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Recent Advances in Mechanistic and Synthetic Aspects of Polymerization

Recent Advances in Mechanistic and Synthetic Aspects of Polymerization
Author: M. Fontanille
Publisher: Springer Science & Business Media
Total Pages: 555
Release: 2012-12-06
Genre: Science
ISBN: 9400939892

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Due to their specific properties, polymers with well-defined structures have been receiving increasing attention over the last several years. Owing to the wide variability of their properties, these specialty polymers have been used in various areas from biomedical engineering to electronics or energy applications. The synthesis of such polymers necessi tates the use of new methods of polymerization which derived from an insight into the mechanism of polymerization reactions. A NATO Advanced Research Workshop on "Frontiers in Polymerization Catalysis and Polymer Synthesis" was held in BANDOl (FRANCE) in February 1987. Its aim was to assess the new polymerization methods, as well as the latest advances in the mechanisms of conventional polymerization reactions together with their applications to the synthesis of new macromolecular structures. The financial support from the NATO Scientific Affairs Division which covered the "lecturers' accomodation and travel expenses as well as the organization charges of this event gave it international scope. Several industrial companies participate at the meeting and contributed to it success. The organizors who are also editors of these proceedings, want to express their thanks to both NATO Scientific Affairs Division and the companies present at the meeting.


New Methods Polymer Synthesis

New Methods Polymer Synthesis
Author: J. R. Ebdon
Publisher: Springer Science & Business Media
Total Pages: 209
Release: 2012-12-06
Genre: Science
ISBN: 1468415301

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Most practitioners and students of polymer chemistry are familiar, in general terms at least, with the established methods of polymer synthesis - radical, anionic, cationic and coordination addition polymerization, and stepwise con densation and rearrangement polymerization. These methods are used to synthesize the majority of polymers used in the manufacture of commercially important plastics, fibres, resins and rubbers, and are covered in most introduc tory polymer chemistry textbooks and in most undergraduate and graduate courses on polymer science. Fewer polymer chemists, however, have much familiarity with more recent developments in methods of polymer synthesis, unless they have been specifically involved for some time in the synthesis of speciality polymers. These developments include not only refinements to established methods but also new mechanisms of polymerization, such as group transfer and metathesis polymerization and novel non-polymerization routes to speciality polymers involving, for example, the chemical modification of preformed polymers or the linking together of short terminally functionalized blocks.


New Methods of Polymer Synthesis

New Methods of Polymer Synthesis
Author: J.R. Ebdon
Publisher: Springer Science & Business Media
Total Pages: 209
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9401095523

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Most practitioners and students of polymer chemistry are familiar, in general terms at least, with the established methods of polymer synthesis - radical, anionic, cationic and coordination addition polymerization, and stepwise con densation and rearrangement polymerization. These methods are used to synthesize the majority of polymers used in the manufacture of commercially important plastics, fibres, resins and rubbers, and are covered in most introduc tory polymer chemistry textbooks and in most undergraduate and graduate courses on polymer science. Fewer polymer chemists, however, have much familiarity with more recent developments in methods of polymer synthesis, unless they have been specifically involved for some time in the synthesis of speciality polymers. These developments include not only refinements to established methods but also new mechanisms of polymerization, such as group transfer and metathesis polymerization and novel non-polymerization routes to speciality polymers involving, for example, the chemical modification of preformed polymers or the linking together of short terminally functionalized blocks.


Silicon in Polymer Synthesis

Silicon in Polymer Synthesis
Author: H.R. Kricheldorf
Publisher: Springer Science & Business Media
Total Pages: 507
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 3642791751

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Silicon in Polymer Synthesis gives the first concise overview of silicon used for the synthesis and modification of polymers. The first section gives an introduction to the topic. The subsequent chapters detail the current status both from the basic research as well as from the industrial application points of view.


