Blocking Of Styrene And Select Styrene Derivatives From Living Polyisobutylene Cations PDF Download

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Block Copolymers

Block Copolymers
Author: Nikos Hadjichristidis
Publisher: John Wiley & Sons
Total Pages: 445
Release: 2003-04-28
Genre: Technology & Engineering
ISBN: 0471461342

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Polymers may be classified as either homopolymers, consisting of one single repeating unit, or copolymers, consisting of two or more distinct repeating units. Block copolymers contain long contiguous blocks of two or more repeating units in the same polymer chain. Covering one of the hottest topics in polymer chemistry, Block Copolymers provides a coherent overview of the synthetic routes, physical properties, and applications of block copolymers. This pioneering text provides not only a guideline for developing synthetic strategies for creating block copolymers with defined characteristics, but also a key to the relationship between the physical properties of block copolymers and the structure and dynamics of materials. Covering features of the chemistry and physics of block copolymers that are not found in comparable texts, Block Copolymers illustrates the structure-activity relationship of block copolymers and offers suggestions for the design of specific applications. Divided into five sections-Block Copolymers includes chapters on: * Block Copolymers by Chemical Modification of Precursor Polymers * Nonlinear Block Copolymers * Adsorption of Block Copolymers at Solid-Liquid Interfaces * Theory of Block Copolymer Segregation * Phase Transformation Kinetics * Block Copolymer Morphology * Block Copolymer Dynamics Polymer chemists, physicists, chemical engineers, and materials scientists, as well as graduate students in polymer science, will find Block Copolymers to be an invaluable text.


Controlled/Living Radical Polymerization

Controlled/Living Radical Polymerization
Author: Krzysztof Matyjaszewski
Publisher: OUP USA
Total Pages: 0
Release: 2007-01-04
Genre: Science
ISBN: 9780841239913

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The preparation and characterization of new materials with precisely controlled macromolecular dimensions, functionalities, and decomposition, as well as with well-defined topologies, is perhaps the main focus of contemporary polymer synthesis. The best control of molecular functions can be achieved in a controlled/living polymerization -- a chain growth process without chain breaking reactions. Recently, controlled/living polymerizations have extended to radical systems which are not only commercially important, but also have the largest potential due to the availability of radically polymerizable monomers, facile copolymerization and undemanding experimental conditions. Controlled Radical Polymerization will examine recent advances in mechanistic and synthetic aspects of controlled/living radical (co)polymerization systems. Not only will this book be focused on recent progress in the dynamically developing field of controlled/living radical polymerization, but it will be a sequel to the very popular ACS Symposium Series 685, 768, and 854. The book will consist of >30 chapters separated into seven subsections: Fundamentals, Mechanism of ATRP, Mechanisms of SFRP and Degenerative Transfer Processes, Controlled Architecture by CRP, Organic-inorganic Hybrids by CRP, Biomaterials by CRP and Industrial Applications. This book targets chemists and polymer scientists in academia and in industry.


Elements of Polymer Science & Engineering

Elements of Polymer Science & Engineering
Author: Alfred Rudin
Publisher: Elsevier
Total Pages: 529
Release: 1998-09-21
Genre: Technology & Engineering
ISBN: 0080505473

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Tremendous developments in the field of polymer science, its growing importance, and an increase in the number of polymer science courses in both physics and chemistry departments have led to the revision of the First Edition. This new edition addresses subjects as spectroscopy (NMR), dynamic light scattering, and other modern techniques unknown before the publication of the First Edition. The Second Edition focuses on both theory (physics and chemistry) and engineering applications which make it useful for chemistry, physics, and chemical engineering departments.


Silane Coupling Agents

Silane Coupling Agents
Author: Edwin P. Plueddemann
Publisher: Springer Science & Business Media
Total Pages: 238
Release: 2013-11-11
Genre: Science
ISBN: 1489903429

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* It has been rumored that a bumble bee has such aerodynamic deficiencies that it should be incapable of flight. Fiberglass-reinforced polymer com posites, similarly, have two (apparently) insurmountable obstacles to per formance: 1) Water can hydrolyze any conceivable bond between organic and inorganic phase, and 2) Stresses across the interface during temperature cycling (resulting from a mismatch in thermal expansion coefficients) may exceed the strength of one of the phases. Organofunctional silanes are hybrid organic-inorganic compounds that are used as coupling agents across the organic-inorganic interface to help overcome these two obstacles to composite performance. One of their functions is to use the hydrolytic action of water under equilibrium condi tions to relieve thermally induced stresses across the interface. If equilib rium conditions can be maintained, the two problems act to cancel each other out. Coupling agents are defined primarily as materials that improve the practical adhesive bond of polymer to mineral. This may involve an increase in true adhesion, but it may also involve improved wetting, rheology, and other handling properties. The coupling agent may also modify the inter phase region to strengthen the organic and inorganic boundary layers.


