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Conjugated Polymers

Conjugated Polymers
Author: John R. Reynolds
Publisher: CRC Press
Total Pages: 718
Release: 2019-03-27
Genre: Technology & Engineering
ISBN: 1351659804

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The Fourth Edition of the Handbook of Conducting Polymers, Two-Volume Set continues to be the definitive resource on the topic of conducting polymers. Completely updated with an extensive list of authors that draws on past and new contributors, the book takes into account the significant developments both in fundamental understanding and applications since publication of the previous edition. One of two volumes comprising the comprehensive Handbook, Conjugated Polymers: Perspective, Theory, and New Materials features new chapters on the fundamental theory and new materials involved in conducting polymers. It discusses the history of physics and chemistry of these materials and the theory behind them. Finally, it details polymer and materials chemistry including such topics as conjugated block copolymers, metal-containing conjugated polymers, and continuous flow processing. Aimed at researchers, advanced students, and industry professionals working in materials science and engineering, this book covers fundamentals, recent progress, and new materials involved in conducting polymers and includes a wide-ranging listing of comprehensive chapters authored by an international team of experts.


Conjugated Polymers

Conjugated Polymers
Author: John R. Reynolds
Publisher: CRC Press
Total Pages: 832
Release: 2019-03-25
Genre: Technology & Engineering
ISBN: 1315159295

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This book covers properties, processing, and applications of conducting polymers. It discusses properties and characterization, including photophysics and transport. It then moves to processing and morphology of conducting polymers, covering such topics as printing, thermal processing, morphology evolution, conducting polymer composites, thin films


Doping in Conjugated Polymers

Doping in Conjugated Polymers
Author: Pradip Kar
Publisher: John Wiley & Sons
Total Pages: 176
Release: 2013-08-01
Genre: Technology & Engineering
ISBN: 1118816617

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An A-to-Z of doping including its definition, its importance, methods of measurement, advantages and disadvantages, properties and characteristics—and role in conjugated polymers The versatility of polymer materials is expanding because of the introduction of electro-active behavior into the characteristics of some of them. The most exciting development in this area is related to the discovery of intrinsically conductive polymers or conjugated polymers, which include such examples as polyacetylene, polyaniline, polypyrrole, and polythiophene as well as their derivatives. "Synmet" or "synthetic metal" conjugated polymers, with their metallic characteristics, including conductivity, are of special interest to researchers. An area of limitless potential and application, conjugated polymers have sparked enormous interest, beginning in 2000 when the Nobel Prize for the discovery and development of electrically conducting conjugated polymers was awarded to three scientists: Alan J. Heeger, Alan G. MacDiarmid, and Hideki Shirakawa. Conjugated polymers have a combination of properties—both metallic (conductivity) and polymeric; doping gives the conjugated polymer's semiconducting a wide range of conductivity, from insulating to low conducting. The doping process is a tested effective method for producing conducting polymers as semiconducting material, providing a substitute for inorganic semiconductors. Doping in Conjugated Polymers is the first book dedicated to the subject and offers a comprehensive A-to-Z overview. It details doping interaction, dopant types, doping techniques, and the influence of the dopant on applications. It explains how the performance of doped conjugated polymers is greatly influenced by the nature of the dopants and their level of distribution within the polymer, and shows how the electrochemical, mechanical, and optical properties of the doped conjugated polymers can be tailored by controlling the size and mobility of the dopants counter ions. The book also examines doping at the nanoscale, in particular, with carbon nanotubes. Readership The book will interest a broad range of researchers including chemists, electrochemists, biochemists, experimental and theoretical physicists, electronic and electrical engineers, polymer and materials scientists. It can also be used in both graduate and upper-level undergraduate courses on conjugated polymers and polymer technology.


Conjugated Conducting Polymers

Conjugated Conducting Polymers
Author: Helmut Kiess
Publisher: Springer Science & Business Media
Total Pages: 320
Release: 2012-12-06
Genre: Science
ISBN: 3642467296

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This book reviews the current understanding of electronic, optical and magnetic properties of conjugated polymers in both the semiconducting and metallic states. It introduces in particular novel phenomena and concepts in these quasi one-dimensional materials that differ from the well-established concepts valid for crystalline semiconductors. After a brief introductory chapter, the second chapter presents basic theore tical concepts and treats in detail the various models for n-conjugated polymers and the computational methods required to derive observable quantities. Specific spatially localized structures, often referred to as solitons, polarons and bipolarons, result naturally from the interaction between n-electrons and lattice displacements. For a semi-quantitative understanding of the various measure ments, electron-electron interactions have to be incorporated in the models; this in turn makes the calculations rather complicated. The third chapter is devoted to the electrical properties of these materials. The high metallic conductivity achieved by doping gave rise to the expression conducting polymers, which is often used for such materials even when they are in their semiconducting or insulating state. Although conductivity is one of the most important features, the reader will learn how difficult it is to draw definite conclusions about the nature of the charge carriers and the microscopic transport mechanism solely from electrical measurements. Optical properties are discussed in the fourth chapter.


