Heteropolyacids As Highly Efficient And Green Catalysts Applied In Organic Transformations PDF Download

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Heteropolyacids as Highly Efficient and Green Catalysts Applied in Organic Transformations

Heteropolyacids as Highly Efficient and Green Catalysts Applied in Organic Transformations
Author: Majid M. Heravi
Publisher: Elsevier
Total Pages: 390
Release: 2022-01-19
Genre: Science
ISBN: 0323906583

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Heteropolyacids as Highly Efficient and Green Catalysts Applied in Organic Transformations introduces heteropolyacids (HPAs) as promising candidates for use as green catalysts. This book initially presents an overview of chemistry of HPAs, including the history of their discovery and applications, systematic classifications, solubility, coordination and binding chemistry, isomerization, stability, redox activity, acidic properties, basicity, skeleton structure, structure types, self-assemblage, surface area, electrochemical behavior, methods of investigation, and characterization. Other sections present and compare the applications of HPAs as homogeneous and heterogeneous catalysts. The book provides readers with a basic-to-advanced range of knowledge on how useful and green HPAs can be used for use as catalysts in organic transformations and even the synthesis of complex organic molecules. Focuses on applications of HPAs as catalysts, but also includes basic information on HPAs to make it useful to those researchers and scientists whose activities are focused on biochemical analysis, electrochemistry, electrochemical devices, protection of corrosion, medicine and photo-catalyzed reactions Includes a subdivision devoted to HPA-catalyzed multicomponent reactions for the synthesis of some biologically active compounds via a double-green strategy Illustrates reactions with approximately 100 chemical reaction schemes to aid understanding


Polyoxomolybdates as Green Catalysts for Aerobic Oxidation

Polyoxomolybdates as Green Catalysts for Aerobic Oxidation
Author: Anjali Patel
Publisher: Springer
Total Pages: 63
Release: 2014-11-22
Genre: Science
ISBN: 3319129880

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Heterogeneously catalyzed selective oxidations of alcohols is a highly topical field. The first chapter of this brief describes the importance of the selective oxidation of alcohols and advantages of heterogeneous catalysts over conventional catalysts, use of environmentally benign oxidants, and the design of selective catalysts by tailoring of polyoxometalates at the molecular level. Chapter 2 describes synthesis, characterization 11-molybdophosphate based supported materials and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. ZrO2, Al2O3, MCM-41 and zeolite Hβ were used as supports. Chapter 3 describes synthesis, characterization of transition metals (Mn, Co, Ni, Cu)- substituted phosphomolybdates and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. Chapter 4 describes conclusive remarks for present catalytic systems.


Sulfonic Acid Functionalized Reusable Catalysts in Organic Synthesis

Sulfonic Acid Functionalized Reusable Catalysts in Organic Synthesis
Author: Rajesh H. Vekariya
Publisher: LAP Lambert Academic Publishing
Total Pages: 72
Release: 2015-06-10
Genre:
ISBN: 9783659741296

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Silica gel as an accessible substrate with high surface area can be modified by propyl S-sulfonic acid. Silica-bonded S-sulfonic acid (SBSSA), silica-bonded N-propyl sulfamic acid (SBNPSA) and silica-bonded N-propylpiperazine sulfamic acid (SBPPSA) as highly efficient heterogeneous solid acid catalysts for the green synthesis of various organic compounds including highly important biological active heterocycles have been developed by many scientists recently. The superior advantage of these heterogeneous catalysts is that they can be recovered and reused several times without the loss of their efficiency. This book will help the reader to understand the preparation and utilization of SBSSA, SBNPSA and SBPPSA as solid heterogeneous catalysts for organic transformations in both theoretical and practical aspects.


Clay Mineral Catalysis of Organic Reactions

Clay Mineral Catalysis of Organic Reactions
Author: Benny K.G Theng
Publisher: CRC Press
Total Pages: 426
Release: 2018-07-27
Genre: Science
ISBN: 0429879679

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The book provides insight into the working of clays and clay minerals in speeding up a variety of organic reactions. Clay minerals are known to have a large propensity for taking up organic molecules and can catalyse numerous organic reactions due to fine particle size, extensive surface area, layer structure, and peculiar charge characteristics. They can be used as heterogeneous catalysts and catalyst carriers of organic reactions because they are non-corrosive, easy to separate from the reaction mixture, and reusable. Clays and clay minerals have an advantage over other solid acids as they are abundant, inexpensive, and non-polluting.


Frontiers of Green Catalytic Selective Oxidations

Frontiers of Green Catalytic Selective Oxidations
Author: Konstantin P. Bryliakov
Publisher: Springer Nature
Total Pages: 295
Release: 2019-10-02
Genre: Science
ISBN: 9813297514

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The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C–H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.


Chemistry for Green Environment

Chemistry for Green Environment
Author: M. M. Srivastava
Publisher: Alpha Science Int'l Ltd.
Total Pages: 384
Release: 2005
Genre: Nature
ISBN: 9788173196201

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Providing an overview of the current status of chemistry; regarding the implementation of clean, eco-friendly, less improvident manufacturing processes. This book acknowledges a more eco-conscious face of multi-dimensional chemistry: the need, principle, evolution, strategies and bioethical concerns for sustainable development of environment.


Green Chemistry and Catalysis

Green Chemistry and Catalysis
Author: R. A. Sheldon
Publisher: John Wiley & Sons
Total Pages: 448
Release: 2007-06-27
Genre: Science
ISBN: 3527611010

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This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect: · Numerous catalytic reductions and oxidations methods · Solid-acid and solid-base catalysis · C-C bond formation reactions · Biocatalysis · Asymmetric catalysis · Novel reaction media like e.g. ionic liquids, supercritical CO2 · Renewable raw materials Written by Roger A. Sheldon -- without doubt one of the leaders in the field with much experience in academia and industry -- and his co-workers, the result is a unified whole, an indispensable source for every scientist looking to improve catalytic reactions, whether in the college or company lab.


Sustainable Organic Synthesis

Sustainable Organic Synthesis
Author: Dr Stefano Protti
Publisher: Royal Society of Chemistry
Total Pages: 602
Release: 2021-10-29
Genre: Science
ISBN: 1839162031

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Recent years have seen huge growth in the area of sustainable chemistry. In order to meet the chemical needs of the global population whilst minimising impacts on health and the environment it is essential to keep reconsidering and improving synthetic processes. Sustainable Organic Synthesis is a comprehensive collection of contributions, provided by specialists in Green Chemistry, covering topics ranging from catalytic approaches to benign and alternative reaction media, and innovative and more efficient technologies.


Glycerine Production and Transformation

Glycerine Production and Transformation
Author: Marco Frediani
Publisher: BoD – Books on Demand
Total Pages: 138
Release: 2019-09-11
Genre: Technology & Engineering
ISBN: 1789846900

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The increase in the amount of glycerin in the market is a burden for all producers, especially those operating in the biodiesel sector: reuse options are in fact limited for the management of this by-product. Glycerol enhancement has therefore become a priority to improve the sustainability of the biodiesel industry. Nevertheless, the multifunctionality of glycerol makes it a promising precursor for different types of production (fuel/biofuel, chemical products). This conversion has therefore become a subject of multifaceted research that requires an exchange of knowledge across many sectors. In this book, different disciplines (chemistry, biology, engineering, etc.) have been taken into consideration to propose an interdisciplinary point of view on different aspects.