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Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts

Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts
Author: Isabella Nova
Publisher: Springer Science & Business Media
Total Pages: 715
Release: 2014-03-14
Genre: Science
ISBN: 1489980717

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Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts presents a complete overview of the selective catalytic reduction of NOx by ammonia/urea. The book starts with an illustration of the technology in the framework of the current context (legislation, market, system configurations), covers the fundamental aspects of the SCR process (catalysts, chemistry, mechanism, kinetics) and analyzes its application to useful topics such as modeling of full scale monolith catalysts, control aspects, ammonia injections systems and integration with other devices for combined removal of pollutants.


Control of Diesel Engine Urea Selective Catalytic Reduction Systems

Control of Diesel Engine Urea Selective Catalytic Reduction Systems
Author: Ming-Feng Hsieh
Publisher:
Total Pages: 181
Release: 2010
Genre:
ISBN:

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Abstract: A systematic nonlinear control methodology for urea-SCR systems applicable for light-to-heavy-duty Diesel engine platforms in a variety of on-road, off-road, and marine applications is developed and experimentally validated in this dissertation. Urea selective catalytic reduction (urea-SCR) systems have been proved of being able to reduce more than 90% of Diesel engine-out NOx emissions and have been favored by the automotive industry in recent years. Urea-SCR systems utilize ammonia, converted from 32.5% aqueous urea solution (AdBlue) injected at upstream of the SCR catalyst, as the reductant for NOx reductions. Because ammonia is considered a hazardous material, urea injection should be systematically controlled to avoid undesired tailpipe ammonia slip while achieving a sufficient level of SCR NOx reduction. The novelty of the control methodology is to regulate the ammonia storage distribution along the axial direction of a SCR catalyst to a staircase profile and thus to simultaneously realize high NOx reduction efficiency and low ammonia emissions. To achieve this control objective, several relevant subjects are studied, including: 1) aftertreatment system control-oriented modeling, 2) online NOx sensor ammonia cross-sensitivity correction, 3) SCR catalyst ammonia coverage ratio estimation, as well as 4) adaptive urea dosing controller design. A unique SCR system which consists of a urea injector and two SCR catalysts connected in-series with several NOx and NH3 sensors is used for the study of the proposed urea-SCR control methodology. Such a SCR system is integrated with a state-of-the-art Diesel engine and aftertreatment system (DOC-DPF). The US06 test cycle experimental results show the proposed control methodology, in comparison to a conventional control strategy, is capable of improving the SCR NOx reduction by 63% and reducing the tailpipe ammonia slip amount by 74%. The contributions of this research to the art include: 1) A novel, efficient, and generalizable urea-SCR dosing control methodology; 2) Diesel engine-DOC-DPF NO/NO2 ratio control-oriented models and observer-based estimations; 3) SCR catalyst ammonia coverage ratio estimation methods; 4) An online correction approach for NOx sensor ammonia cross-sensitivity elimination; and 5) An improved SCR control-oriented model.


Modeling and Control of a Hydrocarbon Selective Catalytic Reduction System for Diesel Exhaust

Modeling and Control of a Hydrocarbon Selective Catalytic Reduction System for Diesel Exhaust
Author: Oliver Rivera
Publisher:
Total Pages:
Release: 2012
Genre: Mechanical engineering
ISBN:

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Diesel vehicles are continually being regulated each year by tighter restrictions on exhaust emissions. Nitrogen Oxides (NOx) form one of the more difficult emissions to control. Urea based selective catalytic reduction (SCR) of NOx emissions is an evolving technology that has seen widespread implementation on over the road vehicles. However, this technology requires an on-board reductant to function properly. Hydrocarbon based SCR (HC-SCR) technology eliminates the need for an additional on-board liquid by using diesel fuel as the reductant. A review of aftertreatment systems including HC-SCR is provided in this work. This review is followed by an experimental investigation of an HC-SCR aftertreatment system fitted to a marine diesel engine. A model of the HC-SCR outlet NOx concentration is developed and validated for several operating conditions. A sensitivity analysis of the model parameters is performed, demonstrating the most influential model parameters. A controller is successfully implemented in simulation and in the laboratory environment.


