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Organometallic Chemistry: Volume 44

Organometallic Chemistry: Volume 44
Author: Nathan J Patmore
Publisher: Royal Society of Chemistry
Total Pages: 131
Release: 2022-12-14
Genre: Science
ISBN: 1839166894

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Providing an invaluable resource, this volume contains analysed, evaluated and distilled information on the latest in organometallic and coordination chemistry research and emerging fields. With continued increases in the variety of information available, researchers can find it difficult to keep up to date with the literature in their field. The reviews in this volume range in scope and include recent developments in homogeneous catalysis for the functionalization of carbon dioxide, early transition metal complexes and their uses in medicinal chemistry, homogeneous gold catalysis under microwave irradiation: a greener approach and properties of metal complexes of mesoionic carbenes. This volume is a key reference for researchers in academic and industrial settings.


Organometallics in Process Chemistry

Organometallics in Process Chemistry
Author: Ahmed F. Abdel-Magid
Publisher: Springer Science & Business Media
Total Pages: 316
Release: 2004-06-15
Genre: Science
ISBN: 9783540016038

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The design of efficient syntheses of medicinal agents is one of the prime goals of the process chemist in the pharmaceutical industry. The expanding list of metal-mediated reactions has had a major impact on this endeavor over the last two decades. This volume will highlight some of the areas of organometallic chemistry that have played a particularly important role in development. The chapters are written by chemists who work in the process groups of major pharmaceutical companies and fine chemical manufacturers. Having demonstrated the power of organometallics in their processes the authors herein expand upon their experiences with examples from the literature as reported by process groups within the industry. The chapters are organized either by the application of a particular metal or reaction class. Removal of the residual metal(s) from the isolated active pharmaceutical ingredient (API) is key to the release of the material for human consumption, and hence, is reviewed here as well. This volume of Topics in Organometallic Chemistry is presented to offer a representative cross section of organometallic applications in the pharmaceutical industry as well as to give an appreciation for the creativity possible in process chemistry.


Inventing Reactions

Inventing Reactions
Author: Lukas J. Gooßen
Publisher: Springer
Total Pages: 345
Release: 2012-10-30
Genre: Science
ISBN: 3642342868

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Barry Trost: Transition metal catalyzed allylic alkylation.- Jeffrey W. Bode: Reinventing Amide Bond Formation.- Naoto Chatani and Mamoru Tobisu: Catalytic Transformations Involving the Cleavage of C-OMe Bonds.- Gregory L. Beutner and Scott E. Denmark: The Interplay of Invention, Observation and Discovery in the Development of Lewis Base Activation of Lewis Acids for Catalytic Enantioselective Synthesis.- David R. Stuart and Keith Fagnou: The Discovery and Development of a Palladium(II)-Catalyzed Oxidative Cross-Coupling of Two Unactivated Arenes.- Lukas Gooßen and Käthe Gooßen: Decarboxylative Cross-Coupling Reactions.- A. Stephen K. Hashmi: Gold-Catalyzed Organic Reactions.- Ben List: Developing Catalytic Asymmetric Acetalizations.- Steven M. Bischof, Brian G. Hashiguchi, Michael M. Konnick, and Roy A. Periana: The De NovoDesign of CH Bond Hydroxylation Catalysts.- Benoit Cardinal-David, Karl A. Scheidt: Carbene Catalysis: Beyond the Benzoin and Stetter Reactions.- Kenso Soai and Tsuneomi Kawasaki: Asymmetric autocatalysis of pyrimidyl alkanol.- Douglas C. Behenna and Brian M. Stoltz: Natural Products as Inspiration for Reaction Development: Catalytic Enantioselective Decarboxylative Reactions of Prochiral Enolate Equivalents. Hisashi Yamamoto: Acid Catalysis in Organic Synthesis.


