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Dynamics of Gas-Surface Scattering

Dynamics of Gas-Surface Scattering
Author: Frank O. Goodman
Publisher: Elsevier
Total Pages: 352
Release: 2012-12-02
Genre: Science
ISBN: 0323154611

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Dynamics of Gas-Surface Scattering deals with the dynamics of scattering as inferred from known properties of gases and solids. This book discusses measurements of spatial distributions of scattered atomic and molecular streams, and of the energy and momentum which gas particles exchange at solid surfaces. It also considers two regimes of scattering, both of which are associated with a lower range of incident gas energies: the thermal and structure scattering regimes. Comprised of 10 chapters, this book opens with a brief historical overview of the early experiments that investigated the dynamics of scattering of gases by surfaces. The discussion then turns to some elements of the kinetic theory of gases; intermodular potentials and interaction regimes; and classical-mechanical lattice models used in gas-surface scattering theory. The applications of molecular beams to the study of gas-surface scattering phenomena are also described. The remaining chapters focus on experiments and theories on scattering of molecular streams by surfaces of solids, with emphasis on thermal and structure regimes of inelastic scattering; quantum theory of gas-surface scattering; and quantum mechanical scattering phenomena. This text concludes with an analysis of energy exchange processes that may occur when a solid surface is completely immersed in a still gas. This monograph will be a valuable resource for students and practitioners of physics, chemistry, and applied mathematics.


Dynamics of Gas-Surface Interactions

Dynamics of Gas-Surface Interactions
Author: Ricardo Diez Muino
Publisher: Springer Science & Business Media
Total Pages: 439
Release: 2013-02-26
Genre: Science
ISBN: 3642329551

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This book gives a representative survey of the state of the art of research on gas-surface interactions. It provides an overview of the current understanding of gas surface dynamics and, in particular, of the reactive and non-reactive processes of atoms and small molecules at surfaces. Leading scientists in the field, both from the theoretical and the experimental sides, write in this book about their most recent advances. Surface science grew as an interdisciplinary research area over the last decades, mostly because of new experimental technologies (ultra-high vacuum, for instance), as well as because of a novel paradigm, the ‘surface science’ approach. The book describes the second transformation which is now taking place pushed by the availability of powerful quantum-mechanical theoretical methods implemented numerically. In the book, experiment and theory progress hand in hand with an unprecedented degree of accuracy and control. The book presents how modern surface science targets the atomic-level understanding of physical and chemical processes at surfaces, with particular emphasis on dynamical aspects. This book is a reference in the field.


Dynamics of Gas-Surface Interactions

Dynamics of Gas-Surface Interactions
Author:
Publisher:
Total Pages: 59
Release: 1996
Genre:
ISBN:

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A wide variety of gas-surface-and electron-surface scattering experiments, supported by lattice dynamics, molecular dynamics, and scattering calculations were carried out under the auspices of this grant. These studies were motivated by a desire to understand and control surface reactions, such as surface oxidation, the technological need to characterize the physical properties of thin films and surfaces, and the desire to understand how energy and momentum are exchanged at an interface subjected to gas-surface or electron-surface collisions. Experiments involved clean, alloyed, oxidized, and stepped metallic interfaces. Surface phonon dispersion relations, and hence surface forcefields, for clean and adsorbate covered systems were determined using inelastic atom and electron scattering, providing a microscopic basis for assessing structural stability at interfaces. Major advances occurred in our understanding of the forces which are present at atomic-level steps, as well as in the area of metallic oxidation, including oxide nucleation. Synergistic effects involving electrons were shown to significantly modify metallic oxidation kinetics. Other projects dealt with alloy surface structure and stability, adsorbate negative ion resonances, dipole interactions of adsorbates, spectroscopy of frustrated low energy adsorbate vibrational modes, molecular dynamics simulations of surface vibrational dynamics, and anharmonicity in surface potentials. p1.


Dynamics of Gas-Surface Interaction

Dynamics of Gas-Surface Interaction
Author: Giorgio Benedek
Publisher: Springer Science & Business Media
Total Pages: 295
Release: 2012-12-06
Genre: Science
ISBN: 3642864554

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In recent decades surface science has experienced a large growth in connection with the development of various experimental techniques which are able to characterize solid surfaces through the observation of the scattering of ions, electrons, photons or atoms. These methods of investigation, known under different labels such as LEED, AES, XPS, UPS, etc. have been extensively applied in describing the structure, morphology, and chemical and physical properties of crystal surfaces and interfaces of a large variety of materials of interest in solid-state physics, electronics, metallurgy, biophysics, and heterogeneous catalysis. Among these methods we wish to emphasize molecular beam scattering from solid surfaces. ~lolecular beam scattering has gone through a large development in the last ten years. In this decade a large number of laboratories have used this method to study various clean and adsorbate-covered surfaces. The technique is nonetheless quite old. It dates back to the beginning of the thirties, when Estermann and Stern performed the first atom diffraction experiment proving the wave nature of atoms. In the following years the entire subject of gas-surface interaction was considered a branch of rarefied gas dynamics and developed in connection with aerospace research. Attention was then given to the integral properties of gas-solid interactions (sticking and energy accomodation, mean momentum transfer) rather than to atom-surface scatter ing from well-characterized surfaces.