Synthetic And Stereochemical Aspect Of The Organic Chemistry Of Phosphorous PDF Download
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Author | : P. F. Kerr |
Publisher | : |
Total Pages | : |
Release | : 1980 |
Genre | : |
ISBN | : |
Download Synthetic and Stereochemical Aspect of the Organic Chemistry of Phosphorous Book in PDF, ePub and Kindle
Author | : Harold Goldwhite |
Publisher | : Cambridge University Press |
Total Pages | : 132 |
Release | : 1981-04-30 |
Genre | : Science |
ISBN | : 9780521229784 |
Download Introduction to Phosphorous Chemistry Book in PDF, ePub and Kindle
This 1981 introduction to the chemistry of a single element, phosphorus, covers many of the major themes of chemistry. Important in inorganic and organic chemistry and in biochemistry, phosphorus is also of considerable economic significance and plays a vital role in the biosphere. By presenting a detailed treatment of selected topics, this book provides a concise account of phosphorus chemistry suitable for anyone with an interest in the field. The book provides a survey of phosphorus compounds by structural and bond types, a review of physical methods in phosphorus chemistry, a review of basicity and co-ordination chemistry of phosphorus donors, a discussion of phosphorus in its group, and a chapter on reagents containing phosphorus in general chemistry. A critical bibliography introduces the reader to the advanced literature. S. I. Units are used throughout, but c.g.s units are also given when appropriate.
Author | : Jean-Pierre Majoral |
Publisher | : Springer Science & Business Media |
Total Pages | : 268 |
Release | : 2002 |
Genre | : Biochemistry |
ISBN | : 3540440860 |
Download New Aspects in Phosphorus Chemistry II Book in PDF, ePub and Kindle
Strong non-ionic bases are highly advantageous as stoichiometric reagents and as catalysts in synthetic organic chemistry owing to side reactions that f- quently occur when ionic bases such as LDA or alkali metal alkoxides are employed. A second reason that non-ionic bases are frequently more useful in these applications is that such bases are often more soluble in less polar organic solvents, particularly at low temperatures. Thirdly, non-ionic bases can provide reactive naked or tightly associated deprotonated substrate anions that are s- bilized by the relatively large, poorly solvated cations formed by the protonated base. In such cations, extensive positive charge delocalization can occur. Prior to our work on pro-azaphosphatranes of type 1 (Scheme 1), the very strong n- ionic bases utilized for organic transformations were largely confined to the nitrogenous bases shown below (Scheme 2). Scheme 1 Scheme 2 4 J.G. Verkade 2 Uses of Strong Nonionic Nitrogen Bases 2. 1 Amines One of the earliest strong non-ionic bases to make its appearance was Proton Sponge and its derivatives [1] and these systems have been reviewed [2]. More recently Proton Sponge has been used in the palladium-catalyzed arylation of 2,3-dihydrofuran [3], and it also catalyzes Knoevenagel condensations of s- strates possessing activated methylene groups [4]. Recently the synthesis of the macrocyclic tetramine below (Scheme 3) was reported [5]. The encrypted nitrogens are very basic (pK,24.
Author | : Oleg I. Kolodiazhnyi |
Publisher | : John Wiley & Sons |
Total Pages | : 392 |
Release | : 2016-09-20 |
Genre | : Science |
ISBN | : 352734151X |
Download Asymmetric Synthesis in Organophosphorus Chemistry Book in PDF, ePub and Kindle
Authored by one of the leading experts in the field, this is the only comprehensive overview of chiral organophosphorus compounds, from asymmetric synthesis to catalysis and pharmacological applications. As such, this unique reference covers the chemical background as well as spectroscopical analysis of phosphorus compounds, and thoroughly describes all the various synthetic strategies for these substances. Metal-, organo- and biocatalyzed reactions for the introduction of phosphorus are explained as are asymmetric oxidation and reduction methods for the preparation of all possible oxidation states of phosphorus. The text also includes industrial applications for these compounds. Of particular interest to chemists working in the field of asymmetric synthesis, as well as to the pharmaceutical industry due to the increasing number of phosphorous-containing drugs.
Author | : Louis D. Quin |
Publisher | : John Wiley & Sons |
Total Pages | : 416 |
Release | : 2000-02-04 |
Genre | : Science |
ISBN | : 9780471318248 |
Download A Guide to Organophosphorus Chemistry Book in PDF, ePub and Kindle
Die organische Chemie des Phosphors - ein großes, äußerst lebendiges Forschungsfeld - umfaßt sowohl Verbindungen mit Kohlenstoff-Phosphor-Bindungen als auch organische Ester anorganischer Phosphorsäuren. Dieser Band behandelt die meisten phosphorhaltigen funktionellen Gruppen und daneben aktuelle Fragen wie z.B. ungewöhnliche Koordinationszustände, Heterocyclen, Anwendungen der 31P-NMR und andere spektroskopische Verfahren. Soweit bekannt, werden auch elektronische Reaktionsmechanismen und reaktive Intermediate diskutiert. Mit zahlreichen Literaturhinweisen! (03/00)
Author | : Oleg I. Kolodiazhnyi |
Publisher | : John Wiley & Sons |
Total Pages | : 568 |
Release | : 2008-09-26 |
Genre | : Science |
ISBN | : 3527613919 |
Download Phosphorus Ylides Book in PDF, ePub and Kindle
When Wittig first developed and described phosphorus ylides, nobody could have imagined how useful and versatile this class of compounds could be. This book provides a comprehensive and up-to-date compilation of the chemistry and applications of phosphorus ylides in organic synthesis. The ylides are discussed as reagents in the synthesis of a broad range of substances, amongst them olefins, acetylenes, cyclic and heterocyclic compounds, in such naturally occurring compounds as pheromones, steroids and carotenoids, and pharmaceutically and biologically active compounds such as antibiotics and prostaglandins. A particularly beneficial feature of this book is the 150 key experimental procedures with all the necessary data, allowing the preparation to start immediately without the need for an extremely time-consuming literature search. But should a search prove inevitable, around 2,500 references provide easy access to the primary literature. Every chemist in academia and industry working in organic, bioorganic, inorganic, and medicinal chemistry will welcome this book as an inspiration of concepts, ideas and practical syntheses.
Author | : Abraham Nudelman |
Publisher | : |
Total Pages | : 340 |
Release | : 1969 |
Genre | : Organophosphorus compounds |
ISBN | : |
Download Synthetic and Stereochemical Studies of Organo-phosphorus and Organo-sulfur Compounds Book in PDF, ePub and Kindle
Author | : Jean-Luc Montchamp |
Publisher | : Springer |
Total Pages | : 283 |
Release | : 2015-03-06 |
Genre | : Science |
ISBN | : 3319155121 |
Download Phosphorus Chemistry II Book in PDF, ePub and Kindle
Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Author | : Anthony John Kirby |
Publisher | : |
Total Pages | : 424 |
Release | : 1967 |
Genre | : Science |
ISBN | : |
Download The Organic Chemistry of Phosphorus Book in PDF, ePub and Kindle
Author | : Robert Engel |
Publisher | : CRC Press |
Total Pages | : 896 |
Release | : 1992-06-19 |
Genre | : Science |
ISBN | : 1482277247 |
Download Handbook of Organophosphorus Chemistry Book in PDF, ePub and Kindle
This practical work summarizes the development of organophosphorus chemistry in topical areas and details the discipline's current state - providing applications and experimental procedures throughout.;Written by 18 leading authorities in the field, the Handbook of Organophosphorus Chemistry: examines advances in the mechanistic understanding of th