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Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials

Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials
Author: J.F. Harrod
Publisher: Springer Science & Business Media
Total Pages: 352
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9401103372

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In the ten years since the scientific rationale for the design, synthesis and application of inorganic and organometallic polymers (IOPs) was first conceptualised, we have witnessed the first tentative exploration of IOPs as precursors to new materials, with efforts focusing on the design and synthesis of novel ceramic precursors. Developing expertise led to precursor studies combined with the characterisation of the transformation processes that occur when IOPs are converted to ceramic materials. Now at maturity, the science presented in this volume reveals the polymer precursor approach to materials synthesis together with examples of processing ceramic shapes for a range of mechanical properties, the development of sophisticated, noninvasive analytical techniques, and IOP design rationales relying on well-defined processing-property relationships. The production of multifunctional IOPs is described, providing ion conductivity, gas sensing, bioactivity, magnetic properties, etc., combined with processability. The existence of well-defined IOPs and the exquisite control that can be exerted on sol-gel systems now provide access to such a variety of mixed organic-organometallic and/or inorganic hybrid systems that their exploitation is likely to develop into an entirely new field of materials chemistry. Future exciting avenues of research are also being opened up with the advent of buckyballs, Met-Cars, dopable preceramics, rigid-rod organometallics, and molecular tinkertoys.


Organometallic Compounds

Organometallic Compounds
Author: Dakeshwar Kumar Verma
Publisher: John Wiley & Sons
Total Pages: 453
Release: 2023-03-08
Genre: Science
ISBN: 3527351787

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Organometallic Compounds An up-to-date overview of the fundamentals, synthesis, and applications of organometallic compounds Organometallic Compounds: Synthesis, Reactions, and Applications delivers an accessible and robust introduction to the fundamentals of organometallic compounds, including their reactions, catalytic mechanisms, and modern applications, including carbon-dioxide fixation, reduction, gas adsorption and purification, drug delivery, renewable energy, and wastewater treatment. The book also covers toxicological and computational studies. The authors address the current challenges confronting researchers seeking to sustainably synthesize and process organometallic compounds and offer complete coverage on the most recent advancements in applications relating to the fields of environmental science, electronics, fossil fuels, and more. Readers will also find: Introduces to fundamentals, nomenclature, properties, and classification of organometallic compounds Discusses methods of synthesis of organometallic compounds Practical discussions of organometallic complexes of the lanthanoids and actinoids, as well as bio-organometallic chemistry Includes characterization techniques of organometallic compounds Perfect for organic, environmental, inorganic, water, and catalytic chemists, Organometallic Compounds: Synthesis, Reactions, and Applications will also benefit chemical engineers and industrial chemists.


Organometallics in Synthesis

Organometallics in Synthesis
Author: Manfred Schlosser
Publisher: John Wiley & Sons
Total Pages: 1008
Release: 2013-05-28
Genre: Science
ISBN: 1118484754

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WINNER of the 2013 PROSE Award in Chemistry & Physics This latest edition enables readers to master new classes of organometallic compounds and syntheses A popular resource used by synthetic organic chemists around the world, this book enables readers to conduct seamless synthetic reactions involving key organometallics. Each reaction is set forth in the book's acclaimed recipe-style format so that readers can easily replicate the results in their own labs. Moreover, each chapter has been written by a world leader in the field of organometallics in organic synthesis. These authors offer hands-on guidance and practical examples illustrating the preparation of organometallics and its application in organic synthesis. This Third Manual of Organometallics in Synthesis features completely new content and topics, with an eye towards providing researchers with the most useful and practical reference on the synthesis of organometallics. Organized into chapters by type of organometallic compound, the book covers: Organoalkali chemistry Organomagnesium and organozinc chemistry Organosilicon and relating organotin chemistry Organoiron chemistry Organopalladium chemistry Within each chapter, readers will find background information to learn more about the class of organometallics as well as mechanistic considerations. The authors thoroughly discuss the various methods of preparing the organometallic compounds presented in the book and outline their uses in synthetic reactions. In addition to current applications, the authors explore future research opportunities for each organometallic class. References at the end of each chapter enable readers to explore all the topics in greater depth. More and more industrial processes rely on organometallic chemistry. As a result, readers will find this book's step-by-step instructions essential in such fields as natural product synthesis, pharmaceuticals, fine chemicals, biotechnology, polymers, and materials science.


