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The Chemistry of Matter Waves

The Chemistry of Matter Waves
Author: Jan C.A. Boeyens
Publisher: Springer Science & Business Media
Total Pages: 250
Release: 2013-08-13
Genre: Science
ISBN: 9400775784

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The quantum and relativity theories of physics are considered to underpin all of science in an absolute sense. This monograph argues against this proposition primarily on the basis of the two theories' incompatibility and of some untenable philosophical implications of the quantum model. Elementary matter is assumed in both theories to occur as zero-dimensional point particles. In relativity theory this requires the space-like region of the underlying Minkowski space-time to be rejected as unphysical, despite its precise mathematical characterization. In quantum theory it leads to an incomprehensible interpretation of the wave nature of matter in terms of a probability function and the equally obscure concept of wave-particle duality. The most worrisome aspect about quantum mechanics as a theory of chemistry is its total inability, despite unsubstantiated claims to the contrary, to account for the fundamental concepts of electron spin, molecular structure, and the periodic table of the elements. A remedy of all these defects by reformulation of both theories as nonlinear wave models in four-dimensional space-time is described.


University Physics

University Physics
Author: OpenStax
Publisher:
Total Pages: 622
Release: 2016-11-04
Genre: Science
ISBN: 9781680920451

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University Physics is a three-volume collection that meets the scope and sequence requirements for two- and three-semester calculus-based physics courses. Volume 1 covers mechanics, sound, oscillations, and waves. Volume 2 covers thermodynamics, electricity and magnetism, and Volume 3 covers optics and modern physics. This textbook emphasizes connections between between theory and application, making physics concepts interesting and accessible to students while maintaining the mathematical rigor inherent in the subject. Frequent, strong examples focus on how to approach a problem, how to work with the equations, and how to check and generalize the result. The text and images in this textbook are grayscale.


Explicitly Correlated Wave Functions in Chemistry and Physics

Explicitly Correlated Wave Functions in Chemistry and Physics
Author: J. Rychlewski
Publisher: Springer Science & Business Media
Total Pages: 588
Release: 2003-11-30
Genre: Science
ISBN: 9781402016745

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Explicitly Correlated Wave Functions in Chemistry and Physics is the first book devoted entirely to explicitly correlated wave functions and their theory and applications in chemistry and molecular and atomic physics. Explicitly correlated wave functions are functions that depend explicitly on interelectronic distance. The book covers a wide range of methods based on explicitly correlated functions written by leaders in the field, including Kutzelnigg, Jeziorski, Szalewicz, Klopper and Noga. The book begins with a chapter on the theory of electron correlation and then the following three chapters describe different types of functions that can be used to solve the electronic Schrödinger equation for atoms and molecules. The book goes on to discuss the effects that go beyond the Born-Oppenheimer approximation, theory of relativistic effects, solution of the Dirac-Colomb equation, and relativistic correction using ECG functions. The last part of the book reviews applications of EC functions to calculate atomic and molecular properties and to study positronic systems, resonance states of atoms and nuclear dynamics of the hydrogen molecular ion.


Molecular Beams in Physics and Chemistry

Molecular Beams in Physics and Chemistry
Author: Bretislav Friedrich
Publisher: Springer Nature
Total Pages: 639
Release: 2021-06-19
Genre: Science
ISBN: 3030639630

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This Open Access book gives a comprehensive account of both the history and current achievements of molecular beam research. In 1919, Otto Stern launched the revolutionary molecular beam technique. This technique made it possible to send atoms and molecules with well-defined momentum through vacuum and to measure with high accuracy the deflections they underwent when acted upon by transversal forces. These measurements revealed unforeseen quantum properties of nuclei, atoms, and molecules that became the basis for our current understanding of quantum matter. This volume shows that many key areas of modern physics and chemistry owe their beginnings to the seminal molecular beam work of Otto Stern and his school. Written by internationally recognized experts, the contributions in this volume will help experienced researchers and incoming graduate students alike to keep abreast of current developments in molecular beam research as well as to appreciate the history and evolution of this powerful method and the knowledge it reveals.


Reconstruction of Wave-Particle Duality and its Implications for General Chemistry Textbooks

Reconstruction of Wave-Particle Duality and its Implications for General Chemistry Textbooks
Author: Mansoor Niaz
Publisher: Springer Science & Business Media
Total Pages: 51
Release: 2012-04-26
Genre: Science
ISBN: 9400743963

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It goes without saying that atomic structure, including its dual wave-particle nature, cannot be demonstrated in the classroom. Thus, for most science teachers, especially those in physics and chemistry, the textbook is their key resource and their students’ core source of information. Science education historiography recognizes the role played by the history and philosophy of science in developing the content of our textbooks, and with this in mind, the authors analyze more than 120 general chemistry textbooks published in the USA, based on criteria derived from a historical reconstruction of wave-particle duality. They come to some revealing conclusions, including the fact that very few textbooks discussed issues such as the suggestion, by both Einstein and de Broglie, and before conclusive experimental evidence was available, that wave-particle duality existed. Other large-scale omissions included de Broglie’s prescription for observing this duality, and the importance of the Davisson-Germer experiments, as well as the struggle to interpret the experimental data they were collecting. Also untouched was the background to the role played by Schrödinger in developing de Broglie’s ideas. The authors argue that rectifying these deficiencies will arouse students’ curiosity by giving them the opportunity to engage creatively with the content of science curricula. They also assert that it isn’t just the experimental data in science that matters, but the theoretical insights and unwonted inspirations, too. In addition, the controversies and discrepancies in the theoretical and experimental record are key drivers in understanding the development of science as we know it today.


