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Photoelectrochemical Solar Fuel Production

Photoelectrochemical Solar Fuel Production
Author: Sixto Giménez
Publisher: Springer
Total Pages: 574
Release: 2016-04-29
Genre: Technology & Engineering
ISBN: 3319296418

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This book explores the conversion for solar energy into renewable liquid fuels through electrochemical reactions. The first section of the book is devoted to the theoretical fundamentals of solar fuels production, focusing on the surface properties of semiconductor materials in contact with aqueous solutions and the reaction mechanisms. The second section describes a collection of current, relevant characterization techniques, which provide essential information of the band structure of the semiconductors and carrier dynamics at the interface semiconductor. The third, and last section comprises the most recent developments in materials and engineered structures to optimize the performance of solar-to-fuel conversion devices.


Photoelectrochemical Solar Cells

Photoelectrochemical Solar Cells
Author: Nurdan Demirci Sankir
Publisher: John Wiley & Sons
Total Pages: 480
Release: 2018-12-10
Genre: Science
ISBN: 1119459974

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This book provides an overall view of the photoelectrochemical systems for solar hydrogen generation, and new and novel materials for photoelectrochemical solar cell applications. The book is organized in three parts. General concepts and photoelectrochemical systems are covered in Part I. Part II is devoted to photoactive materials for solar hydrogen generation. Main focus of the last part is the photoelectrochemical related systems. This part provides a diverse information about the implementation of multi-junctional solar cells in solar fuel generation systems, dye-sensitized solar hydrogen production and photocatalytic formation of photoactive semiconductors.


Photoelectrochemical Generation of Fuels

Photoelectrochemical Generation of Fuels
Author: Anirban Das
Publisher: CRC Press
Total Pages: 221
Release: 2022-10-31
Genre: Science
ISBN: 100075118X

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Photoelectrochemical processes due to the symbiosis of photochemical and electrochemical processes result in unique reaction pathways and products. This technique catalysed by nanomaterials is extensively used to harness sunlight for production of fuels and chemical feedstocks. This book explains the basic concepts of photoelectrochemistry as well as their application in the generation of solar fuels from water, CO2 and N2 as feedstocks. It also contains standard methodologies and benchmarks of fuel production including current state of the art in nanocatalysts as well as their mechanism of action. This book: Explores fundamentals and real-time applications of photoelectrochemistry in fuel generation Reviews basic theory and best-known catalysts and best conditions/processes for fuel generation in each of the chapters Covers standard methodologies, processes, and limitations for large-scale applications Focusses on sustainable production of fuels from renewable energy and resources This book aims at graduate students/researchers in chemical, energy and materials engineering.


Photoelectrochemical Hydrogen Production

Photoelectrochemical Hydrogen Production
Author: Roel van de Krol
Publisher: Springer Science & Business Media
Total Pages: 322
Release: 2011-11-09
Genre: Technology & Engineering
ISBN: 146141380X

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Photoelectrochemical Hydrogen Production describes the principles and materials challenges for the conversion of sunlight into hydrogen through water splitting at a semiconducting electrode. Readers will find an analysis of the solid state properties and materials requirements for semiconducting photo-electrodes, a detailed description of the semiconductor/electrolyte interface, in addition to the photo-electrochemical (PEC) cell. Experimental techniques to investigate both materials and PEC device performance are outlined, followed by an overview of the current state-of-the-art in PEC materials and devices, and combinatorial approaches towards the development of new materials. Finally, the economic and business perspectives of PEC devices are discussed, and promising future directions indicated. Photoelectrochemical Hydrogen Production is a one-stop resource for scientists, students and R&D practitioners starting in this field, providing both the theoretical background as well as useful practical information on photoelectrochemical measurement techniques. Experts in the field benefit from the chapters on current state-of-the-art materials/devices and future directions.