Organometallics in Synthesis

Organometallics in Synthesis
Author: Bruce H. Lipshutz
Publisher: John Wiley & Sons
Total Pages: 528
Release: 2013-12-02
Genre: Science
ISBN: 1118651448

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Provides detailed procedures and useful hints on organometallic reactions of Cu, Rh, Ni, and Au With contributions from leading organic chemists who specialize in the use of organometallics in organic synthesis, this acclaimed Manual offers an especially valuable resource for all synthetic chemists, providing a practical reference for conducting transition metal mediated synthetic reactions. This Fourth Manual is divided into four chapters: Chapter I: Organocopper Chemistry Chapter II: Organorhodium Chemistry Chapter III: Organonickel Chemistry Chapter IV: Organogold Chemistry Each of these newly written chapters features detailed, practical examples from the literature that guide readers through the preparation of organometallic reagents and their applications in organic synthesis. Procedures are presented in the Manual's acclaimed step-by-step recipe format, enabling both novices and experienced synthetic chemists to perform all the reactions with ease. In addition, the Manual features: Extensive background information on the organometallic chemistry of Cu, Rh, Ni, and Au References to the primary literature facilitating further investigation of all the reactions covered in the Manual Mechanistic considerations to help readers better understand how the desired products are formed Future research opportunities for each organometallic class Organometallics in Synthesis provides extensive and detailed information enabling synthetic chemists to readily assess the applicability of a synthetic method to a given need, and then to perform the reaction with confidence. The Manual covers both established organometallic procedures along with the most recently published protocols. Industrial processes are increasingly relying on organometallic chemistry. In this Manual, readers will find applications to such fields as natural products total synthesis, pharmaceuticals, fine chemicals, biotechnology, agricultural science, polymers, and materials science.


Chemistry of Advanced Materials

Chemistry of Advanced Materials
Author: Leonard V. Interrante
Publisher: Wiley-VCH
Total Pages: 600
Release: 1998
Genre: Science
ISBN:

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This is to be initial, 'overview' volume of a series on the "Chemistry of Advanced Materials". This series of volumes is intented to complement VCH's existing series on "Materials Science and Technology" and, in particular, to highlight the role of chemistry in the preparation and processing of advanced materials. The introductory volume in the series is intented to "set the stage" for the succeeding volumes and to introduce the subject of materials chemistry to a general audience of scientifically literate nonspecialists. Subjects covered in this intitial volume will eventually be the subject of one or more individual volumes in the series. This series is directed to a broad audience of chemists and materials scientists. This volume, in particular, should be appropriate for a general scientific audience and be of interest, as well as comprehensible, even to undergraduate students in chemistry and materials science.


Supercritical Fluids and Organometallic Compounds

Supercritical Fluids and Organometallic Compounds
Author: Can Erkey
Publisher: Elsevier
Total Pages: 248
Release: 2011-10-27
Genre: Science
ISBN: 0080914489

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Organometallic compounds are utilized as reagents in the preparation and processing of advanced nanostructured materials, as catalysts in the production of a wide variety of specialty chemicals and polymers, and as drugs. Supercritical fluid science and technology has a wide variety of applications ranging from extraction of pharmaceutically active compounds to the synthesis of advanced materials. The combination of organometallic chemistry and supercritical fluids has significant potential. This book covers the fundamental aspects and related applications in this rapidly growing area. Covers the preparation of nanostructured composite materials using supercritical fluids Focuses on the intersection of organometallic chemistry and supercritical fluids Addresses the behavior of organometallic compounds in supercritical fluid environments


Synthesis and Application of Organoboron Compounds

Synthesis and Application of Organoboron Compounds
Author: Elena Fernández
Publisher: Springer
Total Pages: 334
Release: 2015-03-04
Genre: Science
ISBN: 3319130544

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The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.


