Effects Of The Deletion Of Chemical Agent Washout On Operations At The Blue Grass Chemical Agent Destruction Pilot Plant PDF Download
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| Author | : National Academies of Sciences, Engineering, and Medicine |
| Publisher | : National Academies Press |
| Total Pages | : 53 |
| Release | : 2016-06-13 |
| Genre | : Technology & Engineering |
| ISBN | : 0309389518 |
Download Effects of the Deletion of Chemical Agent Washout on Operations at the Blue Grass Chemical Agent Destruction Pilot Plant Book in PDF, ePub and Kindle
The United States manufactured significant quantities of chemical weapons during the Cold War and the years prior. Because the chemical weapons are aging, storage constitutes an ongoing risk to the facility workforces and to the communities nearby. In addition, the Chemical Weapons Convention treaty stipulates that the chemical weapons be destroyed. The United States has destroyed approximately 90 percent of the chemical weapons stockpile located at seven sites. As part of the effort to destroy its remaining stockpile, the Department of Defense is building the Blue Grass Chemical Agent Destruction Pilot Plant (BGCAPP) on the Blue Grass Army Depot (BGAD), near Richmond, Kentucky. The stockpile stored at BGAD consists of rockets and projectiles containing the nerve agents GB and VX and the blister agent mustard. Continued storage poses a risk to the BGAD workforce and the surrounding community because these munitions are several decades old and are developing leaks. Due to public opposition to the use of incineration to destroy the BGAD stockpile, Congress mandated that non- incineration technologies be identified for use at BGCAPP. As a result, the original BGCAPP design called for munitions to be drained of agent and then for the munition bodies to be washed out using high-pressure hot water. However as part of a larger package of modifications called Engineering Change Proposal 87 (ECP-87), the munition washout step was eliminated. Effects of the Deletion of Chemical Agent Washout on Operations at the Blue Grass Chemical Agent Destruction Pilot Plant examines the impacts of this design change on operations at BGCAPP and makes recommendations to guide future decision making.
| Author | : National Academies of Sciences, Engineering, and Medicine |
| Publisher | : National Academies Press |
| Total Pages | : 53 |
| Release | : 2016-07-13 |
| Genre | : Technology & Engineering |
| ISBN | : 0309389488 |
Download Effects of the Deletion of Chemical Agent Washout on Operations at the Blue Grass Chemical Agent Destruction Pilot Plant Book in PDF, ePub and Kindle
The United States manufactured significant quantities of chemical weapons during the Cold War and the years prior. Because the chemical weapons are aging, storage constitutes an ongoing risk to the facility workforces and to the communities nearby. In addition, the Chemical Weapons Convention treaty stipulates that the chemical weapons be destroyed. The United States has destroyed approximately 90 percent of the chemical weapons stockpile located at seven sites. As part of the effort to destroy its remaining stockpile, the Department of Defense is building the Blue Grass Chemical Agent Destruction Pilot Plant (BGCAPP) on the Blue Grass Army Depot (BGAD), near Richmond, Kentucky. The stockpile stored at BGAD consists of rockets and projectiles containing the nerve agents GB and VX and the blister agent mustard. Continued storage poses a risk to the BGAD workforce and the surrounding community because these munitions are several decades old and are developing leaks. Due to public opposition to the use of incineration to destroy the BGAD stockpile, Congress mandated that non- incineration technologies be identified for use at BGCAPP. As a result, the original BGCAPP design called for munitions to be drained of agent and then for the munition bodies to be washed out using high-pressure hot water. However as part of a larger package of modifications called Engineering Change Proposal 87 (ECP-87), the munition washout step was eliminated. Effects of the Deletion of Chemical Agent Washout on Operations at the Blue Grass Chemical Agent Destruction Pilot Plant examines the impacts of this design change on operations at BGCAPP and makes recommendations to guide future decision making.
