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| Author | : Piet W.N.M. van Leeuwen |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 219 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 9401104751 |
Download Theoretical Aspects of Homogeneous Catalysis Book in PDF, ePub and Kindle
This publication is the first to present the quantitative application of quantum chemistry to organometallic reactions. Great progress has been made in recent years in the calculation of transition states of organometallic conversions in both homo and heterogeneous catalysis. This volume, which contains seven contributions by leading scientists, deals with key reactions of homogeneous catalysis including oxidative addition, migratory insertions, 2+2 additions, the Wacker reaction, and epoxidation. The book provides experimental chemists with an up-to-date overview of the state of the art in this field, and will stimulate an adjustment of views previously based on semiempirical calculations. For researchers and advanced graduate students whose work involves organometallics and catalysis.
| Author | : Piet W.N.M. van Leeuwen |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 413 |
| Release | : 2006-08-02 |
| Genre | : Science |
| ISBN | : 1402020007 |
Download Homogeneous Catalysis Book in PDF, ePub and Kindle
No available as softcover No other book available that gives insight into so many reactions of importance, while the field of homogeneous catalysis is becoming more and more important to organic chemists, industrial chemists, and academia. Gives real insight in the many new and old reactions of importance, based on the author's extensive experience in both teaching and industrial practice. Provide background to chemists trained in a different discipline and graduate and masters students who take catalysis as a main or secondary topic.
| Author | : Oleg N. Temkin |
| Publisher | : John Wiley & Sons |
| Total Pages | : 963 |
| Release | : 2012-02-08 |
| Genre | : Science |
| ISBN | : 1119966825 |
Download Homogeneous Catalysis with Metal Complexes Book in PDF, ePub and Kindle
Homogeneous catalysis by soluble metal complexes has gained considerable attention due to its unique applications and features such as high activity and selectivity. Catalysis of this type has demonstrated impressive achievements in synthetic organic chemistry and commercial chemical technology. Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms presents a comprehensive summary of the results obtained over the last sixty years in the field of the kinetics and mechanisms of organic and inorganic reactions catalyzed with metal complexes. Topics covered include: Specific features of catalytic reaction kinetics in the presence of various mono- and polynuclear metal complexes and nanoclusters Multi-route mechanisms and the methods of their identification, as well as approaches to the kinetics of polyfunctional catalytic systems Principles and features of the dynamic behavior of nonlinear kinetic models The potential, achievements, and limitations of applying the kinetic approach to the identification of complex reaction mechanisms The development of a rational strategy for designing kinetic models The kinetic models and mechanisms of many homogeneous catalytic processes employed in synthetic and commercial chemistry Written for specialists in the field of kinetics and catalysis, this book is also relevant for post-graduates engaged in the study
| Author | : John C. Chadwick |
| Publisher | : John Wiley & Sons |
| Total Pages | : 592 |
| Release | : 2011-06-09 |
| Genre | : Science |
| ISBN | : 3527636005 |
Download Homogeneous Catalysts Book in PDF, ePub and Kindle
This first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste. The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics.
| Author | : Sumit Bhaduri |
| Publisher | : John Wiley & Sons |
| Total Pages | : 291 |
| Release | : 2014-09-08 |
| Genre | : Science |
| ISBN | : 1118872479 |
Download Homogeneous Catalysis Book in PDF, ePub and Kindle
Over the last decade, the area of homogeneous catalysis with transition metal has grown in great scientific interest and technological promise, with research in this area earning three Nobel Prizes and filing thousands of patents relating to metallocene and non-metallocene single site catalysts, asymmetric catalysis, carbon-carbon bond forming metathesis and cross coupling reactions. This text explains these new developments in a unified, cogent, and comprehensible manner while also detailing earlier discoveries and the fundamentals of homogeneous catalysis. Serving as a self-study guide for students and all chemists seeking to gain entry into this field, it can also be used by experienced researchers from both academia and industry for referring to leading state of the art review articles and patents, and also as a quick self-study manual in an area that is outside their immediate expertise. The book features: • Topics including renewable feed stocks (biofuel, glycerol), carbon dioxide based processes (polycarbonates), fluorous solvents, ionic liquid, hydroformylation, polymerization, oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry, homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (case studies), and examples from proven industrial processes with clear discussions on environmental and techno-commercial issues • Extensive references to cutting edge research with application potential and leading patents • Tables and illustrations to help explain difficult concepts
| Author | : R. Ugo |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 209 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 9400983719 |
Download Aspects of Homogeneous Catalysis Book in PDF, ePub and Kindle
| Author | : R. Ugo |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 199 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 9401022852 |
Download Aspects of Homogeneous Catalysis Book in PDF, ePub and Kindle
| Author | : R. Ugo |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 350 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 9400963637 |
Download Aspects of Homogeneous Catalysis Book in PDF, ePub and Kindle
1. INTRODUCTION Although quite spectacular results have been obtained in the last few decades in the field of homogeneous transition metal catalyzed transformations of olefins and alkynes [1], reactions which could lead to heterocycles have been partly neglected. An obvious reason for this is that substrates containing heteroatoms such as N, 0 or S could coordinate the metal and suppress the catalytic activity. Nevertheless, some interesting early examples of transition-metal-catalyzed syntheses of heterocyclic compounds have been reported and these have been reviewed by C. W. Bird [2] . More recently the incorporation of CO , which enables esters and lactones 2 to be synthesized from olefinic starting materials, has begun to attract attention (see, for example, ref. [3]). The dominant role of palladium as the catalyst for the formation of O-containing heterocycles has been suggested to be associated with the relatively low strength of the Pd-O bond. Among the first examples of a nitrogen-containing heterocycle to be formed by homogeneous catalysis is the triazine shown in Equation 1 which is the product of the trimerization of benzonitrile in the presence of iron penta carbonyl or Raney nickel [4] .
| Author | : Gheorghe Duca |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 484 |
| Release | : 2012-06-15 |
| Genre | : Science |
| ISBN | : 364224629X |
Download Homogeneous Catalysis with Metal Complexes Book in PDF, ePub and Kindle
The book about homogeneous catalysis with metal complexes deals with the description of the reductive-oxidative, metal complexes in a liquid phase (in polar solvents, mainly in water, and less in nonpolar solvents). The exceptional importance of the redox processes in chemical systems, in the reactions occuring in living organisms, the environmental processes, atmosphere, water, soil, and in industrial technologies (especially in food-processing industries) is discussed. The detailed practical aspects of the established regularities are explained for solving the specific practical tasks in various fields of industrial chemistry, biochemistry, medicine, analytical chemistry and ecological chemistry. The main scope of the book is the survey and systematization of the latest advances in homogeneous catalysis with metal complexes. It gives an overview of the research results and practical experience accumulated by the author during the last decade.
| Author | : S. Ted Oyama |
| Publisher | : Elsevier |
| Total Pages | : 524 |
| Release | : 2011-10-13 |
| Genre | : Technology & Engineering |
| ISBN | : 0080558011 |
Download Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis Book in PDF, ePub and Kindle
The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. Comprehensive listing of epoxide products Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts Analysis of the general strengths and weaknesses of varied catalytic systems Detailed description of the mechanisms of reaction for classical and emerging catalysts