Synthesis of Organometallic Compounds

Synthesis of Organometallic Compounds
Author: Sanshiro Komiya
Publisher: John Wiley & Sons
Total Pages: 450
Release: 1997-05-28
Genre: Science
ISBN: 0471971952

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Inorganic Chemistry: Inorganic Chemistry: A Textbook Series This series reflects the breadth of modern research in inorganic chemistry and fulfils the need for advanced texts. The series covers the whole range of inorganic and physical chemistry, solid state chemistry, coordination chemistry, main group chemistry and bioinorganic chemistry. Synthesis of Organometallic Compounds A Practical Guide Edited by Sanshiro Komiya Tokyo University of Agriculture and Technology, Japan. This book describes the concepts of organometallic chemistry and provides an overview of the chemistry of each metal including the synthesis and handling of its important organometallic compounds. Synthesis of Organometallic Compounds: A Practical Guide provides: an excellent introduction to organometallic synthesis detailed synthetic protocols for the most important organometallic syntheses an overview of the reactivity, applications and versatility of organometallic compounds a survey of metals and their organometallic derivatives The purpose of this book is to serve as a practical guide to understanding the general concepts of organometallics for graduate students and scientists who are not necessarily specialists in organometallic chemistry.


Science and Technology of Polymers and Advanced Materials

Science and Technology of Polymers and Advanced Materials
Author: Paras N. Prasad
Publisher: Springer Science & Business Media
Total Pages: 859
Release: 2013-11-11
Genre: Science
ISBN: 1489901124

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This book summarizes the state ofthe art research presented at the Fourth International Conference on Frontiers of Polymersand Advanced Materialsheld in Cairo, Egypt in January 4-9, 1997. This conference follows the successful conferences held in Kuala Lumpur, Malaysia in 1995, in Jakarta, Indonesia in 1993 andin New Delhi, India in 1991. These conferences focussed on the most recent and important advances in a wide range of carefully chosen subject areas dealing with advanced materials, their science and technology and new business opportunities resulting from recent technological advances. As its predecessors, the conference held in Cairo was truly international with strong participation of 488 deiegales representing 37 countries from the USA and Egypt, as weil as Europe, South East Asia, Japan, South Africa and the Middle East. The conference was organized by the Egyptian Academy of Scientific Research and Technology, The Arab Society ofMaterials Science and the State University ofNew Y ork at Butfalo. The stated goals ofthe conference were: • To highlight advances and new. findings in the general area of polymers and advanced materials. - • T o foster global collaboration between the USA, Egypt and other nations in the general field of polymers and advanced materials. • To promote the development of scientific ilifrastructure in this field among the different participating countries, especially in the Middle East. • To create a basisforfuture long-term scientific exchanges between the USA and Egypt, and/or other countries.


The Organometallic Chemistry of the Transition Metals

The Organometallic Chemistry of the Transition Metals
Author: Robert H. Crabtree
Publisher: John Wiley & Sons
Total Pages: 466
Release: 2019-07-18
Genre: Science
ISBN: 1119465885

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Provides vital information on organometallic compounds, their preparation, and use in synthesis, and explores the fundamentals of the field and its modern applications Fully updated and expanded to reflect recent advances, the new, seventh edition of this bestselling text presents students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features up-to-date examples of fundamental reaction steps and greater emphasis on key topics like oxidation catalysis, CH functionalization, nanoclusters and nanoparticles, and green chemistry. New coverage is added for computational chemistry, energy production, and biochemical aspects of organometallic chemistry. The Organometallic Chemistry of the Transition Metals, Seventh Edition provides new/enhanced chapter coverage of ligand-assisted additions and eliminations; proton-coupled electron transfer; surface, supported, and cooperative catalysis; green, energy, and materials applications; and photoredox catalysis. It covers coordination chemistry; alkyls and hydrides; Pi-complexes; and oxidative addition and reductive elimination. The book also features sections on insertion and elimination; spectroscopy; metathesis polymerization and bond activation; and more. Provides an excellent foundation of the fundamentals of organometallic chemistry Includes end-of-chapter problems and their solutions Expands and includes up-to-date examples of fundamental reaction steps and focuses on important topics such as oxidation catalysis, CH functionalization, nanoparticles, and green chemistry Features all new coverage for computational chemistry, energy production, and biochemical aspects of organometallic chemistry The Organometallic Chemistry of the Transition Metals, Seventh Edition is an insightful book that will appeal to all advanced undergraduate and graduate students in organic chemistry, organometallic chemistry, inorganic chemistry, and bioinorganic chemistry, as well as any practicing chemist in those fields.