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Radioactive Waste Forms for the Future

Radioactive Waste Forms for the Future
Author: Werner Lutze
Publisher: North Holland
Total Pages: 802
Release: 1988
Genre: Science
ISBN:

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This volume presents a compilation of important information on the full range of radioactive waste forms that have been developed, or at least suggested, for the incorporation of high-level nuclear waste. Many of the results were published in the ''gray literature'' of final reports of national laboratories or in various, generally less available, proceedings volumes. This is the first publication to draw information on nuclear waste forms for high-level wastes together into a single volume. Although borosilicate glass has become the standard waste form, additional research in this compound is still necessary. With improved technology (particularly processing technologies) and with a more detailed knowledge of repository conditions, glasses and second generation waste forms with improved performance properties can be developed. Sustained research programs on nuclear waste form development will yield results that can only add to public confidence and the final, safe disposal of nuclear waste. The aim of this volume is to provide a 'spring board' for these future research efforts. A detailed presentation is given on the properties and performance of non-crystalline waste forms (borosilicate glass, sintered glass, and lead-iron phosphate glass), and crystalline waste forms (Synroc, tailored ceramics, TiO 2 - ceramic matrix, glass-ceramics and FUETAP concrete). A chapter on Novel Waste Forms reviews a number of methods that warrant further development because of their potential superior performance and unique applications. The final chapter includes a tabulated comparison of important waste form properties and an extended discussion on the corrosion process and radiation damage effects for each waste form. Of particular interest is a performance assessment of nuclear waste borosilicate glass and the crystalline ceramic Synroc. This is the first detailed attempt to compare these two important waste forms on the basis of their materials properties. The discussion emphasizes the difficulties in making such a comparison and details the types of data that are required. Each chapter has been written by an expert and includes a current compilation of waste form properties with an extensive list of references. This volume will provide a stimulus for future research as well as useful reference material for scientists working in the field of nuclear waste disposal and materials science.


The Future of Nuclear Waste

The Future of Nuclear Waste
Author: Rosemary Joyce
Publisher: Oxford University Press, USA
Total Pages: 305
Release: 2020
Genre: Health & Fitness
ISBN: 019088813X

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"How can sites of waste disposal be marked to prevent contamination in the future? The United States government addressed this challenge in planning for nuclear waste repositories. Consulting with experts in imagining future scenarios, in language and communication, and in anthropology, the Department of Energy sought to develop plans that would satisfy demands from the Environmental Protection Agency for a marker system that would be effective long into the future. Expert consultants proposed two very different designs: one based on archaeological sites recognized as cultural heritage monuments; the other proposing that certain forms invoke universal feelings. The Department of Energy opted for a design based on archaeological ruins, cited as proof human-made markers could last and communicate warnings for thousands of years. This book explores the common sense assumptions the experts made about their archaeological models, and shows how they are contradicted by what archaeologists understand about these places and things. The book alternates between discussions of archaeological marker designs and reflections on the alternative proposal based on archetypes intended to arouse universal responses. Recognizing these archetype designs as similar in scale and form to Land Art projects, it compares the way government experts proposed their designs would work with views of modern artists and critics. Drawing on views of indigenous people who disproportionately are asked to accommodate such projects, the book explores concessions within the project that only oral transmission is likely to ensure such sites remain identifiable long into the future"--


Radioactive Waste Disposal and Geology

Radioactive Waste Disposal and Geology
Author: Konrad Krauskopf
Publisher: Springer Science & Business Media
Total Pages: 157
Release: 2013-03-07
Genre: Science
ISBN: 9400912013

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The perception of radioactive waste as a major problem for the industrial world has developed only recently. Four decades ago the disposal of such waste was regarded as a relatively minor matter. Those were the heady days when nuclear fission seemed the answer to the world's energy needs: the two wartime bombs had demonstrated its awesome power, and now it was to be harnessed for the production of electricity, the excavation of canals, even the running of cars and airplanes. In all applications of fission some waste containing radioactive elements would be generated of course, but it seemed only a trivial annoyance, a problem whose solution could be deferred until the more exciting challenges of constructing reactors and devising more efficient weapons had been mastered. So waste accumulated, some in tanks and some buried in shallow trenches. These were recognized as only temporary, makeshift measures, because it was known that the debris would be hazardous to its surroundings for many thousands of years and hence that more permanent disposal would someday be needed. The difficulty of accomplishing this more lasting disposal only gradually became apparent. The difficulty has been compounded by uncertainty about the physiological effects oflow-Ievel radiation, by the inadequacy of detailed knowledge about the behavior of engineered and geologic materials over long periods under unusual conditions, and by the sensitization of popular fears about radiation in all its forms following widely publicized reactor accidents and leaks from waste storage sites.


