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Synthesis and Applications of New Spin Crossover Compounds

Synthesis and Applications of New Spin Crossover Compounds
Author: Takafumi Kitazawa
Publisher: MDPI
Total Pages: 254
Release: 2019-10-11
Genre: Science
ISBN: 303921361X

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The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials—promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscles. This Special Issue is devoted to various aspects of SCO and related research, comprising 18 interesting original papers on valuable and important SCO topics. Significant and fundamental scientific attention has been focused on the SCO phenomena in a wide research range of fields of fundamental chemical and physical and related sciences, containing the interdisciplinary regions of chemical and physical sciences related to the SCO phenomena. Coordination materials with bistable systems between the LS and the HS states are usually triggered by external stimuli, such as temperature, light, pressure, guest molecule inclusion, soft X-ray, and nuclear decay. Since the first Hofmann-like spin crossover (SCO) behavior in {Fe(py)2[Ni(CN)4]}n (py = pyridine) was demonstrated, this crystal chemistry motif has been frequently used to design Fe(II) SCO materials to enable determination of the correlations between structural features and magnetic properties.


Sustainable Materials for Sensing and Remediation of Noxious Pollutants

Sustainable Materials for Sensing and Remediation of Noxious Pollutants
Author: Inderjeet Tyagi
Publisher: Elsevier
Total Pages: 374
Release: 2022-08-05
Genre: Business & Economics
ISBN: 0323994261

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Due to rapid urbanization and development, water get polluted by the noxious waste released from industrial, sewage and agricultural runoffs. Sustainable Materials for Sensing and Remediation of Noxious Pollutants covers two most widely used aspects in the field of wastewater i.e. sensing and rapid remediation with a possible solution of successful technology commercialization. Chapters include information on low cost materials as sensing and remediating agents for the rapid removal of noxious impurities from wastewater. It includes chapters on the sensing of noxious metals, low cost adsorbents for the removal of noxious impurities i.e. inorganic (metal ions) and organic (dyes). Additional chapters include future/upcoming scopes of work and one chapter on the general introduction of the field. The book content will be technical and focused for the audience like graduate students, academicians, researchers and industrial professionals. Sustainable Materials for Sensing and Remediation of Noxious Pollutants is single reference source for environmental scientists and engineers interested in low cost sensing and remediation strategies. Assists readers in developing new strategies to address the issues related to sensing and remediation activities Includes low cost materials for sensor and adsorbent development allowing professionals to make decisions based on economic considerations Provides alternatives for the development of socioeconomically sustainable products for sensing and remediation application


Metal-Organic Framework Nanocomposites

Metal-Organic Framework Nanocomposites
Author: Anish Khan
Publisher: CRC Press
Total Pages: 339
Release: 2020-11-24
Genre: Technology & Engineering
ISBN: 1000244865

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Metal-Organic Framework Nanocomposites: From Design to Application assembles the latest advances in MOF nanocomposites, emphasizing their design, characterization, manufacturing, and application and offering a wide-ranging view of these materials with exceptional physical and chemical properties. FEATURES Discusses various types of MOF materials, such as polyaniline MOF nanocomposites, magnetic MOF nanocomposites, and carbon nanotube-based MOF nanocomposites Includes chapters on the usage of these materials in pollutant removal, electrochemical devices, photocatalysts, biomedical applications, and other applications Covers different aspects of composite fabrication from energy storage and catalysts, including preparation, design, and characterization techniques Emphasizes the latest technology in the field of manufacturing and design Aimed at researchers, academics, and advanced students in materials science and engineering, this book offers a comprehensive overview and analysis of these extraordinary materials.


