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Direct Alcohol Fuel Cells for Portable Applications

Direct Alcohol Fuel Cells for Portable Applications
Author: Alexandra M. F. R. Pinto
Publisher: Academic Press
Total Pages: 353
Release: 2018-09-08
Genre: Technology & Engineering
ISBN: 0128118989

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Direct Alcohol Fuel Cells for Portable Applications: Fundamentals, Engineering and Advances presents the fundamental concepts, technological advances and challenges in developing, modeling and deploying fuel cells and fuel cell systems for portable devices, including micro and mini fuel cells. The authors review the fundamental science of direct alcohol fuel cells, covering, in detail, thermodynamics, electrode kinetics and electrocatalysis of charge-transfer reactions, mass and heat transfer phenomena, and basic modeling aspects. In addition, the book examines other fuels in DAFCs, such as formic acid, ethylene glycol and glycerol, along with technological aspects and applications, including case studies and cost analysis. Researchers, engineering professionals, fuel cell developers, policymakers and senior graduate students will find this a valuable resource. The book’s comprehensive coverage of fundamentals is especially useful for graduate students, advanced undergraduate students and those new to the field. Provides a comprehensive understanding of the fundamentals of DAFCs and their basic components, design and performance Presents current and complete information on the state-of-the-art of DAFC technology and its most relevant challenges for commercial deployment Includes practical application examples, problems and case studies Covers the use of other fuels, such as formic acid, ethylene glycol and glycerol


Direct Alcohol Fuel Cells

Direct Alcohol Fuel Cells
Author: Horacio R. Corti
Publisher: Springer Science & Business Media
Total Pages: 377
Release: 2013-12-02
Genre: Science
ISBN: 9400777086

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Direct Alcohol Fuel Cells: Materials, Performance, Durability and Applications begins with an introductory overview of direct alcohol fuel cells (DAFC); it focuses on the main goals and challenges in the areas of materials development, performance, and commercialization. The preparation and the properties of the anodic catalysts used for the oxidation of methanol, higher alcohols, and alcohol tolerant cathodes are then described. The membranes used as proton conductors in DAFC are examined, as well as alkaline membranes, focusing on the electrical conductivity and alcohol permeability. The use of different kinds of carbon materials as catalyst supports, gas diffusion layers, and current collectors in DAFC is also discussed. State of the art of the modeling is used to estimate performance and durability. The closing chapter reviews the use of DAFC in portable equipment and mobile devices and features a detailed discussion on the mechanisms of component degradation which limits their durability. This book is written to facilitate the understanding of DAFC technology, applications, and future challenges. It is an excellent introduction for electrochemical and material engineers interested in small fuel cells as portable energy sources, scientists focused on materials science for energy production and storage, as well as policy-makers in the area of renewable energies.


Direct Liquid Fuel Cells

Direct Liquid Fuel Cells
Author: Ramiz Gültekin Akay
Publisher: Academic Press
Total Pages: 328
Release: 2020-09-28
Genre: Science
ISBN: 0128186240

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Direct Liquid Fuel Cells is a comprehensive overview of the fundamentals and specificities of the use of methanol, ethanol, glycerol, formic acid and formate, dimethyl ether, borohydride, hydrazine and other promising liquid fuels in fuel cells. Each chapter covers a different liquid fuel-based fuel cell such as: Anode catalysts of direct methanol fuel cells (DMFCs), future system designs and future trends for direct ethanol fuel cells (DEFCs), development of catalysts for direct glycerol fuel cells (DGFCs), the mechanisms of the reactions taking place at the anode and cathode electrodes, and the reported anode catalysts for direct formic acid fuel cell (DFAFC) and direct formate fuel cell (DFFC), characteristics of direct dimethyl ether fuel cell (DDMEFC), including its electrochemical and operating systems and design, the developments in direct borohydride fuel cells, the development of catalysts for direct hydrazine fuel cells (DHFCs), and also the uncommonly used liquids that have a potential for fuel cell applications including 2-propanol, ethylene glycol, ascorbic acid and ascorbate studied in the literature as well as utilization of some blended fuels. In each part, the most recent literature is reviewed and the state of the art is presented. It also includes examples of practical problems with solutions and a summarized comparison of performance, advantages, and limitations of each type of fuel cell discussed. Direct Liquid Fuel Cells is not a typical textbook but rather designed as a reference book of which any level of students (undergraduate or graduate), instructors, field specialists, industry and general audience, who benefit from current and complete understanding of the many aspects involved in the development and operation of these types of fuel cells, could make use of any chapter when necessary. Presents information on different types of direct liquid fuel cells. Explores information under each section, for specific fuel-based fuel cells in more detail in terms of the materials used. Covers three main sections: direct alcohol, organic fuel-based and inorganic fuel-based fuel cells