| Author | : National Research Council |
| Publisher | : National Academies Press |
| Total Pages | : 94 |
| Release | : 2005-11-25 |
| Genre | : Science |
| ISBN | : 0309096987 |
Download Interim Design Assessment for the Blue Grass Chemical Agent Destruction Pilot Plant Book in PDF, ePub and Kindle
Because of concerns about incineration, the Department of Defense plans to use alternative means to destroy the chemical agent stockpiles at the Pueblo and Blue Grass facilities. The DOD contracted with Bechtel Parsons to design and operate pilot plants for this purpose. As part of the NRC efforts to assist the DOD with its chemical demilitarization efforts, the Department requested a review and assessment of the Bechtel designs for both plants. An earlier report presented an assessment of the Pueblo design. This report provides a review of the Blue Grass Chemical Agent Destruction Pilot Plant based on review of data and information about the initial design and some intermediate design data. Among other topics, the report presents technical risk assessment issues, an analysis of delivery and disassembly operations and of agent destruction core processes, and an examination of waste treatment.
| Author | : National Academies of Sciences, Engineering, and Medicine |
| Publisher | : National Academies Press |
| Total Pages | : 194 |
| Release | : 2015-10-05 |
| Genre | : Science |
| ISBN | : 0309376432 |
Download Review Criteria for Successful Treatment of Hydrolysate at the Blue Grass Chemical Agent Destruction Pilot Plant Book in PDF, ePub and Kindle
In 1993, the United States signed the Chemical Weapons Convention (CWC), an international treaty outlawing the production, stockpiling, and use of chemical weapons. The chemical weapons stockpiles at five of the U.S. chemical weapons storage sites have now been destroyed. At those sites, the munitions were robotically opened and the chemical agent was removed, collected, and incinerated. One of the remaining sites with chemical weapons stockpiles is the Blue Grass Army Depot near Richmond, Kentucky. In this case, caustic hydrolysis will be used to destroy the agents and energetics, resulting in a secondary waste stream known as hydrolysate. Review Criteria for Successful Treatment of Hydrolysate at the Blue Grass Chemical Agent Destruction Pilot Plant develops criteria for successfully treating the hydrolysate, identifies systemization data that should factor into the criteria/decision process, suggests potential modifications to suggested treatment that would allow continued onsite processing, and assesses waste disposal procedures. This study further examines the possibility of delay or failure of the existing technology and examines possible alternatives to onsite treatment.
| Author | : National Research Council |
| Publisher | : National Academies Press |
| Total Pages | : 192 |
| Release | : 2012-10-21 |
| Genre | : Science |
| ISBN | : 0309259851 |
Download Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants Book in PDF, ePub and Kindle
January 2012 saw the completion of the U.S. Army's Chemical Materials Agency's (CMA's) task to destroy 90 percent of the nation's stockpile of chemical weapons. CMA completed destruction of the chemical agents and associated weapons deployed overseas, which were transported to Johnston Atoll, southwest of Hawaii, and demilitarized there. The remaining 10 percent of the nation's chemical weapons stockpile is stored at two continental U.S. depots, in Lexington, Kentucky, and Pueblo, Colorado. Their destruction has been assigned to a separate U.S. Army organization, the Assembled Chemical Weapons Alternatives (ACWA) Element. ACWA is currently constructing the last two chemical weapons disposal facilities, the Pueblo and Blue Grass Chemical Agent Destruction Pilot Plants (denoted PCAPP and BGCAPP), with weapons destruction activities scheduled to start in 2015 and 2020, respectively. ACWA is charged with destroying the mustard agent stockpile at Pueblo and the nerve and mustard agent stockpile at Blue Grass without using the multiple incinerators and furnaces used at the five CMA demilitarization plants that dealt with assembled chemical weapons - munitions containing both chemical agents and explosive/propulsive components. The two ACWA demilitarization facilities are congressionally mandated to employ noncombustion-based chemical neutralization processes to destroy chemical agents. In order to safely operate its disposal plants, CMA developed methods and procedures to monitor chemical agent contamination of both secondary waste materials and plant structural components. ACWA currently plans to adopt these methods and procedures for use at these facilities. The Assessment of Agent Monitoring Strategies for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants report also develops and describes a half-dozen scenarios involving prospective ACWA secondary waste characterization, process equipment maintenance and changeover activities, and closure agent decontamination challenges, where direct, real-time agent contamination measurements on surfaces or in porous bulk materials might allow more efficient and possibly safer operations if suitable analytical technology is available and affordable.