Ideas of Quantum Chemistry

Ideas of Quantum Chemistry
Author: Lucjan Piela
Publisher: Elsevier
Total Pages: 1122
Release: 2006-11-28
Genre: Science
ISBN: 0080466761

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Ideas of Quantum Chemistry shows how quantum mechanics is applied to chemistry to give it a theoretical foundation. The structure of the book (a TREE-form) emphasizes the logical relationships between various topics, facts and methods. It shows the reader which parts of the text are needed for understanding specific aspects of the subject matter. Interspersed throughout the text are short biographies of key scientists and their contributions to the development of the field.Ideas of Quantum Chemistry has both textbook and reference work aspects. Like a textbook, the material is organized into digestable sections with each chapter following the same structure. It answers frequently asked questions and highlights the most important conclusions and the essential mathematical formulae in the text. In its reference aspects, it has a broader range than traditional quantum chemistry books and reviews virtually all of the pertinent literature. It is useful both for beginners as well as specialists in advanced topics of quantum chemistry. The book is supplemented by an appendix on the Internet. * Presents the widest range of quantum chemical problems covered in one book * Unique structure allows material to be tailored to the specific needs of the reader * Informal language facilitates the understanding of difficult topics


Controlling the Quantum World

Controlling the Quantum World
Author: National Research Council
Publisher: National Academies Press
Total Pages: 245
Release: 2007-06-21
Genre: Science
ISBN: 0309102707

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As part of the Physics 2010 decadal survey project, the Department of Energy and the National Science Foundation requested that the National Research Council assess the opportunities, over roughly the next decade, in atomic, molecular, and optical (AMO) science and technology. In particular, the National Research Council was asked to cover the state of AMO science, emphasizing recent accomplishments and identifying new and compelling scientific questions. Controlling the Quantum World, discusses both the roles and challenges for AMO science in instrumentation; scientific research near absolute zero; development of extremely intense x-ray and laser sources; exploration and control of molecular processes; photonics at the nanoscale level; and development of quantum information technology. This book also offers an assessment of and recommendations about critical issues concerning maintaining U.S. leadership in AMO science and technology.


An Introduction To Quantum Chemistry

An Introduction To Quantum Chemistry
Author: Satake & Taguchi
Publisher: Discovery Publishing House
Total Pages: 334
Release: 1996
Genre:
ISBN: 9788171413324

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Contents: Introduction, Some Mathematical Concepts, The Classical Theory of Vibrations, Two and Three Dimensions Waves, The Quantum Hypothesis, The Bohr Model and Matter Waves, Particle Waves and Quantum Mechanics, Wave Mechanics of Sum Simple Systems, The Hydrogen Atom, The Helium Atom, Many Electron Atoms.


Explicitly Correlated Wave Functions in Chemistry and Physics

Explicitly Correlated Wave Functions in Chemistry and Physics
Author: J. Rychlewski
Publisher: Springer Science & Business Media
Total Pages: 573
Release: 2013-03-14
Genre: Science
ISBN: 9401703132

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Explicitly Correlated Wave Functions in Chemistry and Physics is the first book devoted entirely to explicitly correlated wave functions and their theory and applications in chemistry and molecular and atomic physics. Explicitly correlated wave functions are functions that depend explicitly on interelectronic distance. The book covers a wide range of methods based on explicitly correlated functions written by leaders in the field, including Kutzelnigg, Jeziorski, Szalewicz, Klopper and Noga. The book begins with a chapter on the theory of electron correlation and then the following three chapters describe different types of functions that can be used to solve the electronic Schrödinger equation for atoms and molecules. The book goes on to discuss the effects that go beyond the Born-Oppenheimer approximation, theory of relativistic effects, solution of the Dirac-Colomb equation, and relativistic correction using ECG functions. The last part of the book reviews applications of EC functions to calculate atomic and molecular properties and to study positronic systems, resonance states of atoms and nuclear dynamics of the hydrogen molecular ion.


Quantum Chemistry

Quantum Chemistry
Author: John P. Lowe
Publisher: Elsevier
Total Pages: 732
Release: 2012-12-02
Genre: Science
ISBN: 0080515541

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Praised for its appealing writing style and clear pedagogy, Lowe's Quantum Chemistry is now available in its Second Edition as a text for senior undergraduate- and graduate-level chemistry students. The book assumes little mathematical or physical sophistication and emphasizes an understanding of the techniques and results of quantum chemistry, thus enabling students to comprehend much of the current chemical literature in which quantum chemical methods or concepts are used as tools. The book begins with a six-chapter introduction of standard one-dimensional systems, the hydrogen atom, many-electron atoms, and principles of quantum mechanics. It then provides thorough treatments of variation and perturbation methods, group theory, ab initio theory, Huckel and extended Huckel methods, qualitative MO theory, and MO theory of periodic systems. Chapters are completed with exercises to facilitate self-study. Solutions to selected exercises are included. Assumes little mathematical or physical sophistication Emphasizes understanding of the techniques and results of quantum chemistry Includes improved coverage of time-dependent phenomena, term symbols, and molecular rotation and vibration Provides a new chapter on molecular orbital theory of periodic systems Features new exercise sets with solutions Includes a helpful new appendix that compiles angular momentum rules from operator algebra