Anionic Polymerization

Anionic Polymerization
Author: Henry Hsieh
Publisher: CRC Press
Total Pages: 748
Release: 1996-03-15
Genre: Technology & Engineering
ISBN: 9780824795238

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This work introduces the basic theories and experimental methods of anionic polymerization as well as the synthesis, analysis and characteristics of anionic polymerized products. It details the creation of linear and branched polymers, random and block copolymers, graft and macromonomers, and many other substances. The work emphasizes the relationship between fundamental principles and commercial applications.;College or university bookstores may purchase five or more copies at a special student price, available on request from Marcel Dekker, Inc.


Principles of Polymer Systems

Principles of Polymer Systems
Author: Ferdinand Rodriguez
Publisher: CRC Press
Total Pages: 796
Release: 2014-12-09
Genre: Science
ISBN: 1482223791

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A classic text in the field of chemical engineering, this revised sixth edition offers a comprehensive exploration of polymers at a level geared toward upper-level undergraduates and beginning graduate students. It contains more theoretical background for some of the fundamental concepts pertaining to polymer structure and behavior, while also providing an up-to-date discussion of the latest developments in polymerization systems. New problems have been added to several of the chapters, and a solutions manual is available upon qualifying course adoption.


Functional Polymers

Functional Polymers
Author: Raja Shunmugam
Publisher: CRC Press
Total Pages: 327
Release: 2017-05-08
Genre: Science
ISBN: 1315342316

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This new book covers the synthetic as well application aspects of functional polymers. It highlights modern trends in the field and showcases the recent characterization techniques that are being employed in the field of polymer science. The chapters are written by top-notch scientists who are internationally recognized in the field. The chapters will highlight the modern trend in the field.


Controlled and Living Polymerizations

Controlled and Living Polymerizations
Author: Krzysztof Matyjaszewski
Publisher: John Wiley & Sons
Total Pages: 634
Release: 2009-12-23
Genre: Science
ISBN: 9783527629107

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Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.


Ionomers

Ionomers
Author: M.R. Tant
Publisher: Springer Science & Business Media
Total Pages: 524
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 940091461X

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Polymers have achieved an enviable position as the class of materials having the highest volume of production, exceeding that of both metals and ceramics. The meteoric rise in the production and utilization of polymers has been due to advances in polymer synthesis which allow the creation of specific and well-defined molecular structures, to new knowledge concerning the relationships between polymer structure and properties, and to an improved understanding of how processing can be used as a tool to develop morphological features which result in desired properties. Polymers have truly become 'engineered materials' in every sense of the term. Polymer scientists and engineers are forever seeking to modify and improve the properties of synthetic polymeric systems for use in specific applications. Towards this end they have often looked to nature for advice on how to design molecules for specific needs. An excellent illustration of this is the use of noncovalent bonding (ionic, hydrogen, and van der Waals) in lipids, proteins, and nucleic acids, where these noncovalent bonds, acting both intra and intermolecularly, precisely control the structure and thus the function of the entire system. The utilization of ionic bonding, in particular in man-made polymers has attracted widespread interest in recent years, since ionic interactions exert a similar strong influence on the structure and properties of these synthetic systems.


New Methods for Polymer Synthesis

New Methods for Polymer Synthesis
Author: W.J. Mijs
Publisher: Springer Science & Business Media
Total Pages: 327
Release: 2013-06-29
Genre: Science
ISBN: 148992356X

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The art and science of macromolecular architecture is based on synthesis, analysis, processing, and evaluation of physical properties of polymers. The growing specificity of available synthetic methods and the increasing refinement of analytical and physical analysis are gradually providing a deeper insight into structure-property relationships of polymers, upon which many applications can be based. This book deals with recent methods for polymer synthesis. Those that lead to specific structures have been selected especially. Background, mechanism scope and limitations, and illustrative procedures are given for each method. With this layout the editor hopes that the book will provide a practical guideline, for the synthetic polymer chemist in industry or at a university graduate school, on how to apply the methods in the design of new polymer structures. The editor is grateful to the authors not only for their contributions containing interesting new developments in polymer synthesis, but also for the way they have fitted their text into the general framework of the book. The elegant chemistry described in the following chapters will, it is hoped, inspire more organic chemists to apply their skills to polymer synthesis, where the beauty of organic chemistry in terms of structural control and reactivity may be even more apparent than in the low molecular field.