Disposal of All Forms of Radioactive Waste and Residues

Disposal of All Forms of Radioactive Waste and Residues
Author: Michael Lersow
Publisher: Springer Nature
Total Pages: 449
Release: 2019-11-16
Genre: Science
ISBN: 3030329100

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This book describes repository solutions for all types of radioactive waste and residues in different geotechnical repository structures. The focus is initially on existing or planned final disposal sites in Germany and the process of finding sites. However, international comparisons are drawn, especially to locations in the US. This affects both the repository structures and the legal requirements. The radioactive substances considered include residues from uranium ore processing, as well as low and intermediate level radioactive waste up to heat generating, high level radioactive wastes, such as spent fuel and vitrified waste from reprocessing. In order to evaluate the repository structures and their inventories, a dimensionless radiotoxicity index Ai / Fi [activity of radionuclide quantity (Ai) related to the exemption limit of radionuclide (Fi)] has been introduced. This gives the reader a well-founded overview of the degree of inconsistency in the handling of safety requirements for the respective geotechnical environmental structures. This creates the necessary transparency on this issue, which has not been previously available and is required by stakeholders today. The long-term security, the duration of the observation period and the certainty of the safety prognosis are also discussed in the book as well as the participation of subsequent generations in current and possible future repositories. This is vital as nuclear energy will continue to be used worldwide in the long term. The international repository projects presented have all been subjected to the same evaluation criteria. This applies both to existing operational project as well as those about to be commissioned and the processes for seeking locations. Special attention has been paid to monitoring, both operational and long-term monitoring. This broad range of topics makes this book a very valuable read for both the interested public and the professional world.


Ceramic and Glass Radioactive Waste Forms

Ceramic and Glass Radioactive Waste Forms
Author:
Publisher:
Total Pages:
Release: 1977
Genre:
ISBN:

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This report contains 14 individual presentations and 6 group reports on the subject of glass and polycrystalline ceramic radioactive waste forms. It was the general consensus that the information available on glass as a waste form provided a good basis for planning on the use of glass as an initial waste form, that crystalline ceramic forms could also be good waste forms if much more development work were completed, and that prediction of the chemical and physical stability of the waste form far into the future would be much improved if the basic synergistic effects of low temperature, radiation and long times were better understood. Continuing development of the polycrystalline ceramic forms was recommended. It was concluded that the leach rate of radioactive species from the waste form is an important criterion for evaluating its suitability, particularly for the time period before solidified waste is permanently placed in the geologic isolation of a Federal repository. Separate abstracts were prepared for 12 of the individual papers; the remaining two were previously abstracted.


Low-level Radioactive Waste

Low-level Radioactive Waste
Author: United States Government Accountability Office
Publisher: Createspace Independent Publishing Platform
Total Pages: 30
Release: 2017-10-20
Genre:
ISBN: 9781978450127

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Low-Level Radioactive Waste: Future Waste Volumes and Disposal Options Are Uncertain


Cementitious Materials for Nuclear Waste Immobilization

Cementitious Materials for Nuclear Waste Immobilization
Author: Rehab O. Abdel Rahman
Publisher: John Wiley & Sons
Total Pages: 245
Release: 2014-11-17
Genre: Science
ISBN: 1118512006

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Cementitious materials are an essential part in any radioactive waste disposal facility. Conditioning processes such as cementation are used to convert waste into a stable solid form that is insoluble and will prevent dispersion to the surrounding environment. It is incredibly important to understand the long-term behavior of these materials. This book summarises approaches and current practices in use of cementitious materials for nuclear waste immobilisation. It gives a unique description of the most important aspects of cements as nuclear waste forms: starting with a description of wastes, analyzing the cementitious systems used for immobilization and describing the technologies used, and ending with analysis of cementitious waste forms and their long term behavior in an envisaged disposal environment. Extensive research has been devoted to study the feasibility of using cement or cement based materials in immobilizing and solidifying different radioactive wastes. However, these research results are scattered. This work provides the reader with both the science and technology of the immobilization process, and the cementitious materials used to immobilize nuclear waste. It summarizes current knowledge in the field, and highlights important areas that need more investigation. The chapters include: Introduction, Portland cement, Alternative cements, Cement characterization and testing, Radioactive waste cementation, Waste cementation technology, Cementitious wasteform durability and performance assessment.


Geological Disposal of Radioactive Wastes and Natural Analogues

Geological Disposal of Radioactive Wastes and Natural Analogues
Author: W. Miller
Publisher: Elsevier
Total Pages: 329
Release: 2000-11-09
Genre: Technology & Engineering
ISBN: 0080532454

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Many countries are currently exploring the option to dispose of highly radioactive solid wastes deep underground in purpose built, engineered repositories. A number of surface and shallow repositories for less radioactive wastes are already in operation. One of the challenges facing the nuclear industry is to demonstrate confidently that a repository will contain wastes for so long that any releases that might take place in the future will pose no significant health or environmental risk. One method for building confidence in the long-term future safety of a repository is to look at the physical and chemical processes which operate in natural and archaeological systems, and to draw appropriate parallels with the repository. For example, to understand why some uranium orebodies have remained isolated underground for billions of years. Such studies are called 'natural analogues'. This book investigates the concept of geological disposal and examines the wide range of natural analogues which have been studied. Lessons learnt from studies of archaeological and natural systems can be used to improve our capabilities for assessing the future safety of a radioactive waste repository.


Waste Forms Technology and Performance

Waste Forms Technology and Performance
Author: National Research Council
Publisher: National Academies Press
Total Pages: 308
Release: 2011-09-05
Genre: Science
ISBN: 0309187338

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The Department of Energy's Office of Environmental Management (DOE-EM) is responsible for cleaning up radioactive waste and environmental contamination resulting from five decades of nuclear weapons production and testing. A major focus of this program involves the retrieval, processing, and immobilization of waste into stable, solid waste forms for disposal. Waste Forms Technology and Performance, a report requested by DOE-EM, examines requirements for waste form technology and performance in the cleanup program. The report provides information to DOE-EM to support improvements in methods for processing waste and selecting and fabricating waste forms. Waste Forms Technology and Performance places particular emphasis on processing technologies for high-level radioactive waste, DOE's most expensive and arguably most difficult cleanup challenge. The report's key messages are presented in ten findings and one recommendation.