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Silicon and Siliceous Structures in Biological Systems

Silicon and Siliceous Structures in Biological Systems
Author: T.L. Simpson
Publisher: Springer Science & Business Media
Total Pages: 589
Release: 2012-12-06
Genre: Science
ISBN: 1461259444

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The publication of this book was undertaken with two purposes in view: to bring together informatian on the deposition by living organ isms of unique skeletal structures composed of amorphous silica, and to review recent data on the involvement of silicon in physiological and biochemical processes. Although widely varying viewpoints are represented, all the contributors are very interested in the events in volved in the formatian of siliceaus structures and their function. Data presented deal with these questions in a variety of plant and animal systems, and at levels ranging from the evolutionary to the biochemical and ultrastructural. Innovations in electron microscopy and, indeed, the advent of electron microscopy itself, have stimulated many ultra structural studies of silica deposition, work which has deepened and widened the interest in those organisms which routinely produce "glassy skeletons. " The question of how silicon participates in biological systems in volves a spectrum of fields that indudes the chemistry of silicon per se, its biogeochemistry, biochemistry, ecology, and so forth. In this book, however, attention is focused up on the biological aspects of silicon and siliceous structures, with emphasis on the evolutian, phylogeny, morphology, and distribution of siliceaus structures, on the cellular as peets of silica deposition, and on the physiological and biochemical roles of silicon. This volume represents the first compilatian of such data. Because such a variety of subjects and fields are covered, the reader will have to glean for himself some of the comparative aspects of the data.


Silicon-based Materials in Biological Environments

Silicon-based Materials in Biological Environments
Author:
Publisher:
Total Pages:
Release: 2005
Genre:
ISBN:

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The liberation of poly(dimethylsiloxane) fluid, from the inside of silicone breast implants by diffusion and/or implant rupture, has been associated with a variety of rheumatologic disorders in patients who have received them. Continued use of these materials necessitates a better understanding of how they are created and/or utilized by biological systems. In order to determine if a fibrinogen-dependent process could play a role in the dissemination of PDMS fluid in vivo, I used histological methods in conjunction with ICP-AES to assess the dissemination of silicone droplets in normal mice and in mice lacking fibrinogen. I found that mice lacking fibrinogen had no evidence of dissemination after an administration of emulsified PDMS. In contrast, mice with normal amounts of fibrinogen showed significant evidence of dissemination, suggesting that fibrinogen has a mechanistic role on the dissemination of PDMS in vivo. I also investigated a model biological system capable of processing silicon in nature. Marine diatoms use short cationic peptides to synthesize silica. I hypothesized that if the human body was capable of silicone degradation, such peptide sequences or the key residues therein might be involved. Therefore, I characterized the reaction kinetics and resulting product morphology attributed to several silica-precipitating peptide sequences derived from the diatom Cylindrotheca fusiformis in order to better understand how biologic systems process silicon. During the course of my investigations, I used the model system to produce novel silica nano-structures and incorporate them into polymeric matrices for device application. Herein I present my research on silicon-based materials and its relevance to bioengineering. The topics covered by my research include: (1) the role of fibrinogen in the dissemination of PDMS in vivo, (2) the kinetics of silica formation mediated by cationic peptides in vitro, (3) the formation of novel silica nanostructures by those same peptides and (4) the development and characterization of a silica-containing organic/inorganic hybrid material utilizing a silica-precipitating peptide.


Silicon Biomineralization

Silicon Biomineralization
Author: Werner E. G. Müller
Publisher: Springer Science & Business Media
Total Pages: 342
Release: 2012-12-06
Genre: Science
ISBN: 3642554865

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During evolution silica deposition has been used in Protozoa, Metazoa and in plants as skeletal elements. It appears that the mechanisms for the formation of biogenic silica have evolved independently in these three taxa. In Protozoa and plants biosilicification appears to be primarily driven by non-enzymatic processes and procedes on organic matrices. In contrast, in sponges (phylum Porifera) this process is mediated by enzymes; the initiation of this process is likewise dependent on organic matrices. In this monograph the role of biosilica as stabilizing structures in different organisms is reviewed and their role for morphogenetic processes is outlined. It provides an up-to-date summary of the mechanisms by which polymeric biosilica is formed. The volume is intended for biologists, biochemists and molecular biologists, involved in the understanding of structure formation in living organisms and will also be very useful for scientists working in the field of applied Nanotechnology and Nanobiotechnology.