Electronic and Optical Properties of Conjugated Polymers

Electronic and Optical Properties of Conjugated Polymers
Author: William Barford
Publisher: International Monographs on Ph
Total Pages: 320
Release: 2013-04-04
Genre: Science
ISBN: 0199677468

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Conjugated polymers have important technological applications including solar cells and light emitting devices. They are active components in many important biological processes. This book describes and explains the electronic and optical properties of conjugated polymers by developing theoretical models to understand the key electronic states.


Conjugated Polymers

Conjugated Polymers
Author: J.L. Brédas
Publisher: Springer Science & Business Media
Total Pages: 638
Release: 2012-12-06
Genre: Science
ISBN: 9401134766

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Conjugated Polymers at Nanoscale

Conjugated Polymers at Nanoscale
Author: Karen K. Gleason
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 146
Release: 2021-08-23
Genre: Technology & Engineering
ISBN: 1501516175

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Nanoscale control of order and orientation is essential for optimizing the performance of conjugated polymers. These semi-crystalline materials enable flexible devices for electronic, optical, electrochemical, and thermoelectric applications and are also of interest for the emerging fields of bioelectronics and spintronics.


Organic Electronic Materials

Organic Electronic Materials
Author: R. Farchioni
Publisher: Springer Science & Business Media
Total Pages: 457
Release: 2013-11-21
Genre: Technology & Engineering
ISBN: 3642564259

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This book brings together selected contributions both on the fundamental information on the physics and chemistry of these materials, new physical ideas and decisive experiments. It constitutes both an insightful treatise and a handy reference for specialists and graduate students working in solid state physics and chemistry, material science and related fields.


Conjugated Polymer Synthesis

Conjugated Polymer Synthesis
Author: Yoshiki Chujo
Publisher: John Wiley & Sons
Total Pages: 333
Release: 2011-08-02
Genre: Technology & Engineering
ISBN: 3527632689

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Edited and authored by top international experts, this first book on conjugated polymers with a focus on synthesis provides a detailed overview of all modern synthetic methods for these highly interesting compounds. As such, it describes every important compound class, including polysilanes, organoboron compounds, and ferrocene-containing conjugated polymers. An indispensable source for every synthetic polymer chemist.


Nanofibers of Conjugated Polymers

Nanofibers of Conjugated Polymers
Author: A. Sezai Sarac
Publisher: CRC Press
Total Pages: 297
Release: 2017-03-27
Genre: Science
ISBN: 9814613525

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Conjugated polymer composites with high dielectric constants are being developed by the electronics industry in response to the need for power-grounded decoupling to secure the integrity of high-speed signals and to reduce electromagnetic interference. Electrically conducting polymers are materials that simultaneously possess the physical and chemical properties of organic polymers and the electronic characteristics of metals. Multifunctional micro- and nanostructures of conjugated polymers, such as of pyrrole, have received great attention in recent years because they can polymerize easily and have high conductivity and good thermal stability. They, however, have some disadvantages such as brittleness and hard processability, which can be overcome by developing their nanocomposites. Nanofiber materials with different dielectric properties can be made from conjugated polymer composites and used in the electronics industry, in sensors and batteries, for electrical stimulation to enhance nerve-regeneration process, and for constructing scaffolds for nerve tissue engineering. Electrospinning is a versatile technique that is used to produce ultrathin continuous fibers with high surface-to-volume and aspect ratios from a variety of materials, including polymers, composites, and ceramics. Conductive materials in fibrillar shape may be advantageous compared with films because of their inherent properties such as anisotropy, high surface area, and mechanical strength. They are of particular interest in electroactive composites as they can be efficiently distributed in an insulating polymer matrix to improve both electrical and mechanical properties. Combination of electrical properties with good mechanical performance is of particular interest in electroactive polymer technology. This book covers the general aspects of electrospinning and discusses the fundamental concepts that can be used to produce nanofibers with the help of mathematical models and equations. It also details the methods through which different polymeric structures can be included in conjugated polymers during electrospinning to form composites or blends of conjugated polymer nanofibers.