Controlled Radical Polymerization In The Dispersed Phase PDF Download
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Author | : Mary E. Thomson |
Publisher | : |
Total Pages | : |
Release | : 2013 |
Genre | : |
ISBN | : 9780494784693 |
Download Controlled Radical Polymerization in the Dispersed Phase Book in PDF, ePub and Kindle
Author | : |
Publisher | : Steinkopff |
Total Pages | : 246 |
Release | : 2014-03-12 |
Genre | : Science |
ISBN | : 9783662151310 |
Download Dispersed Systems Book in PDF, ePub and Kindle
Author | : Thomas Edward Enright |
Publisher | : |
Total Pages | : 370 |
Release | : 2010 |
Genre | : |
ISBN | : |
Download Living/controlled Radical Polymerization in a Continuous Tubular Reactor Book in PDF, ePub and Kindle
Significant advances have been made in the understanding of living/controlled radical polymerization processes since their discovery in the early 1990's. These processes enable an unprecedented degree of control over polymer architecture that was previously not possible using conventional radical polymerization processes, and this has made possible the synthesis of many new and interesting materials. However, there has been only limited success in commercializing these new methods. Recently there has been increased focus on the development of more industrially viable processes. Dispersed aqueous phase reactions have received much attention because these water-based processes have several technical, economic, and environmental benefits over the more common solution and bulk reactions that were originally developed. Likewise, there has been some investigation of using continuous reactors that have potential technical and economic benefits over the more commonly employed batch reactors. This thesis presents an in-depth study that combines the three aforementioned technologies: living/controlled radical polymerization, dispersed phase aqueous reactions, and continuous reactors. Specifically, the system of interest is a nitroxide-mediated miniemulsion polymerization reaction in a continuous tubular reactor to produce polymer latex. Design of the continuous tubular reactor is discussed in some detail with a focus on specific technical challenges that were faced in building a functional apparatus for this system. Scoping experiments are described which identified a significant effect of temperature ramping rate that is critical to understand when moving to larger scale reactors for this system. The unexpected phenomenon of room temperature polymerization initiated by ascorbic acid is also described. There is demonstration for the first time that bulk and miniemulsion polymers can be produced in a tubular reactor under controlled nitroxide-mediated polymerization conditions, and copolymers can be produced. A detailed residence time distribution study for the tubular reactor is also shown, and several interesting phenomena are discussed that have implications on the practical operating conditions of the tubular reactor. This particular study makes it clear that one should experimentally verify the residence time distribution within a continuous system with the reactants of interest, and that model systems may not give an accurate picture of the real system.
Author | : John Daniel Biasutti |
Publisher | : |
Total Pages | : 278 |
Release | : 2006 |
Genre | : Polymerization |
ISBN | : |
Download Aspects of Controlled Radical Polymerization in Dispersed Media Book in PDF, ePub and Kindle
Author | : Philipp Vana |
Publisher | : Springer |
Total Pages | : 231 |
Release | : 2015-08-11 |
Genre | : Technology & Engineering |
ISBN | : 3319221388 |
Download Controlled Radical Polymerization at and from Solid Surfaces Book in PDF, ePub and Kindle
The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science. The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics. Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist. Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned. Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students
Author | : Krzysztof Matyjaszewski |
Publisher | : |
Total Pages | : 712 |
Release | : 2003 |
Genre | : Science |
ISBN | : |
Download Advances in Controlled/living Radical Polymerization Book in PDF, ePub and Kindle
Advances in Controlled/Living Radical Polymerization presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). This book also includes synthesis and characterization of many new materials.
Author | : Krzysztof Matyjaszewski |
Publisher | : Academic |
Total Pages | : 444 |
Release | : 2009 |
Genre | : Language Arts & Disciplines |
ISBN | : |
Download Controlled/living Radical Polymerization Book in PDF, ePub and Kindle
Recent progress in the field of controlled/living radical polymerization.
Author | : Michael Buback |
Publisher | : John Wiley & Sons |
Total Pages | : 270 |
Release | : 2007-07-16 |
Genre | : Technology & Engineering |
ISBN | : 3527320563 |
Download Radical Polymerization Book in PDF, ePub and Kindle
The IUPAC-sponsored International Symposium on "Radical Polymerization: Kinetics and Mechanism" was held in Il Ciocco (Italia) during the week September 3-8, 2006. It was the fourth within the series of so-called SML conferences, which are the major scientific forum for addressing kinetic and mechanistic aspects of free-radical polymerization and of ontrolled radical polymerization. Top international authors like K. Matyjaszewski, T. P. Davis, T. Fukuda and others present their latest research. The five major themes covered were: Fundamentals of Free-Radical Polymerization, Heterogeneous Polymerization, Controlled Radical Polymerization, Polymer Reaction Engineering, and Polymer Characterization. SML IV again marked an important step forward toward the better understanding of the kinetics and mechanism of radical polymerization, which is extremely relevant for both conventional and controlled radical polymerization and for people in academia as well as in industry.
Author | : Abdelhamid Elaissari |
Publisher | : CRC Press |
Total Pages | : 529 |
Release | : 2003-08-06 |
Genre | : Science |
ISBN | : 1135527393 |
Download Colloidal Polymers Book in PDF, ePub and Kindle
Amidst developments in nanotechnology and successes in catalytic emulsion polymerization of olefins, polymerization in dispersed media is arousing an increasing interest from both practical and fundamental points of view. This text describes ultramodern approaches to synthesis, preparation, characterization, and functionalization of latexes, nanopa
Author | : |
Publisher | : Cuvillier Verlag |
Total Pages | : 176 |
Release | : 2006-08-22 |
Genre | : Science |
ISBN | : 3736919913 |
Download Radical Polymerization: Kinetics and Mechanism Book in PDF, ePub and Kindle