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Aspects of Non-equilibrium Thermodynamics

Aspects of Non-equilibrium Thermodynamics
Author: Wolfgang Muschik
Publisher: World Scientific
Total Pages: 124
Release: 1990
Genre: Science
ISBN: 9789810200879

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In six lectures aspects of modern non-equilibrium thermodynamics of discrete systems as well as continuum theoretical concepts are represented. Starting out with survey and introduction, state spaces are defined, the existence of internal energy is investigated, and Clausius inequality including negative absolute temperature is derived by diagram technique. Non-equilibrium contact quantities, such as contact temperature ? the dynamic analogue of thermostatic temperature ? and chemical potentials are phenomenologically defined and quantumstatistically founded. Using Clausius inequality the existence of non-negative entropy production is proved which allows to formulate a dissipation inequality in continuum thermodynamics. The transition between thermodynamics of discrete systems and continuum thermodynamics with respect to contact quantities is considered. Different possibilities of exploiting the dissipation inequality for getting constraints for constitutive equations are discussed. Finally hyperbolic heat conduction in non-extended thermodynamics is treated.


Understanding Non-equilibrium Thermodynamics

Understanding Non-equilibrium Thermodynamics
Author: Georgy Lebon
Publisher: Springer Science & Business Media
Total Pages: 331
Release: 2008-01-12
Genre: Science
ISBN: 3540742522

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Discover the many facets of non-equilibrium thermodynamics. The first part of this book describes the current thermodynamic formalism recognized as the classical theory. The second part focuses on different approaches. Throughout the presentation, the emphasis is on problem-solving applications. To help build your understanding, some problems have been analyzed using several formalisms to underscore their differences and their similarities.


Non-equilibrium Thermodynamics Of Heterogeneous Systems

Non-equilibrium Thermodynamics Of Heterogeneous Systems
Author: Signe Kjelstrup
Publisher: World Scientific
Total Pages: 451
Release: 2008-02-22
Genre: Science
ISBN: 981447231X

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The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.


Non-Equilibrium Thermodynamics

Non-Equilibrium Thermodynamics
Author: S. R. De Groot
Publisher: Courier Corporation
Total Pages: 532
Release: 2013-01-23
Genre: Science
ISBN: 0486153509

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Classic monograph treats irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications with chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, more.


Statistical Physics And Thermodynamics Of Nonlinear Nonequilibrium Systems

Statistical Physics And Thermodynamics Of Nonlinear Nonequilibrium Systems
Author: Wolfgang Muschik
Publisher: World Scientific
Total Pages: 270
Release: 1993-03-27
Genre: Science
ISBN: 981459086X

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In these proceedings, it is shown that thermodynamical concepts are not ‘old fashioned’ but still are most useful at the frontiers of modern science. Among the contributors are well-known experts such as Andresen (Copenhagen), Eu (Montreal), Groβmann (Marburg), Kawasaki (Fuhuoha), Maugin (Paris), Nicolis (Bruxelles) and Szépfalusy (Budapest). The subject covers a wide field including: recent developments in phenomenological thermodynamics, statistical foundation of thermodynamical concepts, thermodynamical concepts in nonlinear dynamics, applications to nonlinear (neural) networks, stochastic theory and transition processes.


Thermodynamic Approaches in Engineering Systems

Thermodynamic Approaches in Engineering Systems
Author: Stanislaw Sieniutycz
Publisher: Elsevier
Total Pages: 740
Release: 2016-05-20
Genre: Technology & Engineering
ISBN: 0128093390

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Thermodynamic Approaches in Engineering Systems responds to the need for a synthesizing volume that throws light upon the extensive field of thermodynamics from a chemical engineering perspective that applies basic ideas and key results from the field to chemical engineering problems. This book outlines and interprets the most valuable achievements in applied non-equilibrium thermodynamics obtained within the recent fifty years. It synthesizes nontrivial achievements of thermodynamics in important branches of chemical and biochemical engineering. Readers will gain an update on what has been achieved, what new research problems could be stated, and what kind of further studies should be developed within specialized research. Presents clearly structured chapters beginning with an introduction, elaboration of the process, and results summarized in a conclusion Written by a first-class expert in the field of advanced methods in thermodynamics Provides a synthesis of recent thermodynamic developments in practical systems Presents very elaborate literature discussions from the past fifty years


