Boron Metallo Boron Compounds And Boranes Edited By Roy M Adams By Various Authors PDF Download

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Boron-Based Compounds

Boron-Based Compounds
Author: Evamarie Hey-Hawkins
Publisher: John Wiley & Sons
Total Pages: 496
Release: 2018-04-03
Genre: Science
ISBN: 111927558X

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Noted experts review the current status of boron-containing drugs and materials for molecular medical diagnostics Boron-Based Compounds offers a summary of the present status and promotes the further development of new boron-containing drugs and advanced materials, mostly boron clusters, for molecular medical diagnostics. The knowledge accumulated during the past decades on the chemistry and biology of bioorganic and organometallic boron compounds laid the foundation for the emergence of a new area of study and application of boron compounds as lipophilic pharmacophores and modulators of biologically active molecules.This important text brings together in one comprehensive volume contributions from renowned experts in the field of medicinal chemistry of boron compounds. The authors cover a range of the most relevant topics including boron compounds as modulators of the bioactivity of biomolecules, boron clusters as pharmacophores or for drug delivery, boron compounds for boron neutron capture therapy (BNCT) and for diagnostics, as well as in silico molecular modeling of boron- and carborane-containing compounds in drug design. Authoritative and accessible, Boron-Based Compounds: Contains contributions from a panel of internationally renowned experts in the field Offers a concise summary of the current status of boron-containing drugs and materials used for molecular diagnostics Highlights the range and capacity of boron-based compounds in medical applications Includes information on boron neutron capture therapy and diagnostics Designed for academic and industrial scientists, this important resource offers the cutting-edge information needed to understand the current state of boron-containing drugs and materials for molecular medical diagnostics.


BORON HYDRIDE CHEMISTRY.

BORON HYDRIDE CHEMISTRY.
Author: Roy M. Adams
Publisher:
Total Pages: 85
Release: 1970
Genre:
ISBN:

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Attempts to prepare icosahedral closed cage compounds of high boron content with nitrogen, phosphorus or carbon as a hetero atoms were unsuccessful. Electrolysis of the B3H8( - ) and B11H14( - ) ions in acetonitrile did not produce high boron content materials. Oxidation potential for the B3H8 ion were observed at +0.15 volts at pH 4.5 and at +0.205 volts at pH 12 and at +0.86 volts in acetronitrile. The hydrolysis kinetics led to observation of an unidentified intermediate with reduction potential -0.49 volts. Oxidation potentials of the B11H14( - ) ion were +1.56 volts in acetonitrile and +0.70 volts in dimethylformamide. The boranes of dimethylsulfide, ethylene sulfide, trimethylene sulfide, tetrahydrothiophene, and dithiane (C2H4S)2 were prepared. Trithiane (CH2S)3 did not absorb borane at all. The ethylene sulfide and trimethylene sulfide-boranes polymerized. The utility of dimethyl sulfide-borane as a borane carrier was demonstrated with amines, phosphines and phosphites and also its reducing power toward organic groups. The infrared and Raman spectra of enriched and deuterated dimethyl sulfide-borane were taken and assignments made. It was used to prepare 3-methylthioborane, unique in being a stable distillable monoalkyl-borane with retained hydridic activity. Several unreported heterocyclic boron compounds were prepared including oxaborolanes, oxaborinanes, a thiaazaborolane, a diazaborolane, and a thiazaborolane. (Author).


General Catalogue of Printed Books

General Catalogue of Printed Books
Author: British Museum. Department of Printed Books
Publisher:
Total Pages: 536
Release: 1965
Genre: Bibliography
ISBN:

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NBS Special Publication

NBS Special Publication
Author:
Publisher:
Total Pages: 1528
Release: 1972
Genre: Weights and measures
ISBN:

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Boranes and Metalloboranes

Boranes and Metalloboranes
Author: Catherine E. Housecroft
Publisher: Ellis Horwood
Total Pages: 174
Release: 1990
Genre: Borane
ISBN:

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