| Author | : National Research Council |
| Publisher | : National Academies Press |
| Total Pages | : 92 |
| Release | : 2005-02-18 |
| Genre | : Technology & Engineering |
| ISBN | : 0309094453 |
Download Interim Design Assessment for the Pueblo Chemical Agent Destruction Pilot Plant Book in PDF, ePub and Kindle
In 1996, Congress enacted directing the Department of Defense to assess and demonstrate technology alternatives to incineration for destruction of the chemical weapons stored at Pueblo Chemical and Blue Grass Army Depots. Since then, the National Research Council (NRC) has been carrying out evaluations of candidate technologies including reviews of engineering design studies and demonstration testing. Most recently, the NRC was asked by the Army to evaluate designs for pilot plants at Pueblo and Blue Grass. These pilot plants would use chemical neutralization for destroying the chemical agent and the energetics in the munitions stockpiles of these two depots. This report provides the interim assessment of the Pueblo Chemical Agent Destruction Pilot Plant (PCAPP) to permit adjustment of any significant problems as soon as possible. The report presents an analysis of the issues about the current PCAPP design and a series of findings and recommendations about ways to reduce concerns with involve the public more heavily in the process.
| Author | : National Research Council |
| Publisher | : National Academies Press |
| Total Pages | : 119 |
| Release | : 2013-10-10 |
| Genre | : Technology & Engineering |
| ISBN | : 0309287324 |
Download Assessment of Supercritical Water Oxidation System Testing for the Blue Grass Chemical Agent Destruction Pilot Plant Book in PDF, ePub and Kindle
Assessment of Supercritical Water Oxidation System Testing for the Blue Grass Chemical Agent Destruction Pilot Plant reviews and evaluates the results of the tests conducted on one of the SCWO units to be provided to Blue Grass Chemical Agent Destruction Pilot Plant. The Army Element, Assembled Chemical Weapons Alternatives (ACWA) is responsible for managing the conduct of destruction operations for the remaining 10 percent of the nation's chemical agent stockpile, stored at the Blue Grass Army Depot (Kentucky) and the Pueblo Chemical Depot (Colorado). Facilities to destroy the agents and their associated munitions are currently being constructed at these sites. The Blue Grass Chemical Agent Destruction Pilot Plant (BGCAPP) will destroy chemical agent and some associated energetic materials by a process of chemical neutralization known as hydrolysis. The resulting chemical waste stream is known as hydrolysate. Among the first-of-a-kind equipment to be installed at BGCAPP are three supercritical water oxidation (SCWO) reactor systems. These particular hydrolysate feeds present unique non-agent-related challenges to subsequent processing via SCWO due to their caustic nature and issues of salt management.This report provides recommendations on SCWO systemization testing inclusive of durability testing and discusses systemization testing objectives and concepts.
| Author | : National Research Council |
| Publisher | : National Academies Press |
| Total Pages | : 84 |
| Release | : 2008-12-14 |
| Genre | : Political Science |
| ISBN | : 0309120500 |
Download Review of Secondary Waste Disposal Planning for the Blue Grass and Pueblo Chemical Agent Destruction Pilot Plants Book in PDF, ePub and Kindle
The U.S. Army Program Manager for Assembled Chemical Weapons Alternatives (PMACWA) is charged with disposing of chemical weapons as stored at two sites: Pueblo, Colorado, and Blue Grass, Kentucky. In accordance with congressional mandates, technologies other than incineration are to be used if they are as safe and as cost effective. The weapons are to be disposed of in compliance with the Chemical Weapons Convention. Although an element of the U.S. Army, the PMACWA is responsible to the Assistant Secretary of Defense for Acquisitions, Technology, and Logistics for completing this mission. This book deals with the expected significant quantities of secondary wastes that will be generated during operations of the facilities and their closure. While there are only estimates for the waste quantities that will be generated, they provide a good basis for planning and developing alternatives for waste disposal while the plants are still in the design phase. Establishing efficient disposal options for the secondary wastes can enable more timely and cost-effective operation and closure of the facilities.