Solar Fuels

Solar Fuels
Author: Nurdan Demirci Sankir
Publisher: John Wiley & Sons
Total Pages: 436
Release: 2023-04-20
Genre: Science
ISBN: 1119752086

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SOLAR FUELS In this book, you will have the opportunity to have comprehensive knowledge about the use of energy from the sun, which is our source of life, by converting it into different chemical fuels as well as catching up with the latest technology. The most important obstacle to solar meeting all our energy needs is that solar energy is not always accessible and, therefore, cannot be used when needed. Consequently, the conversion of solar energy into chemical energy, which has become increasingly important in recent years, is a groundbreaking topic in the field of renewable energy. This type of chemical energy is called solar fuel. Hydrogen, methanol, methane, and carbon monoxide are among the solar fuels, which can be produced via solar-thermal, artificial photosynthesis, photocatalytic or photoelectrochemical routes. Solar Fuels compiles the objectives related to the new semiconductor materials and manufacturing techniques for solar fuel generation. Chapters are written by distinguished authors who have extensive experience in their fields. A multidisciplinary contributor profile, including chemical engineering, materials science, environmental engineering, and mechanical and aerospace engineering provides a broader point of view and coverage of the topic. Therefore, readers absolutely will have a chance to learn about not only the fundamentals, but also the various aspects of materials science and manufacturing technologies for solar fuel production. Moreover, readers from diverse fields should take advantage of this book to comprehend the impacts of solar energy conversion in chemical form. Audience The book will be of interest to a multidisciplinary group of fields in industry and academia, including physics, chemistry, materials science, biochemical engineering, optoelectronic information, photovoltaic and renewable energy engineering, electrochemistry, electrical engineering, and mechanical and manufacturing engineering.


Materials and Processes for Solar Fuel Production

Materials and Processes for Solar Fuel Production
Author: Balasubramanian Viswanathan
Publisher: Springer
Total Pages: 246
Release: 2014-10-09
Genre: Science
ISBN: 1493916289

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This book features different approaches to non-biochemical pathways for solar fuel production. This one-of-a-kind book addresses photovoltaics, photocatalytic water splitting for clean hydrogen production and CO2 conversion to hydrocarbon fuel through in-depth comprehensive contributions from a select blend of established and experienced authors from across the world. The commercial application of solar based systems, with particular emphasis on non-PV based devices have been discussed. This book intends to serve as a primary resource for a multidisciplinary audience including chemists, engineers and scientists providing a one-stop location for all aspects related to solar fuel production. The material is divided into three sections: Solar assisted water splitting to produce hydrogen; Solar assisted CO2 utilization to produce green fuels and Solar assisted electricity generation. The content strikes a balance between theory, material synthesis and application with the central theme being solar fuels.


Heterogeneous Photocatalysis

Heterogeneous Photocatalysis
Author: Jennifer Strunk
Publisher: John Wiley & Sons
Total Pages: 386
Release: 2021-08-23
Genre: Science
ISBN: 3527344640

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Discover the latest research in photocatalysis combined with foundational topics in basic physical and chemical photocatalytic processes In Heterogeneous Photocatalysis: From Fundamentals to Applications in Energy Conversion and Depollution, distinguished researcher and editor Jennifer Strunk delivers a rigorous discussion of the two main topics in her field—energy conversion and depollution reactions. The book covers topics like water splitting, CO2 reduction, NOx abatement and harmful organics degradation. In addition to the latest research on these topics, the reference provides readers with fundamental information about elementary physical and chemical processes in photocatalysis that are extremely practical in this interdisciplinary field. It offers an excellent overview of modern heterogeneous photocatalysis and combines concepts from different viewpoints to allow researchers with backgrounds as varied as electrochemistry, material science, and semiconductor physics to begin developing solutions with photocatalysis. In addition to subjects like metal-free photocatalysts and photocarrier loss pathways in metal oxide absorber materials for photocatalysis explored with time-resolved spectroscopy, readers will also benefit from the inclusion of: Thorough introductions to kinetic and thermodynamic considerations for photocatalyst design and the logic, concepts, and methods of the design of reliable studies on photocatalysis Detailed explorations of in-situ spectroscopy for mechanistic studies in semiconductor photocatalysis and the principles and limitations of photoelectrochemical fuel generation Discussions of photocatalysis, including the heterogeneous catalysis perspective and insights into photocatalysis from computational chemistry Treatments of selected aspects of photoreactor engineering and defects in photocatalysis Perfect for photochemists, physical and catalytic chemists, electrochemists, and materials scientists, Heterogeneous Photocatalysis will also earn a place in the libraries of surface physicists and environmental chemists seeking up-to-date information about energy conversion and depollution reactions.


