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Effects of Oil Modification on Aging Characteristics of Asphalt Materials

Effects of Oil Modification on Aging Characteristics of Asphalt Materials
Author: Ryan Sylla
Publisher:
Total Pages: 55
Release: 2015
Genre: Asphalt
ISBN:

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Thermal induced cracking of asphalt mixtures is currently recognized as one of the primary distresses of asphalt pavements in cold climate regions. Thermal cracking is caused by cold temperatures, which results in the asphalt mixture becoming brittle and less capable of tolerating and relaxing thermally induced stresses. The contraction of the asphalt pavement due to decreasing temperature combined with the underlying base restraining any movement causes stress build up in the pavement until the ultimate strength is reached of the asphalt mixture, which leads to thermal crack formation. Although there are many proven asphalt modification methods to improve the asphalt performance at high service temperatures, oil modification is one of few methods that can address the low temperature distresses. Although the use of oil modifiers is common in today’s asphalt industry, oil modification’s effects to the aging mechanisms of the asphalt is relatively unknown. This study focuses on determining the implications on the aging process when using oil modifiers in asphalt binder and asphalt mastic phases. In this thesis three different oils (paraffinic, refined waste, and bio oil) were evaluated for their effects to the aging mechanisms in comparison with the unmodified base binder. The characterization of these materials was conducted by two approaches including: a.) Superpave linear viscoelastic approach using the Bending Beam Rheometer (BBR) and b.) Fracture mechanics approach using the Single Edge Notched Beam (SENB) test. In order to capture the effects of aging, the relative changes in performance were monitored through three stages of aging that aim to simulate the asphalt binder at different times within a pavement’s service life. The aging behavior of oil modified binders was also captured in the mastic phase, which is a more representative state of the continuous phase in an asphalt pavement in comparison to just the binder phase. Results indicate that the oil modification significantly effects the binder phase, but does not significantly affect the mastic phase. Binder results indicate the overall aging resistance of asphalt binder is slightly improved with oil modification and the time that aging occurs within the aging cycle is significantly altered in comparison with the unmodified binder. However, the refined waste oil in higher concentrations demonstrated detrimental effects to the aging characteristics of the binder. Mastic performance results showed little correlation with the binder performance indicating that the filler is a dominating factor. However, the mineral filler type (granite vs limestone) noticeably influenced the resulting performance of the mastics. Overall, this study concludes that oil modification can significantly alter the aging mechanisms of the binder, however these changes in binder performance do not correlate well to performance in the mixture phase.


Investigation of the Effect of Oil Modification on Critical Characteristics of Asphalt Binders

Investigation of the Effect of Oil Modification on Critical Characteristics of Asphalt Binders
Author:
Publisher:
Total Pages: 0
Release: 2013
Genre:
ISBN:

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Thermally induced cracking of asphalt pavement continues to be a serious issue in cold climate regions as well as in areas which experience extreme daily temperature differentials. Low temperature cracking of asphalt pavements is attributed to thermal stresses and strains developed during cooling cycles. Improving asphalt binder low temperature fracture and stiffness properties continues to be a subject of particular concern. Therefore, significant amount of research has been focused on improving asphalt binder properties through modification. In recent years, wide ranges of oil based modifications have been introduced to improve asphalt binder performance, especially at the low service temperatures. Although, significant use of these oils is seen in practice, knowledge of the fundamental mechanisms of oil modification and their properties for achieving optimum characteristics is limited. Hence, this study focuses on better understanding of the effect of oil modifiers which would help better material selection and achieve optimum performance in terms of increasing the life span of pavements. In this study, the effect of oil modification on the rheological properties of the asphalt binder is investigated. To examine the effect of oil modification on binder characteristics, low temperature properties as well as high temperature performance of oil modified binders were evaluated. It is found that oils vary in their effects on asphalt binder performance. However, for all oils used in the study, adding an oil to binder can improve binder low temperature performance, and this result mainly attributed to the softening effect. In addition to that, a simple linear model is proposed to predict the performance grade of oil modified binder based on the properties of its constituents at high and low temperatures. Another part of this study focuses on the oil modification effect on asphalt binder thermal strain and stresses. A viscoelastic analytical procedure is combined with experimentally derived failure stress and strain envelopes to determine the controlling failure mechanism, strain tolerance or critical stress, in thermal cracking of oil modified binders. The low temperature failure results depict that oil modification has a good potential of improving the cracking resistance of asphalt binders during thermal cycles.


Investigation of the Effect of Oil Modification on Asphalt Binders

Investigation of the Effect of Oil Modification on Asphalt Binders
Author: Amir Golalipour
Publisher: LAP Lambert Academic Publishing
Total Pages: 240
Release: 2014-07-21
Genre:
ISBN: 9783659514753

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Thermally induced cracking of asphalt pavement continues to be a serious issue in cold climate regions as well as in areas which experience extreme daily temperature differentials. Low temperature cracking of asphalt pavements is attributed to thermal stresses and strains developed during cooling cycles. Improving asphalt binder low temperature fracture and stiffness properties continues to be a subject of particular concern. Therefore, significant amount of research has been focused on improving asphalt binder properties through modification. In recent years, wide ranges of oil based modifications have been introduced to improve asphalt binder performance, especially at the low service temperatures. Although, significant use of these oils is seen in practice, knowledge of the fundamental mechanisms of oil modification and their properties for achieving optimum characteristics is limited. Hence, this study focuses on better understanding of the effect of oil modifiers which would help better material selection and achieve optimum performance in terms of increasing the life span of pavements.


