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Author | : Vsevolod F. Kiselev |
Publisher | : Springer Science & Business Media |
Total Pages | : 453 |
Release | : 2012-12-06 |
Genre | : Technology & Engineering |
ISBN | : 3642738877 |
Download Adsorption and Catalysis on Transition Metals and Their Oxides Book in PDF, ePub and Kindle
This book deals with adsorption and catalysis on the surface of transition elements and their compounds, many of which are in teresting because of their particular electronic structure. The authors have worked through a vast body of experimental evi dence on the structure and properties of surfaces of transition metals and relevant oxides. Consideration is given mostly to simple (as opposed to mixed) oxides of transition elements, to common metals and to the adsorption of simple gases. A great deal of attention is paid to the nature of active surface sites responsible for chemisorption and catalytic transformations. The description relies mainly on the simplified ligand-field theory, which, however, proves quite satisfactory for predicting the adsorptive and catalytic activity of species. In many cases simple systems were explored with the aid of novel techniques, and it is only for such systems that the mechanism of the ele mentary act of adsorption and catalysis can be given adequate treatment. The present monograph has emerged from our earlier work in Russian, which appeared in the Khimiya Publishing House (Mos cow) in 1981. This English edition has, however, been revised completely to broaden its scope and to include more recent a chievements. For fruitful discussions the authors are grateful to A.A.
Author | : Vsevolod F Kiselev |
Publisher | : |
Total Pages | : 460 |
Release | : 1989-05-11 |
Genre | : |
ISBN | : 9783642738883 |
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Author | : H.H. Kung |
Publisher | : Elsevier |
Total Pages | : 299 |
Release | : 1989-04-01 |
Genre | : Science |
ISBN | : 0080887422 |
Download Transition Metal Oxides Book in PDF, ePub and Kindle
In this book the author presents an up-to-date summary of existing information on the structure, electronic properties, chemistry and catalytic properties of transition metal oxides. The subjects covered in the book can be divided into three sections. The first (chapters 1 to 3) covers the structural, physical, magnetic, and electronic properties of transition metal oxides. Although the emphasis is on surface properties, relevant bulk properties are also discussed. The second section (chapters 4 to 7) covers surface chemical properties. It includes topics that describe the importance of surface coordinative unsaturation in adsorption, the formation of surface acidity and the role of acidity in determining surface chemical properties, the nature and reactivities of adsorbed oxygen, and the surface chemistry in the reduction of oxides. The third section (chapters 8 to 14) is on the catalytic properties. Various catalytic reactions including decomposition, hydrogenation, isomerization, metathesis, selective oxidation, and reactions involving carbon oxides are discussed. Emphasis is placed more on reaction mechanisms and the role of catalysts than on kinetics and processes. Chapters on the preparation of oxide catalysts and on photo-assisted processes are also included. Whenever appropriate, relationships between various topics are indicated. Written for surface physicists, chemists, and catalytic engineers, the book will serve as a useful source of information for investigators and as a comprehensive overview of the subject for graduate students.
Author | : Harold H. Kung |
Publisher | : |
Total Pages | : 285 |
Release | : 1989 |
Genre | : Catalysis |
ISBN | : 9780444418012 |
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Author | : S. David Jackson |
Publisher | : John Wiley & Sons |
Total Pages | : 916 |
Release | : 2008-11-24 |
Genre | : Science |
ISBN | : 9783527318155 |
Download Metal Oxide Catalysis, 2 Volume Set Book in PDF, ePub and Kindle
With its two-volume structure, this handbook and ready reference allows for comprehensive coverage of both characterization and applications, while uniform editing throughout ensures that the structure remains consistent. The result is an up-to-date review of metal oxides in catalysis. The first volume covers a range of techniques that are used to characterize oxides, with each chapter written by an expert in the field. Volume 2 goes on to cover the use of metal oxides in catalytic reactions. For all chemists and engineers working in the field of heterogeneous catalysis.