Non-Equilibrium Thermodynamics with Application to Solids

Non-Equilibrium Thermodynamics with Application to Solids
Author: W. Muschik
Publisher: Springer
Total Pages: 336
Release: 2014-05-04
Genre: Technology & Engineering
ISBN: 3709143217

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This book puts emphasis on developing the basic ideas behind the different approaches to non-equilibrium thermodynamics and on applying them to solids. After a survey about different approaches an introduction to their common fundamentals is given in the first part. In the second part the mechanical behavior of special materials such as viscoelasticity, viscoplasticity, viscoelastoplasticity, and thermoplasticity are discussed. The third part is devoted to extended thermodynamics. The basic ideas, phenomenological as well as microscopical, are reviewed and applied to thermo- and viscoelastic materials. Electromagnetic solids showing dielectric relaxation, such as ceramics, showing electromagneto-mechanical hysteresis and superconductivity are treated in the fourth part. In the last part stability with regard to constitutive equations is investigated. Especially stability of quasi-static processes and of elastic-plastic systems are discussed.


Alternative Mathematical Theory of Non-equilibrium Phenomena

Alternative Mathematical Theory of Non-equilibrium Phenomena
Author: Dieter Straub
Publisher: Academic Press
Total Pages: 395
Release: 1996-10-09
Genre: Science
ISBN: 0080527078

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Alternative Mathematical Theory of Non-equilibrium Phenomena presents an entirely new theoretical approach to complex non-equilibrium phenomena, especially Gibbs/Falk thermodynamics and fluid mechanics. This innovative new theory allows for inclusion of all state variables and introduces a new vector-dissipation velocity-which leads to useful restatements of momentum, the Second Law, and tensors for the laws of motion, friction, and heat conduction. This application-oriented text is relatively self-contained and is an excellent guide-book for engineers with a strong interest in fundamentals, or for professionals using applied mathematics and physics in engineering applications. This book emphasizes macroscopic phenomena, focusing specifically on gaseous states, though relations to liquid and crystalline states are also considered. The author presents a new Alternative Continuum Theory of Compressible Fluids (AT) which providesa qualitative description of the subject in predominantly physical terms, minimizing the mathematical premises. The methodology discussed has applications in a wide range of fields outside of physics in areas including General System Theory, TheoreticalEconomics, and Biophysics and Medicine. Presents the first theory capable of handling non-equilibria phenomena Offers a unified theory of all branches of macroscopic physics Considers a consistent and uniform view of reality, supported by modern mathematics, leading to results different than those produced by classical theories Results in a change of paradigms in physics, engineering, and natural philosophy


Non-equilibrium thermodynamics and physical kinetics

Non-equilibrium thermodynamics and physical kinetics
Author: Halid Bikkin
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 425
Release: 2014-08-22
Genre: Science
ISBN: 3110373009

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This graduate textbook covers contemporary directions of non-equilibrium statistical mechanics as well as classical methods of kinetics. Starting from phenomenological non-equilibrium thermodynamics, the kinetic equation method discussed and demonstrated with electrons and phonons in conducting crystals. Linear response theory as well as the non-equilibrium statistical operator and the master equation approach are discussed in the course of the book. With one of the main propositions being to avoid terms such as "obviously" and "it is easy to show", this treatise is an easy-to-read introduction into this traditional, yet vibrant field. Problems and their well-documented solutions included at appropriate points of the narrative allow the reader to actively develop essential parts of the theory himself. From the content: Phenomenological thermodynamics of irreversible processes Brownian motion Kinetic equations in non-equilibrium thermodynamics Kinetic equation for electrons and phonons in conducting crystals Theory of non-linear response to an external mechanical pertubation Non-equilibrium statistical operator method Response of a highly non-equilibrium system to a weakly measuring field Master equation approach