Soft Mechanochemical Synthesis

Soft Mechanochemical Synthesis
Author: G.V. Avvakumov
Publisher: Springer Science & Business Media
Total Pages: 211
Release: 2007-05-08
Genre: Science
ISBN: 0306476460

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Mechanical methods of the activation of chemical processes are currently widely used for the synthesis of various compounds. The present monograph deals with the development of a novel approach to mechanochemical synthesis based on reactions of solid acids, bases, hydrated compounds, crystal hydrates, basic and acidic salts. This method has been called soft mechanochemical synthesis. The monograph includes the papers published by the present authors. They describe the results of their investigations n the last two decades. New theoretical and experimental data on kinetics and mechanism of soft mechanochemical reactions in the mixtures of compounds mentioned above to give complex oxide compounds are presented. The description of new high energetic and high efficient mills providing effective occurrence of these reactions is delivered. The possibilities of applying soft mechanochemical synthesis for materials used in catalysts, material science, electronics, etc., are discussed. The advantages of the method proposed in comparison with other methods are demonstrated. The monograph is designed for researchers, engineers and technicians engaged in chemical and ceramic industry, for scientists and students specialized in the area of development, and application of new materials.


Metal-Organic Frameworks

Metal-Organic Frameworks
Author: Leonard R. MacGillivray
Publisher: John Wiley & Sons
Total Pages: 440
Release: 2010-12-17
Genre: Science
ISBN: 111803516X

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Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.


Supported Catalysts and Their Applications

Supported Catalysts and Their Applications
Author: David C Sherrington
Publisher: Royal Society of Chemistry
Total Pages: 282
Release: 2007-10-31
Genre: Science
ISBN: 1847551963

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The need to improve both the efficiency and environmental acceptability of industrial processes is driving the development of heterogeneous catalysts across the chemical industry, including commodity, specialty and fine chemicals and in pharmaceuticals and agrochemicals. Drawing on international research, Supported Catalysts and their Applications discusses aspects of the design, synthesis and application of solid supported reagents and catalysts, including supported reagents for multi-step organic synthesis; selectivity in oxidation catalysis; mesoporous molecular sieve catalysts; and the use of Zeolite Beta in organic reactions. In addition, the two discrete areas of heterogeneous catalysis (inorganic oxide materials and polymer-based catalysts) that were developing in parallel are now shown to be converging, which will be of great benefit to the whole field. Providing a snapshot of the state-of-the-art in this fast-moving field, this book will be welcomed by industrialists and researchers, particularly in the agrochemicals and pharmaceuticals industries.


Spin Crossover in Transition Metal Compounds I

Spin Crossover in Transition Metal Compounds I
Author: Philipp Gütlich
Publisher: Springer Science & Business Media
Total Pages: 640
Release: 2004-05-12
Genre: Science
ISBN: 9783540403944

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With contributions by numerous experts


Core Concepts in Supramolecular Chemistry and Nanochemistry

Core Concepts in Supramolecular Chemistry and Nanochemistry
Author: Jonathan W. Steed
Publisher: John Wiley & Sons
Total Pages: 320
Release: 2007-04-30
Genre: Science
ISBN: 9780470858707

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Supramolecular chemistry and nanochemistry are two strongly interrelated cutting edge frontiers in research in the chemical sciences. The results of recent work in the area are now an increasing part of modern degree courses and hugely important to researchers. Core Concepts in Supramolecular Chemistry and Nanochemistry clearly outlines the fundamentals that underlie supramolecular chemistry and nanochemistry and takes an umbrella view of the whole area. This concise textbook traces the fascinating modern practice of the chemistry of the non-covalent bond from its fundamental origins through to it expression in the emergence of nanochemistry. Fusing synthetic materials and supramolecular chemistry with crystal engineering and the emerging principles of nanotechnology, the book is an ideal introduction to current chemical thought for researchers and a superb resource for students entering these exciting areas for the first time. The book builds from first principles rather than adopting a review style and includes key references to guide the reader through influential work. supplementary website featuring powerpoint slides of the figures in the book further references in each chapter builds from first principles rather than adopting a review style includes chapter on nanochemistry clear diagrams to highlight basic principles