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CO2 as a Building Block in Organic Synthesis

CO2 as a Building Block in Organic Synthesis
Author: Shoubhik Das
Publisher: John Wiley & Sons
Total Pages: 623
Release: 2020-09-16
Genre: Science
ISBN: 3527821961

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A guide to the fascinating application of CO2 as a building block in organic synthesis This important book explores modern organic synthesis’ use of the cheap, non-toxic and abundant chemical CO2as an attractive C1 building block. With contributions from an international panel of experts, CO2 as a Building Block in Organic Synthesis offers a review of the most important reactions which use CO2 as a building block in organic synthesis. The contributors examine a wide-range of CO2 reactions including methylation reactions, CH bond functionalization, carboxylation, cyclic carbonate synthesis, multicomponent reactions, and many more. The book reviews the most recent developments in the field and also: Presents the most important reactions like CH-bond functionalization, carboxylation, carbonate synthesis and many more Contains contributions from an international panel of experts Offers a comprehensive resource for academics and professionals in the field Written for organic chemists, chemists working with or on organometallics, catalytic chemists, pharmaceutical chemists, and chemists in industry, CO2 as Building Block in Organic Synthesis contains an analysis of the most important reactions which use CO2 as an effective building block in organic synthesis.


CO2 as a Building Block in Organic Synthesis

CO2 as a Building Block in Organic Synthesis
Author: Shoubhik Das
Publisher: John Wiley & Sons
Total Pages: 464
Release: 2020-08-18
Genre: Science
ISBN: 3527821945

Download CO2 as a Building Block in Organic Synthesis Book in PDF, ePub and Kindle

A guide to the fascinating application of CO2 as a building block in organic synthesis This important book explores modern organic synthesis’ use of the cheap, non-toxic and abundant chemical CO2 as an attractive C1 building block. With contributions from an international panel of experts, CO2 as Building Block in Organic Synthesis offers a review of the most important reactions which use CO2 as a building block in organic synthesis. The contributors examine a wide-range of CO2 reactions including methylation reactions, CH bond functionalization, carboxylation, cyclic carbonate synthesis, multicomponent reactions, and many more. The book reviews the most recent developments in the field and also: Presents the most important reactions like CH-bond functionalization, carboxylation, carbonate synthesis and many more Contains contributions from an international panel of experts Offers a comprehensive resource for academics and professionals in the field Written for organic chemists, chemists working with or on organometallics, catalytic chemists, pharmaceutical chemists, and chemists in industry, CO2 as Building Block in Organic Synthesis contains an analysis of the most important reactions which use CO2 as an effective building block in organic synthesis.


CO2 as Building Block for Synthesis

CO2 as Building Block for Synthesis
Author: Shoubhik Das
Publisher: VCH
Total Pages: 432
Release: 2020-09-16
Genre:
ISBN: 9783527346134

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This book presents the most important reactions which use CO2 as an effective building block in organic synthesis. Reactions like methylation reactions, CH bond functionalization, carboxylation and many more a included and make this book an indispensable source of information.


Capture and Utilization of Carbon Dioxide with Polyethylene Glycol

Capture and Utilization of Carbon Dioxide with Polyethylene Glycol
Author: Zhen-Zhen Yang
Publisher: Springer Science & Business Media
Total Pages: 88
Release: 2012-08-10
Genre: Science
ISBN: 3642312683

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In this volume, Professor He and his coworkers summarize polyethylene glycol (PEG)-promoted CO2 chemistry on the basis of understanding about phase behavior of PEG/CO2 system and reaction mechanism at molecular level. As PEG could be utilized as a green replacement for organic solvents, phase-transfer catalyst, surfactant, support in various reaction systems, significantly promoting catalytic activity and recovering expensive metal catalysts, particularly regarded as a CO2-philic material, the authors focus on special applications of PEG in CO2 capture and utilization, including PEG-functionalized catalysts for efficient transformation of CO2 and PEG-functionalized absorbents for efficient CO2 capture. Furthermore, they describe carbon capture and utilization strategy as an alternative approach to address the energy penalty problem in carbon capture and storage. Interestingly, the authors also discuss PEG radical chemistry in dense CO2 as rather creative and unusual use of PEG, presumably serves as a reaction medium and a radical initiator for radical chemistry.


C-1 Building Blocks in Organic Synthesis

C-1 Building Blocks in Organic Synthesis
Author: Thomas J. J. Müller
Publisher:
Total Pages: 0
Release: 2014
Genre: Carbonyl compounds
ISBN: 9783131707611

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Chemical Transformations of Carbon Dioxide

Chemical Transformations of Carbon Dioxide
Author: Xiao-Feng Wu
Publisher: Springer
Total Pages: 253
Release: 2018-06-04
Genre: Science
ISBN: 9783319777566

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​The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.


Carbon Dioxide as Chemical Feedstock

Carbon Dioxide as Chemical Feedstock
Author: Michele Aresta
Publisher: John Wiley & Sons
Total Pages: 414
Release: 2010-01-26
Genre: Science
ISBN: 9783527629923

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Filling the need for an up-to-date handbook, this ready reference closely investigates the use of CO2 for ureas, enzymes, carbamates, and isocyanates, as well as its use as a solvent, in electrochemistry, biomass utilization and much more. Edited by an internationally renowned and experienced researcher, this is a comprehensive source for every synthetic chemist in academia and industry.


The logic of chemical synthesis

The logic of chemical synthesis
Author: E.J. Corey
Publisher: Рипол Классик
Total Pages: 447
Release: 1991
Genre: Science
ISBN: 5885010811

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Organometallics for Green Catalysis

Organometallics for Green Catalysis
Author: Pierre H. Dixneuf
Publisher: Springer
Total Pages: 301
Release: 2019-02-25
Genre: Science
ISBN: 3030109550

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This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol –an eco-friendly energy storage strategy– and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and C–O bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective C–H bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. C–H bond oxidation using visible light leads mainly to the formation of C–O and C–N bonds, whereas cross-coupled C–C bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism.


Catalysis in C1 Chemistry

Catalysis in C1 Chemistry
Author: W. Keim
Publisher: Springer Science & Business Media
Total Pages: 318
Release: 2012-12-06
Genre: Science
ISBN: 9400970404

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Continuously increasing oil prices, a dwindling supply of petroleum, and the existence of extensive reserves of biomass, especially of coal, have given rise to a growing interest in generating CO/H from these sources. Catalytic reactions can 2 convert CO/H mixtures to useful hydrocarbons or hydrocarbon intermediates. 2 There is little doubt that petroleum will remain the backbone of the organic chemical industry for many years to come, yet there is great opportunity for CO as an alternative feedstock at times when it is needed. The loosely defined body of chemistry and technology contained in these areas of development has become known as C 1 chemistry, embracing many C 1 building blocks such as CH , CO/H , CO, CH OH, CO and HCN; still emphasis 4 2 3 2 rests on carbon monoxide. Academic research laboratories, oil and chemical companies are in the vanguard of C 1 chemistry. The Japanese Ministry of International Trade and Industry is sponsoring a seven-year program of 14 major chemical companies in C 1 chemistry aimed at developing new technology for making basic chemicals from CO and H2 . It is likely that C 1 chemistry will develop slowly but persistently and the future holds great potential.