| Author | : National Research Council |
| Publisher | : National Academies Press |
| Total Pages | : 150 |
| Release | : 2015-03-26 |
| Genre | : Technology & Engineering |
| ISBN | : 0309317916 |
Download Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant Book in PDF, ePub and Kindle
One of the last two sites with chemical munitions and chemical materiel is the Pueblo Chemical Depot in Pueblo, Colorado. The stockpile at this location consists of about 800,000 projectiles and mortars, all of which are filled with the chemical agent mustard. Under the direction of the Assembled Chemical Weapons Alternative Program (ACWA), the Army has constructed the Pueblo Chemical Agent Destruction Pilot Plant (PCAPP) to destroy these munitions. The primary technology to be used to destroy the mustard agent at PCAPP is hydrolysis, resulting in a secondary waste stream referred to as hydrolysate. PCAPP features a process that will be used to treat the hydrolysate and the thiodiglycol - a breakdown product of mustard - contained within. The process is a biotreatment technology that uses what are known as immobilized cell bioreactors. After biodegradation, the effluent flows to a brine reduction system, producing a solidified filter cake that is intended to be sent offsite to a permitted hazardous waste disposal facility. Water recovered from the brine reduction system is intended to be recycled back through the plant, thereby reducing the amount of water that is withdrawn from groundwater. Although biotreatment of toxic chemicals, brine reduction, and water recovery are established technologies, never before have these technologies been combined to treat mustard hydrolysate. At the request of the U.S. Army, Review Criteria for Successful Treatment of Hydrolysate at the Pueblo Chemical Agent Destruction Pilot Plant reviews the criteria for successfully treating the hydrolysate. This report provides information on the composition of the hydrolysate and describes the PCAPP processes for treating it; discusses stakeholder concerns; reviews regulatory considerations at the federal, state, and local levels; discusses Department of Transportation regulations and identifies risks associated with the offsite shipment of hydrolysate; establishes criteria for successfully treating the hydrolysate and identifies systemization data that should factor into the criteria and decision process for offsite transport and disposal of the hydrolysate; and discusses failure risks and contingency options as well as the downstream impacts of a decision to ship hydrolysate offsite.
| Author | : National Research Council |
| Publisher | : National Academies Press |
| Total Pages | : 62 |
| Release | : 2008-04-26 |
| Genre | : Political Science |
| ISBN | : 0309115159 |
Download Review and Assessment of Developmental Issues Concerning the Metal Parts Treater Design for the Blue Grass Chemical Agent Destruction Pilot Plant Book in PDF, ePub and Kindle
The United States is in the process of destroying its chemical weapons stockpile. In 1996, Congress mandated that DOD demonstrate and select alternative methods to incineration at the Blue Grass and Pueblo sites. The Assembled Chemical Weapons Alternatives (ACWA) program was setup to oversee the development of these methods, and pilot plants were established at both sites. One of the new technologies being developed at the Blue Grass pilot plant are metal parts treaters (MPTs) to be used for the empty metal munitions cases. During recent testing, some issues arose with the MPTs that caused the ACWA to request a review by the NRC to investigate and determine their causes. This book presents a discussion of the MPT system; an assessment of the MPT testing activities; an analysis of thermal testing, modeling, and predicted throughput of the MPT; and an examination of the applicability of munitions treatment units under development at Pueblo for the Blue Grass pilot plant.
