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Defects and Diffusion in Carbon Nanotubes

Defects and Diffusion in Carbon Nanotubes
Author: D.J. Fisher
Publisher: Trans Tech Publications Ltd
Total Pages: 212
Release: 2014-08-04
Genre: Technology & Engineering
ISBN: 3038266027

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Carbon nanotubes are one of the newest materials to be discovered, being barely 20 years old. They are also the most promising one, with one particular sample of multi-walled nanotube attaining a tensile strength of 63GPa, and with carbon nanotubes in general having a specific strength of up to 48000kNm/kg: effectively a direct exploitation of the covalent sp2 bonding between carbon atoms. Plastic deformation begins at about 5% strain. The nanotubes can be produced in lengths of up to 550mm, and thicknesses as small as 4.3Å; making them perfect reinforcement fibres for composites. They also have many other properties which may be useful in electronics, gas storage , etc. The present compilation focuses on the various characteristic types of defect which are found in carbon nanotubes, plus the relatively limited number of diffusion studies which have been performed. The 418 entries cover the period from 1994 to 2014.


Defects and Diffusion in Carbon Nanotubes

Defects and Diffusion in Carbon Nanotubes
Author:
Publisher:
Total Pages: 212
Release: 2014
Genre:
ISBN:

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Carbon nanotubes are one of the newest materials to be discovered, being barely 20 years old. They are also the most promising one, with one particular sample of multi-walled nanotube attaining a tensile strength of 63GPa, and with carbon nanotubes in general having a specific strength of up to 48000kNm/kg: effectively a direct exploitation of the covalent sp2 bonding between carbon atoms. Plastic deformation begins at about 5% strain. The nanotubes can be produced in lengths of up to 550mm, and thicknesses as small as 4.3Å; making them perfect reinforcement fibres for composites. They also have many other properties which may be useful in electronics, gas storage, etc. The present compilation focuses on the various characteristic types of defect which are found in carbon nanotubes, plus the relatively limited number of diffusion studies which have been performed. The 418 entries cover the period from 1994 to 2014. Keyword: carbon nanotube Abstracts of 418 articles published in a wide range of technical journals coverfirst defects in carbon nanotubes then the diffusion of various compounds through carbon nanotubes. Those on defects consider such aspects as adsorption, characterization, disclination, the effect on compressive behavior, the effect on thermal conductivity, heptagon, interstitial, pinhole, topological, andvacancy. Among the chemicals addressed in the diffusion studies are alkanes, gold, carbon dioxide, copper, iron, water, Lennard-Jones fluid, nitrogen, silicon, and simple gases. -- Carbon-- Engineering-- Materials science.


Diffusion in Carbon Allotropes

Diffusion in Carbon Allotropes
Author: David J. Fisher
Publisher: Trans Tech Publications Ltd
Total Pages: 210
Release: 2013-06-13
Genre: Technology & Engineering
ISBN: 303826153X

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Carbon has always been an essential feature of human civilisation (not to mention the human constitution), whether as mere fuel, as an expensive bauble or as an essential component of those two supporting pillars (organic chemicals, steel) of the industrial revolution. Even since its recognition as an element, 21?4 centuries ago, it has never ceased to offer new surprises and properties. Just decades ago, students had to contend with only two main forms, graphite and diamond, but nowadays there is a plethora of nanotubes, fullerenes, graphenes, etc. The present volume offers a compilation (over 400 items) of data on mass diffusion, in all of the various known allotropes of carbon, spanning some 6 decades.


Point Defects in Carbon Nanostructures Studied by In-situ Electron Microscopy

Point Defects in Carbon Nanostructures Studied by In-situ Electron Microscopy
Author:
Publisher:
Total Pages:
Release: 2008
Genre:
ISBN:

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In the present work, the formation and migration of point defects induced by electron irradiation in carbon nanostructures, including carbon onions, nanotubes and graphene layers, were investigated by in-situ TEM. The mobility of carbon atoms normal to the layers in graphitic nanoparticles, the mobility of carbon interstitials inside SWCNTs, and the migration of foreign atoms in graphene layers or in layers of carbon nanotubes were studied. The diffusion of carbon atoms in carbon onions was investigated by annealing carbon onions and observing the relaxation of the compressed clusters in the temperature range of 1200 - 2000oC. An activation energy of 5.0±0.3 eV was obtained. This rather high activation energy for atom exchange between the layers not only prevents the exchange of carbon atoms between the layers at lower temperature but also explains the high morphological and mechanical stability of graphite nanostructures. The migration of carbon atoms in SWCNTs was investigated quantitatively by cutting SWCNT bundles repeatedly with a focused electron beam at different temperatures. A migration barrier of about 0.25 eV was obtained for the diffusion of carbon atoms inside SWCNTs. This is an experimental confirmation of the high mobility of interstitial atoms inside carbon nanotubes, which corroborates previously developed theoretical models of interstitial diffusivity. Individual Au and Pt atoms in one- or two-layered graphene planes and MWCNTs were monitored in real time at high temperatures by high-resolution TEM. The direct observation of the behavior of Au and Pt atoms in graphenic structures in a temperature range of 600 - 700°C allows us to determine the sites occupied by the metal atoms in the graphene layer and the diffusivities of the metal atoms. It was found that metal atoms were located in single or multiple carbon vacancies, not in off-plane positions, and diffused by site exchange with carbon atoms. Metal atoms showed a tendency to form clusters those.


