Non Equilibrium Thermodynamics Of Heterogeneous Systems PDF Download
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Author | : Signe Kjelstrup |
Publisher | : World Scientific |
Total Pages | : 451 |
Release | : 2008 |
Genre | : Technology & Engineering |
ISBN | : 9812779132 |
Download Non-equilibrium Thermodynamics of Heterogeneous Systems Book in PDF, ePub and Kindle
The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.
Author | : Signe Kjelstrup |
Publisher | : World Scientific |
Total Pages | : 492 |
Release | : 2020-08-27 |
Genre | : Science |
ISBN | : 9811216789 |
Download Non-equilibrium Thermodynamics Of Heterogeneous Systems (Second Edition) Book in PDF, ePub and Kindle
This book utilizes non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. There are large coupling effects between transport of heat, mass, charge and chemical reactions at surfaces, and it is important to know how one should properly integrate across systems where different phases are in contact. There is no other book available today that gives a prescription of how to set up flux equations for transports across heterogeneous systems.
Author | : Yasar Demirel |
Publisher | : Elsevier |
Total Pages | : 880 |
Release | : 2018-11-24 |
Genre | : Science |
ISBN | : 0444641130 |
Download Nonequilibrium Thermodynamics Book in PDF, ePub and Kindle
Nonequilibrium Thermodynamics: Transport and Rate Processes in Physical, Chemical and Biological Systems, Fourth Edition emphasizes the unifying role of thermodynamics in analyzing natural phenomena. This updated edition expands on the third edition by focusing on the general balance equations for coupled processes of physical, chemical and biological systems. Updates include stochastic approaches, self-organization criticality, ecosystems, mesoscopic thermodynamics, constructual law, quantum thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems. The book also emphasizes nonequilibrium thermodynamics tools, such as fluctuation theories, mesoscopic thermodynamic analysis, information theories, and quantum thermodynamics in describing and designing small scale systems. Provides a useful text for seniors and graduate students from diverse engineering and science programs Highlights the fundamentals of equilibrium thermodynamics, transport processes and chemical reactions Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical and biological systems Presents a unified analysis for transport and rate processes in various time and space scales Discusses stochastic approaches in thermodynamic analysis, including fluctuation and information theories, mesoscopic nonequilibrium thermodynamics, constructal law and quantum thermodynamics
Author | : Dick Bedeaux |
Publisher | : Royal Society of Chemistry |
Total Pages | : 432 |
Release | : 2016 |
Genre | : Science |
ISBN | : 1782620249 |
Download Experimental Thermodynamics Volume X Book in PDF, ePub and Kindle
Covering recent developments in the theory of non-equilibrium thermodynamics and its applications, this title is aimed at a predominantly, but not exclusively, academic audience of practitioners of thermodynamics and energy conversion.
Author | : S. R. De Groot |
Publisher | : Courier Corporation |
Total Pages | : 532 |
Release | : 2013-01-23 |
Genre | : Science |
ISBN | : 0486153509 |
Download Non-Equilibrium Thermodynamics Book in PDF, ePub and Kindle
Classic monograph treats irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications with chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, more.
Author | : Georgy Lebon |
Publisher | : Springer Science & Business Media |
Total Pages | : 331 |
Release | : 2008-01-12 |
Genre | : Science |
ISBN | : 3540742522 |
Download Understanding Non-equilibrium Thermodynamics Book in PDF, ePub and Kindle
Discover the many facets of non-equilibrium thermodynamics. The first part of this book describes the current thermodynamic formalism recognized as the classical theory. The second part focuses on different approaches. Throughout the presentation, the emphasis is on problem-solving applications. To help build your understanding, some problems have been analyzed using several formalisms to underscore their differences and their similarities.
Author | : Wolfgang Muschik |
Publisher | : World Scientific |
Total Pages | : 124 |
Release | : 1990 |
Genre | : Science |
ISBN | : 9789810200879 |
Download Aspects of Non-equilibrium Thermodynamics Book in PDF, ePub and Kindle
In six lectures aspects of modern non-equilibrium thermodynamics of discrete systems as well as continuum theoretical concepts are represented. Starting out with survey and introduction, state spaces are defined, the existence of internal energy is investigated, and Clausius inequality including negative absolute temperature is derived by diagram technique. Non-equilibrium contact quantities, such as contact temperature ? the dynamic analogue of thermostatic temperature ? and chemical potentials are phenomenologically defined and quantumstatistically founded. Using Clausius inequality the existence of non-negative entropy production is proved which allows to formulate a dissipation inequality in continuum thermodynamics. The transition between thermodynamics of discrete systems and continuum thermodynamics with respect to contact quantities is considered. Different possibilities of exploiting the dissipation inequality for getting constraints for constitutive equations are discussed. Finally hyperbolic heat conduction in non-extended thermodynamics is treated.
Author | : Roderick C. Dewar |
Publisher | : Springer |
Total Pages | : 434 |
Release | : 2013-12-02 |
Genre | : Technology & Engineering |
ISBN | : 3642401546 |
Download Beyond the Second Law Book in PDF, ePub and Kindle
The Second Law, a cornerstone of thermodynamics, governs the average direction of dissipative, non-equilibrium processes. But it says nothing about their actual rates or the probability of fluctuations about the average. This interdisciplinary book, written and peer-reviewed by international experts, presents recent advances in the search for new non-equilibrium principles beyond the Second Law, and their applications to a wide range of systems across physics, chemistry and biology. Beyond The Second Law brings together traditionally isolated areas of non-equilibrium research and highlights potentially fruitful connections between them, with entropy production playing the unifying role. Key theoretical concepts include the Maximum Entropy Production principle, the Fluctuation Theorem, and the Maximum Entropy method of statistical inference. Applications of these principles are illustrated in such diverse fields as climatology, cosmology, crystal growth morphology, Earth system science, environmental physics, evolutionary biology and technology, fluid turbulence, microbial biogeochemistry, plasma physics, and radiative transport, using a wide variety of analytical and experimental techniques. Beyond The Second Law will appeal to students and researchers wishing to gain an understanding of entropy production and its central place in the science of non-equilibrium systems – both in detail and in terms of the bigger picture.
Author | : Ralph John Tykodi |
Publisher | : |
Total Pages | : 488 |
Release | : 2002 |
Genre | : Entropy |
ISBN | : |
Download Thermodynamics of Systems in Nonequilibrium States Book in PDF, ePub and Kindle
Author | : Andrei G. Bashkirov |
Publisher | : CRC Press |
Total Pages | : 180 |
Release | : 2020-10-07 |
Genre | : Science |
ISBN | : 1000141152 |
Download Nonequilibrium Statistical Mechanics of Heterogeneous Fluid Systems Book in PDF, ePub and Kindle
There is a wide variety of heterogeneous fluid systems that possess interphase surfaces. This monograph is devoted to pioneering studies in nonequilibrium statistical mechanics of such systems. Starting from the Liouville equation, the equations of surface hydrodynamics are derived with allowance for discontinuities of thermodynamic parameters of interphase boundaries. Brownian motion of a large solid particle in a fluid and nucleation are treated as results of fluctuations of flows across particle surfaces. With the use of the Gibbs method, a shock wave in a gas is considered as a sort of an interphase surface, and the surface tension of a shock front is introduced for the first time.