Nanomaterials for Direct Alcohol Fuel Cell

Nanomaterials for Direct Alcohol Fuel Cell
Author: Yixuan Wang
Publisher: CRC Press
Total Pages: 299
Release: 2016-12-01
Genre: Science
ISBN: 9814669016

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Direct alcohol fuel cells (DAFCs), such as methanol and ethanol ones, are very promising advanced power systems that may considerably reduce dependence on fossil fuels and are, therefore, attracting increased attention worldwide. Nanostructured materials can improve the performance of the cathodes, anodes, and electrolytes of DAFCs. This book focuses on the most recent advances in the science and technology of nanostructured materials for direct alcohol fuel cells, including novel non-noble or low noble metal catalysts deposited on the graphene layer and metal-free doped carbon black for oxygen electroreduction reaction, Sn-based bimetallic and trimetallic nanoparticles for alcohol electro-oxidation reaction, and novel nanomaterials for promoting proton transfer in electrolytes. In addition, the book includes chapters from not only experimentalists but also computational chemists who have worked in the development of advanced power systems for decades. Illustrated throughout with excellent figures, this multidisciplinary work is not just a reference for researchers in chemistry and materials science, but a handy textbook for advanced undergraduate- and graduate-level students in nanoscience- and nanotechnology-related courses, especially those with an interest in developing novel materials for advanced power systems.


New and Future Developments in Catalysis

New and Future Developments in Catalysis
Author: Steven L Suib
Publisher: Newnes
Total Pages: 551
Release: 2013-07-11
Genre: Science
ISBN: 044453881X

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New and Future Developments in Catalysis is a package of seven books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes.Batteries and fuel cells are considered to be environmentally friendly devices for storage and production of electricity, and they are gaining considerable attention. The preparation of the feed for fuel cells (fuel) as well as the catalysts and the various conversion processes taking place in these devices are covered in this volume, together with the catalytic processes for hydrogen generation and storage. An economic analysis of the various processes is also part of this volume and enables an informed choice of the most suitable process. Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areas A clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular case Outlines the catalytic processes applicable to energy generation and design of green processes


Direct Methanol Fuel Cell Technology

Direct Methanol Fuel Cell Technology
Author: Kingshuk Dutta
Publisher: Elsevier
Total Pages: 565
Release: 2020-02-25
Genre: Technology & Engineering
ISBN: 0128191597

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Direct Methanol Fuel Cell Technology presents the overall progress witnessed in the field of DMFC over the past decade, highlighting the components, materials, functions, properties and features, designs and configurations, operations, modelling, applications, pros and cons, social, political and market penetration, economics and future directions. The book discusses every single aspect of DMFC device technology, the associated advantages and drawbacks of state-of-the-art materials and design, market opportunities and commercialization aspects, and possible future directions of research and development. This book, containing critical analyses and opinions from experts around the world, will garner considerable interest among actual users/scientists/experts. Analyzes developments of membrane electrolytes, electrodes, catalysts, catalyst supports, bipolar plates, gas diffusion layers and flow channels as critical components of direct methanol fuel cells Includes modeling of direct methanol fuel cells to understand their scaling up potentials Discusses commercial aspects of direct methanol fuel cells in terms of market penetration, end application, cost, viability, reliability, social and commercial perception, drawbacks and prospects


Nanomaterials for Direct Alcohol Fuel Cells

Nanomaterials for Direct Alcohol Fuel Cells
Author: Fatih Sen
Publisher: Elsevier
Total Pages: 554
Release: 2021-08-23
Genre: Technology & Engineering
ISBN: 0128217138