Carbon Nanotubes: From Basic Research to Nanotechnology

Carbon Nanotubes: From Basic Research to Nanotechnology
Author: Valentin N. Popov
Publisher: Springer Science & Business Media
Total Pages: 286
Release: 2006-04-04
Genre: Mathematics
ISBN: 9781402045721

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The book comprises reviews on various topics of carbon nanotube research from specialists in the field, together with reports on on-going research. Both are intended to give a detailed picture of the remarkable properties of these one-dimensional nanostructures. Particular attention is paid to the synthesis, characterization, properties, and application of nanotubes. The book will be an indispensable introduction for the newcomers in the field as well as a valuable update for researchers in the field, for it contains the most recent developments.


Defects and Diffusion in Ceramics, 2004

Defects and Diffusion in Ceramics, 2004
Author: D.J. Fisher
Publisher: Trans Tech Publications Ltd
Total Pages: 508
Release: 2004-05-20
Genre: Technology & Engineering
ISBN: 3035707367

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This sixth volume in the series covering the latest results in the field includes abstracts of papers which appeared between the publication of Annual Retrospective V (Volumes 218-220) and the end of April 2004 (journal availability permitting).


Diffusion in Carbon Allotropes

Diffusion in Carbon Allotropes
Author:
Publisher:
Total Pages: 210
Release: 2013
Genre:
ISBN:

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Carbon has always been an essential feature of human civilisation (not to mention the human constitution), whether as mere fuel, as an expensive bauble or as an essential component of those two supporting pillars (organic chemicals, steel) of the industrial revolution. Even since its recognition as an element, 2 1/4 centuries ago, it has never ceased to offer new surprises and properties. Just decades ago, students had to contend with only two main forms, graphite and diamond, but nowadays there is a plethora of nanotubes, fullerenes, graphenes, etc. The present volume offers a compilation (over 400 items) of data on mass diffusion, in all of the various known allotropes of carbon, spanning some 6 decades. Paragraph-long abstracts of 406 research articles examine diffusion in carbon generally, in C60 and C70, diamond, graphene, and graphite. Authors and key words are indexed. The volume is part of a permanent record of findings regarding the defect solid state.


Defect Structure and Properties of Nanomaterials

Defect Structure and Properties of Nanomaterials
Author: J Gubicza
Publisher: Woodhead Publishing
Total Pages: 412
Release: 2017-03-05
Genre: Technology & Engineering
ISBN: 0081019181

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Defect Structure and Properties of Nanomaterials: Second and Extended Edition covers a wide range of nanomaterials including metals, alloys, ceramics, diamond, carbon nanotubes, and their composites. This new edition is fully revised and updated, covering important advances that have taken place in recent years. Nanostructured materials exhibit unique mechanical and physical properties compared with their coarse-grained counterparts, therefore these materials are currently a major focus in materials science. The production methods of nanomaterials affect the lattice defect structure (vacancies, dislocations, disclinations, stacking faults, twins, and grain boundaries) that has a major influence on their mechanical and physical properties. In this book, the production routes of nanomaterials are described in detail, and the relationships between the processing conditions and the resultant defect structure, as well as the defect-related properties (e.g. mechanical behavior, electrical resistance, diffusion, corrosion resistance, thermal stability, hydrogen storage capability, etc.) are reviewed. In particular, new processing methods of nanomaterials are described in the chapter dealing with the manufacturing procedures of nanostructured materials. New chapters on (i) the experimental methods for the study of lattice defects, (ii) the defect structure in nanodisperse particles, and (iii) the influence of lattice defects on electrical, corrosion, and diffusion properties are included, to further enhance what has become a leading reference for engineering, physics, and materials science audiences. Provides a detailed overview of processing methods, defect structure, and defect-related mechanical and physical properties of nanomaterials Covers a wide range of nanomaterials including metals, alloys, ceramics, diamond, carbon nanotubes, and their composites Includes new chapters covering recent advances in both processing techniques and methods for the study of lattice defects Provides valuable information that will help materials scientists and engineers highlight lattice defects and the related mechanical and physical properties


Carbon Nanotubes

Carbon Nanotubes
Author: Siva Yellampalli
Publisher: BoD – Books on Demand
Total Pages: 532
Release: 2011-07-20
Genre: Science
ISBN: 9533074973

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Carbon nanotubes are one of the most intriguing new materials with extraordinary properties being discovered in the last decade. The unique structure of carbon nanotubes provides nanotubes with extraordinary mechanical and electrical properties. The outstanding properties that these materials possess have opened new interesting researches areas in nanoscience and nanotechnology. Although nanotubes are very promising in a wide variety of fields, application of individual nanotubes for large scale production has been limited. The main roadblocks, which hinder its use, are limited understanding of its synthesis and electrical properties which lead to difficulty in structure control, existence of impurities, and poor processability. This book makes an attempt to provide indepth study and analysis of various synthesis methods, processing techniques and characterization of carbon nanotubes that will lead to the increased applications of carbon nanotubes.


Diffusion and Defect Data

Diffusion and Defect Data
Author:
Publisher:
Total Pages: 336
Release: 2004
Genre: Crystals
ISBN:

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