Comprehensive Organometallic Chemistry II

Comprehensive Organometallic Chemistry II
Author: Richard J. Puddephatt
Publisher: Elsevier
Total Pages: 670
Release: 1995
Genre: Organometallic chemistry
ISBN: 9780080423166

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Carbosilanes

Carbosilanes
Author: Gerhard Fritz
Publisher: Springer Science & Business Media
Total Pages: 269
Release: 2012-12-06
Genre: Science
ISBN: 3642708005

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Carbosilanes are compounds in which the elements silicon and carbon alternate in the molecular skeleton [1]. Just as the alkanes are formally derived from the diamond lattice and the aromatics from the graphite lattice, the carbosilanes are structurally derived from silicon carbide. Because of the tetravalent nature of silicon and carbon we can expect stable linear, cyclic and polycyclic compounds to occur. However, carbosilanes do not exist in nature. This book is an attempt to give a summarized presentation. Carbosilanes are, of course, part" of organosilicon chemistry, but their behavior differentiates them distinctly from other organosilicon compounds. The differences result primarily from the alternating Si-C-Si arrangements in the molecular skeleton, and especially the various methylene bridges (CH , CHX, CX ; X = halogen) cause changes in z z Si-C bond polarization and hence influence the reaction possibilities. It is convenient to regard carbosilanes as similar to silicones except that the oxygen bridges of silicones are replaced by methylene units. However, this does not accurately account for all the chemical properties of these compounds. Carbosilanes are related more directly to silicon carbide, as shown occasionally by the reactive behavior of polycyclic car bosilanes. Therefore, in view of the present interest shown for thermally stable cera mics of unusual character, interesting possibilities arise for further development. Most cyclic carbosilanes can be classified in two groups: the carborundanes and the Si-scaphanes. Compounds belonging to the carborundane class maintain Si-C six-membered rings in the boat conformation.


Organometallic Chemistry

Organometallic Chemistry
Author: E W Abel
Publisher: Royal Society of Chemistry
Total Pages: 476
Release: 2007-10-31
Genre: Science
ISBN: 1847554148

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Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.


Advances in Organometallic Chemistry and Catalysis

Advances in Organometallic Chemistry and Catalysis
Author: Armando J. L. Pombeiro
Publisher: John Wiley & Sons
Total Pages: 848
Release: 2013-10-11
Genre: Science
ISBN: 1118742893

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A contemporary compilation of recent achievements in organometallic chemistry The prestigious International Conference on Organometallic Chemistry (ICOMC) was launched in 1963, providing a forum for researchers from around the world to share their findings and explore new paths to advance our knowledge and application of organometallic chemistry. The 25th ICOMC, held in Lisbon in 2012, gathered more than 1,200 participants from 54 countries. This volume celebrates the 25th Silver Edition and the 50th Gold Year of the ICOMC. Featuring contributions from invited 25th ICOMC speakers, Advances in Organometallic Chemistry and Catalysis highlights recent achievements and new and emerging areas of research in the field. Its seven sections cover: Activation and Functionalization of Carbon Single Bonds and Small Molecules Organometallic Synthesis and Catalysis Organometallic Polymerization Catalysis Organometallic Polymers and Materials Organometallic Chemistry and Sustainable Energy Bioorganometallic Chemistry Organometallic Electrochemistry Chapters discuss fundamental underlying concepts, offer illustrative examples and cases, and explore future avenues for continued research. Readers will discover basic principles and properties of organometallic compounds, reaction mechanisms, and detailed descriptions of current applications. Collectively, these chapters underscore the versatility, richness, and potential of modern organometallic chemistry, including its interrelationships with other scientific disciplines. All the contributions are extensively referenced, providing a gateway to the most important original research papers and reviews in organometallic chemistry. Presenting a contemporary understanding of organometallic chemistry and its many applications, Advances in Organometallic Chemistry and Catalysis is recommended for all researchers in the field, from students to advanced investigators.


Compounds with F, Cl, Br, I

Compounds with F, Cl, Br, I
Author: P. Nigel
Publisher: Springer
Total Pages: 175
Release: 1993-08-10
Genre: Science
ISBN: 9783540936664

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Organometallic Chemistry

Organometallic Chemistry
Author: Timothy L. Easun
Publisher: Royal Society of Chemistry
Total Pages: 210
Release: 2018-11-28
Genre: Organometallic chemistry
ISBN: 1788010051

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With the increase in volume, velocity and variety of information, researchers can find it difficult to keep up to date with the literature in their field. Providing an invaluable resource, this volume contains analysed, evaluated and distilled information on the latest in organometallic chemistry research and emerging fields. The reviews range in scope and include π-coordinated arene metal complexes and catalysis by arene exchange, rylenes as chromophores in catalysts for CO2 photoreduction, metal nodes and metal sites in metal–organic frameworks, developments in molecular precursors for CVD and ALD, and multiphoton luminescence processes in f-element containing compounds.