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Nanomaterials for Direct Alcohol Fuel Cells explains nanomaterials and nanocomposites as well as the characterization, manufacturing, and design of alcohol fuel cell applications. The advantages of direct alcohol fuel cells (DAFCs) are significant for reliable and long-lasting portable power sources used in devices such as mobile phones and computers. Even though substantial improvements have been made in DAFC systems over the last decade, more effort is needed to commercialize DAFCs by producing durable, low-cost, and smaller-sized devices. Nanomaterials have an important role to play in achieving this aim. The use of nanotechnology in DAFCs is vital due to their role in the synthesis of nanocatalysts within the manufacturing process. Lately, nanocatalysts containing carbon such as graphene, carbon nanotubes, and carbon nanocoils have also attracted much attention. When compared to traditional materials, carbon-based materials have unique advantages, such as high corrosion resistance, better electrical conductivity, and less catalyst poisoning. This book also covers different aspects of nanocomposites fabrication, including their preparation, design, and characterization techniques for their fuel cell applications. This book is an important reference source for materials scientists, engineers, energy scientists, and electrochemists who are seeking to improve their understanding of how nanomaterials are being used to enhance the efficiency and lower the cost of DAFCs. Shows how nanomaterials are being used for the design and manufacture of DAFCs Explores how nanotechnology is being used to enhance the synthesis and catalysis processes to create the next generation of fuel cells Assesses the major challenges of producing nanomaterial-based DAFCs on an industrial scale


Electrocatalysts for Low Temperature Fuel Cells

Electrocatalysts for Low Temperature Fuel Cells
Author: Thandavarayan Maiyalagan
Publisher: John Wiley & Sons
Total Pages: 618
Release: 2017-05-08
Genre: Technology & Engineering
ISBN: 3527803890

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Meeting the need for a text on solutions to conditions which have so far been a drawback for this important and trend-setting technology, this monograph places special emphasis on novel, alternative catalysts of low temperature fuel cells. Comprehensive in its coverage, the text discusses not only the electrochemical, mechanistic, and material scientific background, but also provides extensive chapters on the design and fabrication of electrocatalysts. A valuable resource aimed at multidisciplinary audiences in the fields of academia and industry.


Carbon Nanotubes and Graphene

Carbon Nanotubes and Graphene
Author: Kazuyoshi Tanaka
Publisher: Newnes
Total Pages: 458
Release: 2014-07-10
Genre: Science
ISBN: 0080982689

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Carbon Nanotubes and Graphene is a timely second edition of the original Science and Technology of Carbon Nanotubes. Updated to include expanded coverage of the preparation, purification, structural characterization, and common application areas of single- and multi-walled CNT structures, this work compares, contrasts, and, where appropriate, unitizes CNT to graphene. This much expanded second edition reference supports knowledge discovery, production of impactful carbon research, encourages transition between research fields, and aids the formation of emergent applications. New chapters encompass recent developments in the theoretical treatments of electronic and vibrational structures, and magnetic, optical, and electrical solid-state properties, providing a vital base to research. Current and potential applications of both materials, including the prospect for large-scale synthesis of graphene, biological structures, and flexible electronics, are also critically discussed. Updated discussion of properties, structure, and morphology of biological and flexible electronic applications aids fundamental knowledge discovery Innovative parallel focus on nanotubes and graphene enables you to learn from the successes and failures of, respectively, mature and emergent partner research disciplines High-quality figures and tables on physical and mathematical applications expertly summarize key information – essential if you need quick, critically relevant data


Electrocatalysis in Fuel Cells

Electrocatalysis in Fuel Cells
Author: Minhua Shao
Publisher: Springer Science & Business Media
Total Pages: 748
Release: 2013-04-08
Genre: Technology & Engineering
ISBN: 1447149114

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Fuel cells are one of the most promising clean energy conversion devices that can solve the environmental and energy problems in our society. However, the high platinum loading of fuel cells - and thus their high cost - prevents their commercialization. Non- or low- platinum electrocatalysts are needed to lower the fuel cell cost. Electrocatalysis in Fuel Cells: A Non and Low Platinum Approach is a comprehensive book summarizing recent advances of electrocatalysis in oxygen reduction and alcohol oxidation, with a particular focus on non- and low-Pt electrocatalysts. All twenty four chapters were written by worldwide experts in their fields. The fundamentals and applications of novel electrocatalysts are discussed thoroughly in the book. The book is geared toward researchers in the field, postgraduate students and lecturers, and scientists and engineers at fuel cell and automotive companies. It can even be a reference book for those who are interested in this area.