The Chemistry of Pincer Compounds

The Chemistry of Pincer Compounds
Author: David Morales-Morales
Publisher: Elsevier
Total Pages: 467
Release: 2011-08-11
Genre: Science
ISBN: 0080545157

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Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties.The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds* Covers the areas in which pincer complexes have had an impact* Includes information on more recent and interesting pincer compounds not just those that are well-known


Selective Catalytic Reduction of NOx

Selective Catalytic Reduction of NOx
Author: Oliver Kröcher
Publisher: MDPI
Total Pages: 281
Release: 2018-12-14
Genre: Electronic books
ISBN: 3038973645

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This book is a printed edition of the Special Issue "Selective Catalytic Reduction of NOx" that was published in Catalysts


Comprehensive Inorganic Chemistry II

Comprehensive Inorganic Chemistry II
Author:
Publisher: Newnes
Total Pages: 7694
Release: 2013-07-23
Genre: Science
ISBN: 0080965296

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Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973


Diesel Emissions and Their Control, 2nd Edition

Diesel Emissions and Their Control, 2nd Edition
Author: W. Addy Majewski
Publisher: SAE International
Total Pages: 1135
Release: 2023-12-20
Genre: Technology & Engineering
ISBN: 1468605704

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Engineers, applied scientists, students, and individuals working to reduceemissions and advance diesel engine technology will find the secondedition of Diesel Emissions and Their Control to be an indispensablereference. Whether readers are at the outset of their learning journey orseeking to deepen their expertise, this comprehensive reference bookcaters to a wide audience.In this substantial update to the 2006 classic, the authors have expandedthe coverage of the latest emission technologies. With the industryevolving rapidly, the book ensures that readers are well-informed aboutthe most recent advances in commercial diesel engines, providing acompetitive edge in their respective fields. The second edition has alsostreamlined the content to focus on the most promising technologies.This book is rooted in the wealth of information available on DieselNet.com, where the “Technology Guide” papers offer in-depth insights. Eachchapter includes links to relevant online materials, granting readers accessto even more expertise and knowledge.The second edition is organized into six parts, providing a structuredjourney through every aspect of diesel engines and emissions control: Part I: A foundational exploration of the diesel engine, combustion, andessential subsystems. Part II: An in-depth look at emission characterization, health andenvironmental impacts, testing methods, and global regulations. Part III: A comprehensive overview of diesel fuels, covering petroleumdiesel, alternative fuels, and engine lubricants. Part IV: An exploration of engine efficiency and emission controltechnologies, from exhaust gas recirculation to engine control. Part V: The latest developments in diesel exhaust aftertreatment,encompassing catalyst technologies and particulate filters. Part VI: A historical journey through the evolution of dieselengine technology, with a focus on heavy-duty engines in the NorthAmerican market. (ISBN 9781468605693, ISBN 9781468605709, ISBN 9781468605716, DOI: 10.4271/9781468605709)


NOx Emission Control Technologies in Stationary and Automotive Internal Combustion Engines

NOx Emission Control Technologies in Stationary and Automotive Internal Combustion Engines
Author: B. Ashok
Publisher: Elsevier
Total Pages: 488
Release: 2021-11-09
Genre: Technology & Engineering
ISBN: 0128242280

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NOx Emission Control Technologies in Stationary and Automotive Internal Combustion Engines: Approaches Toward NOx Free Automobiles presents the fundamental theory of emission formation, particularly the oxides of nitrogen (NOx) and its chemical reactions and control techniques. The book provides a simplified framework for technical literature on NOx reduction strategies in IC engines, highlighting thermodynamics, combustion science, automotive emissions and environmental pollution control. Sections cover the toxicity and roots of emissions for both SI and CI engines and the formation of various emissions such as CO, SO2, HC, NOx, soot, and PM from internal combustion engines, along with various methods of NOx formation. Topics cover the combustion process, engine design parameters, and the application of exhaust gas recirculation for NOx reduction, making this book ideal for researchers and students in automotive, mechanical, mechatronics and chemical engineering students working in the field of emission control techniques. Covers advanced and recent technologies and emerging new trends in NOx reduction for emission control Highlights the effects of exhaust gas recirculation (EGR) on engine performance parameters Discusses emission norms such as EURO VI and Bharat stage VI in reducing global air pollution due to engine emissions


Advanced Direct Injection Combustion Engine Technologies and Development

Advanced Direct Injection Combustion Engine Technologies and Development
Author: H Zhao
Publisher: Elsevier
Total Pages: 325
Release: 2014-01-23
Genre: Technology & Engineering
ISBN: 1845697324

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Direct injection enables precise control of the fuel/air mixture so that engines can be tuned for improved power and fuel economy, but ongoing research challenges remain in improving the technology for commercial applications. As fuel prices escalate DI engines are expected to gain in popularity for automotive applications. This important book, in two volumes, reviews the science and technology of different types of DI combustion engines and their fuels. Volume 1 deals with direct injection gasoline and CNG engines, including history and essential principles, approaches to improved fuel economy, design, optimisation, optical techniques and their applications. Reviews key technologies for enhancing direct injection (DI) gasoline engines Examines approaches to improved fuel economy and lower emissions Discusses DI compressed natural gas (CNG) engines and biofuels