Development of Bi-based Photoelectrodes for Solar Fuel and Chemical Production

Development of Bi-based Photoelectrodes for Solar Fuel and Chemical Production
Author: Adam Michael Hilbrands
Publisher:
Total Pages: 0
Release: 2023
Genre:
ISBN:

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The development of renewable and environmentally benign methods to replace fossil fuel extraction for chemical and fuel production is vital to reduce CO2 emissions and limit the effects of climate change. Solar energy is widely available as a renewable clean energy source. The use of photoelectrochemistry to harness solar energy for chemical and fuel production can decrease society's dependence on fossil fuels and reduce CO2 emissions. The key component of a photoelectrochemical cell is the semiconductor photoelectrode. Bi-based oxide materials have been shown to be effective photoelectrodes due to their small band gaps and excellent charge separation efficiencies. Current areas of research into photoelectrodes include new material discovery, optimization of already known materials, and investigation of new reactions to perform photoelectrochemically. The work herein presents research into all of these areas using Bi-based and other metal oxide materials. First, a combined experimental and computational investigation of the interface between BiVO4 and FeOOH was conducted to improve our understanding of charge transfer between a photoabsorber and catalyst layer. It was discovered that varying the surface of BiVO4 between stoichiometric and Bi-rich affects the deposition of the FeOOH layer, and therefore the energetics at the interface, leading to significantly improved performance for the Bi-rich film. Alcohol oxidation on a BiVO4 photoanode was also investigated using the renewable feedstock chemical glycerol as a method for renewable chemical production. It was discovered that BiVO4 has a unique ability to promote a C-C coupling reaction that generates glycolaldehyde as the primary product, which has never been reported. SrBiO3 was also discovered as a photoelectrode material and synthesized as a thin film under ambient pressure for the first time. Investigation of its material properties and photoelectrochemical performance found SrBiO3 to be a promising photocathode material. Finally, a new electrochemical synthesis method was developed for the materials Fe2O3, CuO, CuFe2O4, and CuFeO2 utilizing the oxidation of catechol-metal complexes to deposit the desired metals. This method allowed for controlled ratios of Cu and Fe to be deposited and resulted in high surface area films that are favorable for use as photoelectrodes.


Photoelectrochemical Engineering for Solar Harvesting

Photoelectrochemical Engineering for Solar Harvesting
Author: Samrana Kazim
Publisher: Elsevier
Total Pages: 504
Release: 2024-06-24
Genre: Technology & Engineering
ISBN: 0323954952

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Photoelectrochemical Engineering for Solar Harvesting provides an up-to-date appraisal of the photon engineering of innovative catalysts for solar energy harvesting.Sunlight-driven fuel synthesis is the most sustainable and potentially economical option for producing energy vectors through water splitting. Thus this book focuses on the design of photocatalysts and water oxidation catalysts, as artificial photosynthesis and hydrogen fuel production via water oxidation (in place of fossil fuels) are two promising approaches towards renewable energy.The book critically analyzes the overall progress, potential challenges, and the possibility of industrialization of new catalysts in the near future. The primary emphasis of the discussion is on experimental approaches from materials synthesis to device applications, however, there will also be some introduction to relevant photochemistry concepts.Photoelectrochemical Engineering for Solar Harvesting is suitable for materials scientists and chemists who through the use of photonics are in continuous pursuit of improving the efficiencies of different devices used to capture solar energy for the generation of sustainable fuel. Covers design of innovative energy materials such as photocatalysts and water oxidation catalysts for solar energy harvesting Reviews briefly computational and theoretical approaches before providing comprehensive overview of experimental directions Provides information to guide photon and photoelectrochemical engineering of catalysts for solar application


Solar-to-Chemical Conversion

Solar-to-Chemical Conversion
Author: Hongqi Sun
Publisher: John Wiley & Sons
Total Pages: 480
Release: 2021-03-11
Genre: Science
ISBN: 3527825096

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This comprehensive book systematically covers the fundamentals in solar energy conversion to chemicals, either fuels or chemical products. It includes natural photosynthesis with emphasis on artificial processes for solar energy conversion and utilization. The chemical processes of solar energy conversion via homogeneous and/or heterogeneous photocatalysis has been described with the mechanistic insights. It also consists of reaction systems toward a variety of applications, such as water splitting for hydrogen or oxygen evolution, photocatalytic CO2 reduction to fuels, and light driven N2 fixation, etc. This unique book offers the readers a broad view of solar energy utilization based on chemical processes and their perspectives for future sustainability.