Biochemistry of Silicon and Related Problems

Biochemistry of Silicon and Related Problems
Author: Gerd Bendz
Publisher: Springer Science & Business Media
Total Pages: 585
Release: 2013-06-29
Genre: Science
ISBN: 1461340187

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Silicon chemistry was initiated in 1823 by Berzelius who prepared elemental silicon. In many ways silicon was considered a typical opposite of carbon, although the two elements are closely related as to their electronic structure, both having four valence electrons. The properties of their compounds are, however, extreme ly different. Both form extended structures, but in different ways - carbon by covalent carbon-carbon bonds; silicon by polar silicon- -oxygen-silicon bonds. The complex carbon compounds are integral parts of all living matter, plants and animals. The corresponding silicon compounds build up a major part of dead matter, soils and minerals. As recently as twenty years ago the title of this Symposium, "BiOChemistry of Silicon", would have been considered as contradictio in adjecto. However, the development in the field has, during the past fifteen years, been overwhelming and has convinced us that silicon is a necessary element in the life processes, for animals as well as for plants. Interesting therapeutical uses have been suggested, but we have also become increasingly aware of serious occupational diseases - asbestosis and silicosis - and of possible cancerogenic effects. It is our hope that this volume will give some idea about various aspects of silicon compounds which were discussed during the Symposium.


The Protistan Cell Surface

The Protistan Cell Surface
Author: Richard Wetherbee
Publisher: Springer Science & Business Media
Total Pages: 297
Release: 2012-12-06
Genre: Science
ISBN: 3709193788

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Protists represent an immensely diverse group of organisms comprised of algae, fungi and protozoa. The nature of protistan cell surface is as diverse as the terminology that has evolved to describe the various surface components. This terminology is defined and discussed in the opening of this book. The remaining contributions provide an up-to-date synopsis of structure, development and function of protistan cell surfaces, including their role in taxonomy and systematics.


Silicon Biochemistry

Silicon Biochemistry
Author: David Evered
Publisher: John Wiley & Sons
Total Pages: 272
Release: 2008-04-30
Genre: Science
ISBN: 0470513330

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The Novartis Foundation Series is a popular collection of the proceedings from Novartis Foundation Symposia, in which groups of leading scientists from a range of topics across biology, chemistry and medicine assembled to present papers and discuss results. The Novartis Foundation, originally known as the Ciba Foundation, is well known to scientists and clinicians around the world.


Biochemistry of the Essential Ultratrace Elements

Biochemistry of the Essential Ultratrace Elements
Author: Earl Frieden
Publisher: Springer Science & Business Media
Total Pages: 433
Release: 2012-12-06
Genre: Science
ISBN: 1468447750

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The remarkable development of molecular biology has had its counterpart in an impressive growth of a segment of biology that might be described as atomic biology. The past several decades have witnessed an explosive growth in our knowledge of the many elements that are essential for life and maintenance of plants and animals. These essential elements include the bulk elements (hydro gen, carbon, nitrogen, oxygen, and sulfur), the macrominerals (sodium, potas sium, calcium, magnesium, chloride, and phosphorus), and the trace elements. This last group includes the ultra trace elements and iron, zinc, and copper. Only the ultratrace elements are featured in this book. Iron has attracted so much research that two volumes are devoted to this metal-The Biochemistry of Non-Heme Iron by A. Bezkoravainy, Plenum Press, 1980, and The Biochemistry of Heme Iron (in preparation). Copper and zinc are also represented by a separate volume in this series. The present volume begins with a discussion of essentiality as applied to the elements and a survey of the entire spectrum of possible required elements.


Origin, Evolution, and Modern Aspects of Biomineralization in Plants and Animals

Origin, Evolution, and Modern Aspects of Biomineralization in Plants and Animals
Author: Rex E. Crick
Publisher: Springer Science & Business Media
Total Pages: 532
Release: 2013-11-11
Genre: Science
ISBN: 1475761147

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The Fifth International Biomineralization Symposium was held in May 1986 at The University of Texas at Arlington, Arlington, Texas. The chosen theme was the origin, evolution and modern aspects of biomineralization in plants and animals. Thus, the symposium was designed to bring together experts in ocean and atmospheric chemistry, geochemistry, paleontology, biology, medicine and related fields to share accumulated knowledge and to broaden research horizons. The contents of this volume reflect the diversified interests and views of contributors from these fields. Topics range from contrasting views of the origin of ocean chemistry, the cause or causes for the biomineralization among plants and animals, the evolution of style and structure of biomineralization, and the role of inorganic and organic compounds in biomineraliza tion. It was clear from those gathered in Arlington that the efforts of all researchers in any aspect of biomineralization can be strengthened and extended by greater exposure to the work of others in allied fields. At the time of this printing, several collaborative efforts have grown from interest and contacts developed during the symposium. Rex E. Crick viii ACKNOWLEDGEMENTS The symposium would not have occurred with the financial support of The Organized Research Fund of The University of Texas at Arlington and The Sea Grant Program administered by Texas A & M University. The staff of the Department of Geology of The University of Texas at Arlington were largely responsible for providing a pleasant atmosphere for learning.


Author: Humphrey John Moule Bowen
Publisher: Royal Society of Chemistry
Total Pages: 156
Release: 1984
Genre:
ISBN: 0851867758

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Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.