expended the area of application of such polymer particles. The kinetics and mechanism of particle generation with the living polymerisation in emulsion and miniemulsion are very complex, however, the recent advances have helped to understand these systems more clearly, thus, allowing to steer them to the advantage. Therefore, these recent advances in the latex technology need to be brought into a cumulative text in order to provide insight into the various possibilities of achieving the optimum latexes.