UHMWPE Biomaterials Handbook

UHMWPE Biomaterials Handbook
Author: Steven M. Kurtz
Publisher: Academic Press
Total Pages: 564
Release: 2009-04-27
Genre: Technology & Engineering
ISBN: 008088444X

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UHMWPE Biomaterials Handbook describes the science, development, properties and application of of ultra-high molecular weight polyethylene (UHMWPE) used in artificial joints. This material is currently used in 1.4 million patients around the world every year for use in the hip, knee, upper extremities, and spine. Since the publication of the 1st edition there have been major advances in the development and clinical adoption of highly crosslinked UHMWPE for hip and knee replacement. There has also been a major international effort to introduce Vitamin E stabilized UHMWPE for patients. The accumulated knowledge on these two classes of materials are a key feature of the 2nd edition, along with an additional 19 additional chapters providing coverage of the key engineering aspects (biomechanical and materials science) and clinical/biological performance of UHMWPE, providing a more complete reference for industrial and academic materials specialists, and for surgeons and clinicians who require an understanding of the biomaterials properties of UHMWPE to work successfully on patient applications. The UHMWPE Handbook is the comprehensive reference for professionals, researchers, and clinicians working with biomaterials technologies for joint replacement New to this edition: 19 new chapters keep readers up to date with this fast moving topic, including a new section on UHMWPE biomaterials; highly crosslinked UHMWPE for hip and knee replacement; Vitamin E stabilized UHMWPE for patients; clinical performance, tribology an biologic interaction of UHMWPE State-of-the-art coverage of UHMWPE technology, orthopedic applications, biomaterial characterisation and engineering aspects from recognised leaders in the field


Recent Advances in Ionic Liquids

Recent Advances in Ionic Liquids
Author: Mohammed Rahman
Publisher: BoD – Books on Demand
Total Pages: 194
Release: 2018-09-26
Genre: Science
ISBN: 1789841178

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Recent Advances in Ionic Liquids contains research on the preparation, characterization, and potential applications of stable ionic liquids (ILs). ILs are a class of low- and stable-melting point, ionic compounds that have a variety of properties allowing many of them to be sustainable green solvents. It is promising novel research from top to bottom and has received a lot of interest over the last few decades. It covers the advanced topics of physical, catalytic, chemical, polymeric, and potential applications of ILs. This book features interesting reports on cutting-edge science and technology related to the preparation, characterization, polymerization, and potential applications of ILs. This potentially unique work offers various approaches on the R


Polymer Chemistry

Polymer Chemistry
Author: Timothy P. Lodge
Publisher: CRC Press
Total Pages: 609
Release: 2020-07-14
Genre: Science
ISBN: 1466581662

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A well-rounded and articulate examination of polymer properties at the molecular level, Polymer Chemistry focuses on fundamental principles based on underlying chemical structures, polymer synthesis, characterization, and properties. It emphasizes the logical progression of concepts and provide mathematical tools as needed as well as fully derived problems for advanced calculations. The much-anticipated Third Edition expands and reorganizes material to better develop polymer chemistry concepts and update the remaining chapters. New examples and problems are also featured throughout. This revised edition: Integrates concepts from physics, biology, materials science, chemical engineering, and statistics as needed. Contains mathematical tools and step-by-step derivations for example problems Incorporates new theories and experiments using the latest tools and instrumentation and topics that appear prominently in current polymer science journals. The number of homework problems has been greatly increased, to over 350 in all. The worked examples and figures have been augmented. More examples of relevant synthetic chemistry have been introduced into Chapter 2 ("Step-Growth Polymers"). More details about atom-transfer radical polymerization and reversible addition/fragmentation chain-transfer polymerization have been added to Chapter 4 ("Controlled Polymerization"). Chapter 7 (renamed "Thermodynamics of Polymer Mixtures") now features a separate section on thermodynamics of polymer blends. Chapter 8 (still called "Light Scattering by Polymer Solutions") has been supplemented with an extensive introduction to small-angle neutron scattering. Polymer Chemistry, Third Edition offers a logical presentation of topics that can be scaled to meet the needs of introductory as well as more advanced courses in chemistry, materials science, polymer science, and chemical engineering.


Science and Technology of Rubber

Science and Technology of Rubber
Author: James E. Mark
Publisher: Elsevier
Total Pages: 762
Release: 2011-07-28
Genre: Science
ISBN: 0080456014

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The Science and Technology of Rubber, Third Edition provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Many advances have been made in polymer and elastomers research over the past ten years since the 2nd edition was published. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling.


New Materials for Catalytic Applications

New Materials for Catalytic Applications
Author: Vasile I. Parvulescu
Publisher: Elsevier
Total Pages: 388
Release: 2016-01-28
Genre: Technology & Engineering
ISBN: 0444635882

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New Materials for Catalytic Applications proposes the use of both new and existing materials for catalytic applications, such as zeolites, metal oxides, microporous and mesoporous materials, and monocrystals. In addition, metal-oxides are discussed from a new perspective, i.e. nano- and photocatalytic applications. The material presents these concepts with a new focus on strategies in synthesis, synthesis based on a rational design, the correlation between basic properties/potential applications, and new catalytic solutions for acid-base, redox, hydrogenation, photocatalytic reactions, etc. Presents organometallic concepts for the synthesis of nanocatalysts Provides a synthesis of new materials following the fluorolytic sol-gel concept Covers electronic and photocatalytic properties via synthesis of nano-oxide materials Details the nature of sites in MOFs generating catalytic properties immobilization of triflates in solid matrices for organic reactions