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Electron Transfer in Chemistry and Biology

Electron Transfer in Chemistry and Biology
Author: Alexander M. Kuznetsov
Publisher: John Wiley & Sons
Total Pages: 386
Release: 1999-01-07
Genre: Science
ISBN:

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Electron Transfer in Chemistry and Biology An Introduction to the Theory Alexander M. Kuznetsov Russian Academy of Sciences, Moscow, Russia Jens Ulstrup Technical University of Denmark, Lyngby, Denmark Electron transfer is perhaps the single most important physical event in chemical, electrochemical, photochemical, biochemical, and biophysical processes. The focus and ubiquity of electron transfer is intriguing and exciting but a coherent and comprehensive approach to this topic is at the same time a challenge. Electron Transfer in Chemistry and Biology provides a thorough and didactic approach to the theoretical basis of electron transfer phenomena. Not only does it offer a full introduction to this area and a discussion of its historical development, it also gives detailed explanations of difficult issues, for example, long-range electron transfers, stochastic and dynamic processes, and biological features. A wide variety of readers will find this volume of great interest, ranging from final year undergraduate students, postgraduate students and university lecturers, to research staff in numerous fields including medical companies, electronics industry, catalysis research and development, chemical industry and some hospitals.


Electron and Proton Transfer in Chemistry and Biology

Electron and Proton Transfer in Chemistry and Biology
Author: Achim Müller
Publisher: Elsevier Publishing Company
Total Pages: 420
Release: 1992
Genre: Science
ISBN:

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Various aspects of electron and proton transfer in chemistry and biology are described in this volume. The joint presentation was chosen for two reasons. Rapid electron and proton transfer govern cellular energetics in both the most primitive and higher organisms with photosynthetic and heterotrophic lifestyles. Further, biology has become the area where the various disciplines of science, which were previously diversified, are once again converging. The book begins with a survey of physicochemical principles of electron transfer in the gas and solid phase, with thermodynamic and photochemical driving force. Inner and outer sphere mechanisms and the coupling of electron transfer to nuclear rearrangements are reviewed. These principles are applied to construct artificial photosynthesis, leading to biological electron transfer involving proteins with transition metal and/or organic redox centres. The tuning of the free energy profile on the reaction trajectory through the protein by single amino acids or by the larger ensemble that determines the electrostatic properties of the reaction path is one major issue.Another one is the transformation of one-electron to paired-electron steps with protection against hazardous radical intermediates. The diversity of electron transport systems is represented in various chapters with emphasis on photosynthesis, respiration and nitrogenases. The book will be of interest to scientists in chemistry, physics and the life sciences.


Charge Transfer in Physics, Chemistry and Biology

Charge Transfer in Physics, Chemistry and Biology
Author: A.M. Kuznetrsov
Publisher: CRC Press
Total Pages: 637
Release: 2020-09-23
Genre: Science
ISBN: 100010270X

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This book covers the various processes of charge transfer in physics, chemistry and biology and shows the similarities and differences between them. It focuses on the physical mechanisms of the elementary processes to demonstrate their common physical nature.


Electron Transfer in Chemistry, Principles, Theories, Methods, and Techniques

Electron Transfer in Chemistry, Principles, Theories, Methods, and Techniques
Author: Vincenzo Balzani
Publisher: Wiley-VCH
Total Pages: 780
Release: 2001-05-02
Genre: Science
ISBN: 9783527299126

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Electron transfer is the most important process to take place in natural and artificial chemical systems, playing a fundamental role, for example, in photosynthesis as well as in photography. Electron transfer reactions - oxidations and reductions - are involved in, among others, a variety of energy conversion processes, analytical methods, synthetic strategies, and information processing systems. This five-volume work is the only comprehensive yet up-to-date reference on electron transfer processes. Following a foreword by Nobel prize-winner R. A. Marcus, renowned experts from all over the world provide an interdisciplinary overview of every aspect of electron transfer including theoretical-physicochemical backgrounds, latest analytical techniques to identify, monitor and measure the rate of electron transfer, utilizing electron transfer reactions in organic synthesis and catalysis, electron transfer in the gas phase or in special heterogeneous systems such as zeolites or sensitized electrodes. Other central issues are the study of biological systems and the biomimetic electron transfer processes in artificial supramolecular systems. Finally, a complete volume is dedicated to the application of electron transfer in molecular-level electronics, imaging processes and energy conversion. Each chapter is complemented by numerous tables, formulae and illustrations providing an indispensable wealth of information. All references are cross-indexed throughout the work for easy access to this highly complex topic. Whether for quickly looking-up a keyword or as a thorough introduction to a special aspect, this is an essential handbook for everyone working in the field, from experts to postgraduates, from synthetic chemists, physicochemists or biochemists to research groups in material sciences.


Advances in Electron Transfer Chemistry

Advances in Electron Transfer Chemistry
Author: Patrick S. Mariano
Publisher: Elsevier
Total Pages: 273
Release: 2013-10-22
Genre: Science
ISBN: 1483100936

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Advances in Electron Transfer Chemistry, Volume 3 presents studies that discuss findings in the various aspects of electron chemistry. The book is comprised of four chapters; each chapter reviews a work that tackles an issue in electron transfer chemistry. Chapter 1 discusses the photoinduced electron transfer in flexible biaryl donor-acceptor molecules. Chapter 2 tackles light-induced electron transfer in inorganic systems in homogeneous and heterogeneous phases. The book also covers internal geometry relaxation effects on electron transfer rates of amino-centered systems. The sequential electron transfer reactions catalyzed by cytochrome p-450 enzymes are also dealt with. The text will be of great use to researchers interested in the field of electron transfer chemistry.


Charge Transfer in Physics, Chemistry and Biology

Charge Transfer in Physics, Chemistry and Biology
Author: A.M. Kuznetrsov
Publisher: CRC Press
Total Pages: 640
Release: 2020-09-23
Genre: Science
ISBN: 1000141209

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This book covers the various processes of charge transfer in physics, chemistry and biology and shows the similarities and differences between them. It focuses on the physical mechanisms of the elementary processes to demonstrate their common physical nature.


Electron Transfer Reactions

Electron Transfer Reactions
Author: Stephan S. Isied
Publisher:
Total Pages: 472
Release: 1997
Genre: Language Arts & Disciplines
ISBN:

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Begins with a historical overview by Henry Taube. Overviews the advances pioneered by Taube, including mechanisms of electron transfer reactions, charge transfer complexes, and *p back bonding effects in metal-ligand interactions. Discusses applications of principles of electron transfer to diverse areas of chemistry and biology such as the selective and controlled oxidation of organic functional groups, polymerization catalysis, metal biological interactions with DNA, biological electron transfer reactions, and new imaging agents in diagnostic medicine.