Author | : J.L.G. Fierro |
Publisher | : CRC Press |
Total Pages | : 808 |
Release | : 2005-08-24 |
Genre | : Science |
ISBN | : 142002812X |
Download Metal Oxides Book in PDF, ePub and Kindle
The chemistry of metals has traditionally been more understood than that of its oxides. As catalytic applications continue to grow in a variety of disciplines, Metal Oxides: Chemistry and Applications offers a timely account of transition-metal oxides (TMO), one of the most important classes of metal oxides, in the context of catalysis. The
Author | : Albert F. Carley |
Publisher | : Springer Science & Business Media |
Total Pages | : 392 |
Release | : 2013-04-18 |
Genre | : Science |
ISBN | : 1475766378 |
Download Surface Chemistry and Catalysis Book in PDF, ePub and Kindle
In 2001 Wyn Roberts celebrated both his 70th birthday and 50 years of working in surface science, to use the term "surface science" in its broadest meaning. This book aims to mark the anniversary with a contribution of lasting value, something more than the usual festschrift issue of a relevant journal. The book is divided into three sections: Surface Science, Model Catalysts and Catalysis, topics in which Wyn has always had interests. The authors for each chapter were chosen from some of the many eminent scientists who have worked with Wyn in various ways and are all internationally acknowledged as leaders in their field. The authors have produced authoritative reviews of their own specialties which together result in a book with an unrivalled combination of breadth and depth exploring the most recent developments in surface chemistry and catalysis.
Author | : R.M. Lambert |
Publisher | : Springer Science & Business Media |
Total Pages | : 534 |
Release | : 2013-04-17 |
Genre | : Science |
ISBN | : 9401589119 |
Download Chemisorption and Reactivity on Supported Clusters and Thin Films: Book in PDF, ePub and Kindle
Heterogeneous catalysis provides the backbone of the world's chemical and oil industries. The innate complexity of practical catalytic systems suggests that useful progress should be achievable by investigating key aspects of catalysis by experimental studies on idealised model systems. Thin films and supported clusters are two promising types of model system that can be used for this purpose, since they mimic important aspects of the properties of practical dispersed catalysts. Similarly, appropriate theoretical studies of chemisorption and surface reaction clusters or extended slab systems can provide valuable information on the factors that underlie bonding and catalytic activity. This volume describes such experimental and theoretical approaches to the surface chemistry and catalytic behaviour of metals, metal oxides and metal/metal oxide systems. An introduction to the principles and main themes of heterogeneous catalysis is followed by detailed accounts of the application of modern experimental and theoretical techniques to fundamental problems. The application of advanced experimental methods is complemented by a full description of theoretical procedures, including Hartree-Fock, density functional and similar techniques. The relative merits of the various approaches are considered and directions for future progress are indicated.
Author | : |
Publisher | : Elsevier |
Total Pages | : 677 |
Release | : 2001-05-21 |
Genre | : Science |
ISBN | : 0080538312 |
Download Oxide Surfaces Book in PDF, ePub and Kindle
The book is a multi-author survey (in 15 chapters) of the current state of knowledge and recent developments in our understanding of oxide surfaces. The author list includes most of the acknowledged world experts in this field. The material covered includes fundamental theory and experimental studies of the geometrical, vibrational and electronic structure of such surfaces, but with a special emphasis on the chemical properties and associated reactivity. The main focus is on metal oxides but coverage extends from 'simple' rocksalt materials such as MgO through to complex transition metal oxides with different valencies.
Author | : M. Che |
Publisher | : Elsevier |
Total Pages | : 461 |
Release | : 1985-07-01 |
Genre | : Technology & Engineering |
ISBN | : 0080960553 |
Download Adsorption and Catalysis on Oxide Surfaces Book in PDF, ePub and Kindle
The Symposium was held to honour the memory of the late Dr. A.J. Tench who made numerous important contributions to our knowledge of the structure, reactivity and adsorption properties of oxide surfaces. This volume contains an up-to-date picture of adsorption and catalysis on oxide surfaces, not in the form of a comprehensive review but in its living aspects of work in progress. It describes detailed studies on the determination of the coordination surface ions, particularly oxide ions, by photoluminescence and reflectance spectroscopy, on the identification of adsorbed species by magnetic optical or surface techniques and on catalysis, with emphasis on new concepts such as catalysis involving excited states or structure sensitive reactions.Professionals working in the industrial and academic laboratories will find the book particularly useful as it provides a state-of-the-art account of our understanding of the structure and adsorption characteristics of oxide surfaces. Contained in the book are first class research papers by leading exponents in this field. A very important issue is that the book highlights for the first time the importance of excited states and structure sensitivity in determining the behaviour of oxide surfaces.