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An Introduction to Free Radical Chemistry

An Introduction to Free Radical Chemistry
Author: Andrew F. Parsons
Publisher: Wiley-Blackwell
Total Pages: 252
Release: 2000-11-30
Genre: Science
ISBN: 9780632052929

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The past twenty years has seen an explosion of interest in free radicals, as their pivotal role in both chemistry and biology has come to light. This introductory textbook aims to capture this excitement for advanced level undergraduates, with particular emphasis on the importance of radical reactions in organic synthesis. The book provides a gentle, stepwise introduction to the subject, taking the student from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes, allowing the relevance of the subject to be grasped more easily. Suitable for advanced level undergraduates and postgraduates in chemistry and biochemistry, the book will also be invaluable for research level scientists requiring an update in the area.


Free Radicals in Organic Chemistry

Free Radicals in Organic Chemistry
Author: Jacques Fossey
Publisher:
Total Pages: 328
Release: 1995-11-09
Genre: Business & Economics
ISBN:

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Free radicals constitute the most frequently used class of reaction intermediates in organic chemistry. This study describes the structure and reactivity of free radicals, and explores their role in both natural phenomena and in the design of new reaction pathways.


Free Radicals in Solution

Free Radicals in Solution
Author: Cheves Walling
Publisher:
Total Pages: 654
Release: 1957
Genre: Science
ISBN:

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Free-Radical Chemistry

Free-Radical Chemistry
Author: D. C. Nonhebel
Publisher: CUP Archive
Total Pages: 620
Release: 1974-01-31
Genre: Science
ISBN: 9780521201490

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The Chemistry of Free Radicals

The Chemistry of Free Radicals
Author: Rayson L. Huang
Publisher: Hodder Education
Total Pages: 264
Release: 1974
Genre: Science
ISBN:

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The Positive Muon as a Probe in Free Radical Chemistry

The Positive Muon as a Probe in Free Radical Chemistry
Author: Emil Roduner
Publisher: Springer Science & Business Media
Total Pages: 113
Release: 2012-12-06
Genre: Science
ISBN: 364251720X

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The work presented here is a result of an extended collaboration with a number of coworkers and guests. Particularly, I would like to thank Dr. P. Burkhard and Dr. W. Strub for their careful work performed for their Ph. D. thesis and Dr. M. Heming for his brilliant ideas and his dedication. Very fruitful and stimulating were collaborations with our guests, i. e. with G. A. Brinkman and P. W. F. Louwrier from NIKHEF-K in Amsterdam, B. C. Webster, M. J. Ramos and D. McKenna from the University of Glasgow, M. C. R. Symons, D. Geeson and C. J. Rhodes from the University of Leicester, S. F. J. Cox and C. A. Scott from the Rutherford Appleton Laboratory in Chilton, and R. De Renzi and M. Ricco from the University of Parma. Many invaluable discussions with friends and competitors in the field helped to address new viewpoints and to define new goals. I shall not forget my teacher and director of the radical chemistry group, Prof. H. Fischer, whom I wish to thank for his interest and active support and for the great liberty he allowed me for the planning and organization of the project. Last but not least, I thank my dear wife Hanny and our children Christian, Martin and Andrea who suffered, without complaint, daddy's absence for so many hours.


Half a Century of Free Radical Chemistry

Half a Century of Free Radical Chemistry
Author: Derek H. R. Barton
Publisher: Cambridge University Press
Total Pages: 180
Release: 1993-04-15
Genre: Science
ISBN: 9780521445801

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This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involving phenolate radical coupling. There follows 20 years of practical work to prove the theory correct, especially in the case of morphine alkaloids. The book then describes the work on nitrile photolysis (Barton reaction) which involved the invention of new radical chemistry leading to a simple synthesis of the important hormone, aldosterone. There follows a description of the invention of an important new method for the deoxygenation of biologically important molecules, especially sugars and nucleosides, using radical chemistry applied to thiocarbonyl derivatives. Some years later, in a logical extension to carboxylic acids, another new reaction was invented which provides carbon, nitrogen, oxygen and other radicals under mild conditions. A final chapter summarizes recent applications of thiocarbonyl group derived radical reactions by other authors.


The Spectra and Structures of Simple Free Radicals

The Spectra and Structures of Simple Free Radicals
Author: Gerhard Herzberg
Publisher: Courier Corporation
Total Pages: 242
Release: 1988-01-01
Genre: Technology & Engineering
ISBN: 048665821X

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"Authoritative and clearly written."—Applied Optics The direct observation of short-lived free radicals and the consequent study of their structure and reactions have led to important developments in almost every branch of chemistry as well as in other areas. This volume by a Nobel laureate offers an excellent introduction to the essentials of molecular spectroscopy. The introductory chapter discusses experimental methods and illustrates the observed spectra of various molecules and free radicals. Subsequent chapters explore rotational, vibrational, and electronic energy levels of diatomic molecules and ions; radiative transitions; linear and nonlinear polyatomic radicals and ions; continuous and diffuse spectra; predissociation and pre-ionization; and recombination. The well-illustrated text features more than 100 figures and spectra. A distilled version of the author's monumental three-volume study, Molecular Spectra and Molecular Structure, it constitutes a superb resource for anyone wishing a concise but complete treatment of the fundamentals of molecular spectroscopy.