Superpave Mix Design

Superpave Mix Design
Author: Asphalt Institute
Publisher:
Total Pages: 102
Release: 2001-01-01
Genre: Asphalt
ISBN: 9781934154175

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Microstructural Characterization of the Chemo-mechanical Behavior of Asphalt in Terms of Aging and Fatigue Performance Properties

Microstructural Characterization of the Chemo-mechanical Behavior of Asphalt in Terms of Aging and Fatigue Performance Properties
Author: Robert Grover Allen
Publisher:
Total Pages:
Release: 2013
Genre:
ISBN:

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The study of asphalt chemo-mechanics requires a basic understanding of the physical properties and chemical composition of asphalt and how these properties are linked to changes in performance induced by chemical modifications. This work uniquely implements the framework of chemo-mechanics by investigating two types of chemical modification processes, natural (oxidative aging) and synthetic (chemical doping) as they relate not only to macro-scale properties of asphalt binder but also to the asphalt microstructure and nanorheology. Furthermore, this study demonstrates the application of atomic force microscopy (AFM) imaging and the extraction of nano-scale engineering properties, i.e. elastic modulus, relaxation modulus, and surface energy, as a method to predict performance related to the fatigue characteristics of asphalt binders by modeling intrinsic material flaws present amongst phase interfaces. It was revealed that oxidative aging induces substantial microstructural changes in asphalt, including variations in phase structure, phase properties, and phase distribution. It has also been shown that certain asphalt chemical parameters have a consistent and measureable effect on the asphalt microstructure that is observed with AFM. In fact, particular phases that emerged via chemical doping revealed a surprising correlation between oxidative aging and the saturates chemical parameter of asphalt in terms of how they explicitly impact durability and performance of asphalt. By implementing a crack initiation model -- which requires measureable microstructural characteristics as an input parameter -- it was found that microstructural flaws (depending on the extremity) can have a more profound impact on asphalt performance than the properties of the material located between the flaws. It was also discovered by comparing the findings to performance data in the Strategic Highway Research Program's (SHRP's) Materials Reference Library (MRL), that the crack initiation model predicts very similar performance as the SHRP's distress resistance indicators. Overall, this body of work yields improved input values for asphalt prediction models and serves as the basis for ongoing studies in the areas of asphalt chemical mapping, modeling of nano-damage, and nano-modification using AFM. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/149372


Testing and Characterization of Asphalt Materials and Pavement Structures

Testing and Characterization of Asphalt Materials and Pavement Structures
Author: Kun Zhang
Publisher: Springer
Total Pages: 179
Release: 2018-07-11
Genre: Science
ISBN: 3319957899

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This book presents new studies dealing with the attempts made by the scientists and practitioners to address contemporary issues in pavement engineering such as aging and modification of asphalt binders, performance evaluation of warm mix asphalt, and mechanical-based pavement structure analysis, etc.. Asphalt binder and mixture have been widely used to construct flexible pavements. Mechanical and Chemical characterizations of asphalt materials and integration of these properties into pavement structures and distresses analysis are of great importance to design a sustainable flexible pavement. This book includes discusses and new results dealing with these issues. Papers were selected from the 5th GeoChina International Conference 2018 – Civil Infrastructures Confronting Severe Weathers and Climate Changes: From Failure to Sustainability, held on July 23 to 25, 2018 in HangZhou, China.


Handbook of Induction Heating

Handbook of Induction Heating
Author: Valery Rudnev
Publisher: CRC Press
Total Pages: 816
Release: 2017-07-14
Genre: Science
ISBN: 1351643762

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The second edition of the Handbook of Induction Heating reflects the number of substantial advances that have taken place over the last decade in theory, computer modeling, semi-conductor power supplies, and process technology of induction heating and induction heat treating. This edition continues to be a synthesis of information, discoveries, and technical insights that have been accumulated at Inductoheat Inc. With an emphasis on design and implementation, the newest edition of this seminal guide provides numerous case studies, ready-to-use tables, diagrams, rules-of-thumb, simplified formulas, and graphs for working professionals and students.


RILEM 252-CMB Symposium

RILEM 252-CMB Symposium
Author: Lily D. Poulikakos
Publisher: Springer
Total Pages: 315
Release: 2018-09-12
Genre: Technology & Engineering
ISBN: 3030004767

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This volume contains the Proceedings of the RILEM TC 252-CMB International Symposium on the Chemo-Mechanical Characterization of Bituminous Materials. The Symposium was attended by researchers and practitioners from different fields presenting the latest findings in the chemical, mechanical, and microstructural characterization of bituminous materials. The book offers new and cutting edge papers on innovative techniques for the characterization of bituminous materials, gaining new insights into current issues such as effects of aging, moisture, and temperature.


Shell Bitumen Handbook

Shell Bitumen Handbook
Author: Robert Hunter
Publisher: ICE Publishing
Total Pages: 0
Release: 2015-01-28
Genre: Technology & Engineering
ISBN: 9780727758378

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Shell has been at the forefront of bitumen technology for over 90 years, and continues to play a leading role in global bitumen research and development. The Shell Bitumen Handbook is an authoritative source of information on bitumen use in road pavements around the world.